Hot-dip galvanized steel sheet for stamping having excellent cold workability, die hardenability, and surface quality, and producing method thereof

Patent metadata

Field	Value
Publication number	US-9605335-B2
Application number	US-201314379980-A
Country	US
Kind code	B2
Filing date	Mar 28, 2013
Priority date	Mar 30, 2012
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Disclosed is a hot-dip galvanized steel sheet for stamping, which has excellent cold workability, has such satisfactory surface quality as to be free from unplating and other defects even in the absence of dedicated facilities, and ensures a strength of 1370 MPa or more after quenching even when cooled at a low rate. Also disclosed is a method effective for the produce of the hot-dip galvanized steel sheet for stamping. The hot-dip galvanized steel sheet for stamping comprises a base steel sheet and a hot-dip galvanized layer on a surface of the base steel sheet, in which the base steel sheet has a predetermined chemical composition and has a microstructure comprising equiaxed ferrite having an average aspect ratio of 4.0 or less and cementite and/or pearlite having an average major axis of grains of 20 μm or less.

First claim

The invention claimed is:

1. A hot-dip galvanized steel sheet for stamping having excellent cold workability, die hardenability, and surface quality, the hot-dip galvanized steel sheet comprising:
a base steel sheet; and,
a hot-dip galvanized layer formed on a surface of the base steel sheet,
the base steel sheet comprising:
carbon (C) in a content of from 0.20% (meaning “mass %”; hereinafter, the same applies the chemical composition) to 0.24%;
silicon (Si) in a content of from greater than 0% to 0.1%;
manganese (Mn) in a content of from 1.20% to 1.5%;
phosphorus (P) in a content of from greater than 0% to 0.02%;
sulfur (S) in a content of from greater than 0% to 0.002%;
chromium (Cr) in a content of from 0.21% to 0.5%;
titanium (Ti) in a content of from 0.02% to 0.05%;
solute aluminum (sol. Al) in a content of from 0.02% to 0.06%; and
boron (B) in a content of from 0.001% to 0.005%, with the balance consisting of iron and inevitable impurities,
wherein the base steel sheet has a microstructure comprising:
equiaxed ferrite as a main phase in combination with cementite and/or pearlite,
a total content of other micro structures is 5 area % or less based on a total area of all microstructures;

equiaxed ferrite having an average aspect ratio of 4.0 or less; and
cementite and/or pearlite each having an average major axis of grains of 20 μm or less.

2. A method for producing a hot-dip galvanized steel sheet for stamping having excellent cold workability, die hardenability, and surface quality, the method comprising the steps of:
heating a steel slab to a temperature of from 1150° C. to 1300° C., the steel slab having the chemical composition as defined in claim 1 ;
hot-rolling the heated steel slab at a finish temperature of from 850° C. to 950° C. to give a steel sheet;
coiling the steel sheet after hot rolling at a temperature in the range of from 550° C. to 700° C.;
cold rolling the steel sheet after coiling to a rolling reduction of from 30% to 70%;
annealing the steel sheet after cold rolling at an annealing maximum temperature of from 700° C. to 800° C. for a holding time in a temperature range of from 700° C. to 800° C. of from 10 seconds to 600 seconds;
further cooling the steel sheet after annealing to 500° C. or lower; and
performing hot-dip galvanization on the steel sheet after cooling,
wherein the annealing is performed under such conditions as to satisfy a condition specified by Expression (1):
15000≦[( T/ 100) 3.5 ]×t≦ 100000  (1)

where T represents the annealing maximum temperature (° C.); and t represents the holding time (second) in a temperature range of from 700° C. to 800° C.

3. The hot-dip galvanized steel sheet according to claim 1 , wherein the base steel sheet has a microstructure comprising cementite having an average major axis grains of from 1 to 20 μm.

4. The hot-dip galvanized steel sheet according to claim 1 , having a strength after quenching tensile strength of 1,370 mPa or more.

5. The hot-dip galvanized steel sheet according to claim 1 , wherein the base steel sheet has a microstructure comprising cementite and/or pearlite each having an average major axis grains of from 3 to 18 μm.

6. The hot-dip galvanized steel sheet according to claim 1 , wherein the base steel sheet has a microstructure that comprises only ferrite grains and at least one of cementite grains and pearlite grains.

7. The hot-dip galvanized steel sheet according to claim 1 , wherein the base steel sheet has a microstructure including ferrite grains having an aspect ratio of from 1.8 to 3.8.

8. The hot-dip galvanized steel sheet according to claim 1 , wherein the base steel sheet comprises at least one of cementite and pearlite grains at grain boundaries of ferrite grains.

9. The hot-dip galvanized steel sheet according to claim 1 , wherein the base steel sheet has a microstructure that does not comprise pearlite grains.

10. The method of claim 2 , wherein the annealing includes a maximum annealing temperature of 720-780° C.

11. The method of claim 2 , wherein the annealing includes a holding time at a maximum annealing temperature of from 40 to 50 seconds.

12. The method of claim 2 , wherein the annealing includes a holding time in a temperature range of 700 to 800° C. of from 21 to 68 seconds.

Assignees

• Kobe Steel Ltd
• Voestalpine Stahl Gmbh

Inventors

• Nakaya Michiharu
• Asai Tatsuya
• Pichler Andreas
• Kurz Thomas

Classifications

• Y10T428/12799

  Next to Fe-base component [e.g., galvanized] · CPC title

• C22C38/00 Primary

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title

• C21D2211/009

  Pearlite · CPC title

• C21D2211/005

  Ferrite · CPC title

• C21D2211/003

  Cementite · CPC title