Cation exchange membrane, electrolysis vessel using the same and method for producing cation exchange membrane

Patent metadata

Field	Value
Publication number	US-9605352-B2
Application number	US-201414476211-A
Country	US
Kind code	B2
Filing date	Sep 3, 2014
Priority date	Oct 26, 2009
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Provided is a cation exchange membrane having excellent mechanical strength against folding and the like and capable of delivering stable electrolytic performance for a long time, an electrolysis vessel using the cation exchange membrane and a method for producing the cation exchange membrane. A cation exchange membrane 1 at least includes: a membrane body containing a fluorine-based polymer having an ion-exchange group; and two or more reinforcing core materials arranged approximately in parallel within the membrane body. The membrane body is provided with two or more elution holes 12 formed between the reinforcing core materials 10 adjacent to each other. In addition, assuming that a distance between the reinforcing core materials 10 adjacent to each other is represented by a, a distance between the reinforcing core materials 10 and the elution holes 12 adjacent to each other is represented by b, a distance between the elution holes 12 adjacent to each other is represented by c, and the number of the elution holes 12 formed between the reinforcing core materials 10 adjacent to each other is represented by n, then a, b, c, and n satisfying the relationship represented by the following expression (1) or expression (2) are at least present.

b>a /( n +1)  (1)

c>a /( n +1)  (2)

First claim

What is claimed is:

1. A method for producing a cation exchange membrane, comprising the steps of:
weaving two or more reinforcing core materials, a sacrifice yarn soluble in an acid or an alkali, and a dummy yarn soluble in a predetermined solvent in which the reinforcing core materials and the sacrifice yarn are insoluble, to obtain a reinforcing material having the sacrifice yarn and the dummy yarn arranged between the reinforcing core materials adjacent to each other;
soaking the reinforcing material in the predetermined solvent to remove the dummy yarn from the reinforcing material;
stacking the reinforcing material from which the dummy yarn is removed and a fluorine-based polymer having an ion-exchange group or an ion-exchange group precursor which can be converted into the ion-exchange group by hydrolysis, to form a membrane body having the reinforcing material; and
soaking the sacrifice yarn in an acid or an alkali to remove the sacrifice yarn from the membrane body, thereby forming an elution hole in the membrane body.

Assignees

• Asahi Kasei Chemicals Corp
• Asahi Chemical Ind

Inventors

• Kameyama Hiroyuki
• Sugimoto Manabu
• Kado Yoshifumi

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M8/1079

  Inducing porosity into non porous precursors membranes, e.g. leaching, pore stretching · CPC title

• H01M8/1039

  halogenated, e.g. sulfonated polyvinylidene fluorides · CPC title

• C25B13/02 Primary

  characterised by shape or form · CPC title

• H01M8/1053

  consisting of layers of polymers with at least one layer being ionically conductive · CPC title