Process and apparatus for purification of industrial brine

Patent metadata

Field	Value
Publication number	US-9605350-B2
Application number	US-201313922658-A
Country	US
Kind code	B2
Filing date	Jun 20, 2013
Priority date	Aug 23, 2007
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Processes and apparatus for purifying brine are provided including (1) providing an aqueous brine solution comprising one or more inorganic salts and one or more organic compounds and (2) conducting at least one unit operation for removing organic compounds from the brine solution to obtain a purified brine solution.

First claim

What is claimed is:

1. A brine purification apparatus comprising:
(A) a first forced circulation evaporative crystallizer;
(B) a second forced circulation evaporative crystallizer;
(C) a first separation device for separating solids from liquids;
(D) a second separation device for separating solids from liquids;
(E) a first dilution vessel; and
(F) a second dilution vessel,
wherein the first forced circulation evaporative crystallizer is connected to the first separation device for conducting a slurry stream comprising an aqueous liquid and crystals from the first forced circulation evaporative crystallizer to the first separation device;
wherein the first separation device is connected to the first dilution vessel for conducting crystals from the first separation device to the first dilution vessel;
wherein the first dilution vessel is connected to a source of aqueous liquid for re-dissolving crystals received from the first separation device;
wherein the first dilution vessel is connected to the second forced circulation evaporative crystallizer for conducting a brine comprising re-dissolved crystals from the first dilution vessel to the second forced circulation evaporative crystallizer;
wherein the second forced circulation evaporative crystallizer is connected to the second separation vessel for conducting a slurry stream comprising an aqueous liquid and crystals from the second forced circulation evaporative crystallizer to the second separation device;
wherein the second separation device is connected to the second dilution vessel for conducting crystals from the second separation device to the second dilution vessel;
wherein the second dilution vessel is connected to a source of aqueous liquid for re-dissolving crystals received from the second separation device; and
wherein the second dilution vessel is connected to the first separation device for conducting a brine comprising re-dissolved crystals from the second dilution vessel to the first separation device for washing the crystals separated by the first separation device.

2. The apparatus of claim 1 , wherein the apparatus further comprises:
(G) a third forced circulation evaporative crystallizer;
(H) a third separation device; and
(I) a third dilution vessel,
wherein the first separation device and/or the second separation device is/are connected to the third forced circulation evaporative crystallizer for conducting the separated aqueous liquid from the first separation device and/or the second separation device to the third forced circulation evaporative crystallizer;
wherein the third forced circulation evaporative crystallizer is connected to the third separation device for conducting a slurry stream comprising an aqueous liquid and crystals from the third forced circulation evaporative crystallizer to the third separation device for separating the crystals from the aqueous liquid; and
wherein the third separation device is connected to the third dilution vessel for conducting crystals from the third separation device to the third dilution vessel;
wherein the first forced circulation evaporative crystallizer for conducting crystals from the third separation device to the third dilution vessel;
wherein the third dilution vessel is connected to a source of aqueous liquid for re-dissolving crystals received from the third separation device; and
wherein the third dilution vessel is connected to the first forced circulation evaporative crystallizer for conducting a brine comprising re-dissolved crystals from the third dilution vessel to the first forced circulation evaporative crystallizer.

3. A chemical process apparatus for producing purified brine comprising a chemical reaction apparatus suitable for reacting a chlorine-atom containing compound with sodium hydroxide to make an aqueous brine solution and a brine purification apparatus according to claim 1 , wherein the chemical reaction apparatus is connected to the brine purification apparatus for conducting an aqueous brine solution from the chemical reaction apparatus to the brine purification apparatus and the chemical reaction apparatus is connected to a source of aqueous sodium hydroxide solution for conducting the aqueous sodium hydroxide solution to the chemical reaction apparatus.

4. The chemical process apparatus according to claim 3 , wherein the chemical reaction apparatus is suitable for (i) converting chlorohydrin(s) to epichlorohydrin; (ii) making epoxy resin(s); or (iii) making methylene dianiline.

5. The chemical process apparatus according to claim 4 , further comprising a hydrochlorination apparatus suitable for making chlorohydrin(s) and the hydrochlorination apparatus is connected to the chemical reactor apparatus for conducting a stream comprising chlorohydrin(s) from the apparatus for making chlorohydrin(s) to the chemical reactor apparatus.

6. The apparatus according to claim 1 , wherein the first and second forced evaporative crystallizers preferably function as multiple effect evaporators connected in series.

7. The apparatus according to claim 1 , wherein at least one connection for a liquid or slurry comprises at least one pump for applying pressure to the liquid or slurry in the specified conducting direction.

8. The apparatus according to claim 1 , wherein at the operating pressure of the first crystallizer is less than the second crystallizer.

9. The apparatus according to claim 1 , wherein each separation device is a centrifuge and/or a hydrocyclone.

10. The apparatus according to claim 9 , wherein the separation device performs a continuous separation.

11. The apparatus of claim 1 , wherein water evaporated during forced circulation evaporative crystallization is recovered via mechanical vapor recompression (MVR).

12. The apparatus according to claim 1 , wherein the brine purification apparatus is connected to an electrochemical cell for conversion of the purified brine to chlorine gas or hypochlorite and sodium hydroxide via conventional chloro-alkali process.

Assignees

• Blue Cube Ip Llc

Inventors

• Hook Bruce
• Tirtowidjojo Dan
• Mehta Anil

Classifications

• B01D9/004

  Fractional crystallisation; Fractionating or rectifying columns · CPC title

• B01D9/0059

  General arrangements of crystallisation plant, e.g. flow sheets · CPC title

• C25B1/16 Primary

  Hydroxides (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• C25B1/26

  Chlorine; Compounds thereof (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• B01D9/0031

  by heating (B01D9/0022, B01D9/0027 take precedence) · CPC title