Cold rolled steel sheet and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-9605329-B2
Application number	US-201314371214-A
Country	US
Kind code	B2
Filing date	Jan 11, 2013
Priority date	Jan 13, 2012
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

When the amount of C, the amount of Si and the amount of Mn are respectively represented by [C], [Si] and [Mn] in unit mass %, the cold rolled steel sheet satisfies a relationship of (5×[Si]+[Mn])/[C]>10, the metallographic structure contains, by area ratio, 40% to 90% of a ferrite and 10% to 60% of a martensite, further contains one or more of 10% or less of a pearlite by area ratio, 5% or less of a retained austenite by volume ratio and 20% or less of a bainite by area ratio, the hardness of the martensite measured using a nanoindenter satisfies H20/H10<1.10 and σHM0<20, and TS×λ representing the product of TS that is a tensile strength and λ that is a hole expansion ratio is 50000 MPa·% or more.

First claim

The invention claimed is:

1. A cold rolled steel sheet comprising, by mass %:
C: more than 0.150% to 0.300%;
Si: 0.010% to 1.000%;
Mn: 1.50% to 2.70%;
P: 0.001% to 0.060%;
S: 0.001% to 0.010%;
N: 0.0005% to 0.0100%; and
Al: 0.010% to 0.050%, and
optionally one or more of:
B: 0.0005% to 0.0020%;
Mo: 0.01% to 0.50%;
Cr: 0.01% to 0.50%;
V: 0.001% to 0.100%;
Ti: 0.001% to 0.100%;
Nb: 0.001% to 0.050%;
Ni: 0.01% to 1.00%;
Cu: 0.01% to 1.00%;
Ca: 0.0005% to 0.0050%; and
REM: 0.0005% to 0.0050%, and
a balance including Fe and unavoidable impurities,
wherein, when an amount of C, an amount of Si and an amount of Mn are respectively represented by [C], [Si] and [Mn] in unit mass %, a relationship of the following formula 1 is satisfied,
a metallographic structure contains, by area ratio, 40% to 90% of a ferrite and 10% to 60% of a martensite, and further contains one or more of 10% or less of a pearlite by area ratio, 5% or less of a retained austenite by volume ratio and 20% or less of a bainite by area ratio,
a hardness of the martensite measured using a nanoindenter satisfies the following formulae 2a and 3a, and
TS×λ, representing a product of TS that is a tensile strength and X, that is a hole expansion ratio is 50000 MPa·% or more,
(5×[Si]+[Mn])/[C]>10  (1)

H 20/ H 10<1.10  (2a)

σ HM 0<20  (3a)

here, the H10 represents an average hardness of the martensite at the surface part of the cold rolled steel sheet, the H20 represents an average hardness of the martensite at a center portion of a sheet thickness that occupies a ±100 μm range from a sheet thickness center of the cold rolled steel sheet in a thickness direction, and the σHM0 represents a variance of the hardness of the martensite present in the center portion of the sheet thickness.

2. The cold rolled steel sheet according to claim 1 ,
wherein an area ratio of an MnS that is present in the metallographic structure and has an equivalent circle diameter in a range of 0.1 μm to 10 μm is 0.01% or less, and the following formula 4a is satisfied,
n 20/ n 10<1.5  (4a)

here, the n10 represents an average number density of the MnS per 10000 μm 2 at a ¼ part of the sheet thickness of the cold rolled steel sheet, and the n20 represents an average number density of the MnS per 10000 μm 2 at the center portion of the sheet thickness.

3. The cold rolled steel sheet according to claim 1 ,
wherein, additionally, after a hot stamping including a heating at a temperature in a range of 750° C. to 1000° C., a working and a cooling, is carried out, the hardness of the martensite measured using a nanoindenter satisfies the following formulae 2b and 3b, the metallographic structure contains 80% or more of a martensite by area ratio, optionally, further contains one or more of 10% or less of a pearlite by area ratio, 5% or less of a retained austenite by volume ratio, less than 20% of a ferrite and less than 20% of a bainite by area ratio, and TS×λ representing the product of TS that is the tensile strength and λ that is the hole expansion ratio is 50000 MPa·% or more,
H 2/ H 1<1.10  (2b)

σ HM< 20  (3b)

here, the H1 represents an average hardness of the martensite at the surface part after the hot stamping, the H2 represents an average hardness of the martensite at the center portion of the sheet thickness after the hot stamping, and the σHM represents a variance of the hardness of the martensite present at the center portion of the sheet thickness after the hot stamping.

4. The cold rolled steel sheet according to claim 3 ,
wherein an area ratio of MnS that is present in the metallographic structure and has an equivalent circle diameter in a range of 0.1 μm to 10 μm is 0.01% or less, and
the following formula 4b is satisfied,
n 2/ n 1<1.5  (4b)

here, the n1 represents an average number density of the MnS per 10000 μm 2 at a ¼ part of the sheet thickness in the cold rolled steel sheet after the hot stamping, and the n2 represents an average number density of the MnS per 10000 μm 2 at the center portion of the sheet thickness after the hot stamping.

5. The cold rolled steel sheet according to any one of claims 1 to 4 ,
wherein a hot-dip galvanized layer is further formed on a surface of the cold rolled steel sheet.

6. The cold rolled steel sheet according to claim 5 ,
wherein the hot-dip galvanized layer includes a galvannealed layer.

7. The cold rolled steel sheet according to any one of claims 1 to 4 ,
wherein an electrogalvanizing layer is further formed on a surface of the cold rolled steel sheet.

8. The cold rolled steel sheet according to any one of claims 1 to 4 ,
wherein an aluminizing layer is further formed on a surface of the cold rolled steel sheet.

9. A manufacturing method of manufacturing a cold rolled steel sheet according to claim 1 , the method comprising:
casting molten steel having the chemical components according to claim 1 and obtaining a steel;
heating the steel;
hot-rolling the steel using a hot rolling facility having a plurality of stands;
coiling the steel after the hot rolling;
pickling the steel after the coiling;
cold-rolling the steel after the pickling using a cold rolling mill having a plurality of stands under conditions in which the following formula 5 is satisfied;
heating the steel at a temperature in a range of 700° C. to 850° C. and cooling the steel after the cold rolling; and
temper-rolling the steel after the heating and cooling of the steel,
1.5× r 1/ r+ 1.2× r 2/ r+r 3/ r> 1.0  (5)

wherein r1, r2 and r3 each represent an individual target cold rolling reduction in an i th stand from the uppermost stand among a plurality of the stands in the cold rolling in unit %, and r represents a total cold rolling reduction In the cold rolling in unit %.

10. The manufacturing method of manufacturing a cold rolled steel sheet according to claim 9 ,
wherein, when a coiling temperature in the coiling is represented by CT in unit ° C.; and
an amount of C, an amount of Mn, an amount of Cr and an amount of Mo of the steel are respectively represented by [C], [Mn], [Cr] and [Mo] in unit mass %,
the following formula 6 is satisfied,
560−474×[C]−90×[Mn]−20×[Cr]−20×[Mo]<CT<830−270×[C]−90×[Mn]−70×[Cr]−80×[Mo]  (6).

11. The manufacturing method of manufacturing a cold rolled steel sheet according to claim 9 or 10 ,
wherein, when a heating temperature in the heating is represented by T in unit ° C.; an in-furnace time is represented by t in unit minute; and
an amount of Mn and an amount of S in the steel are respectively represented by [Mn] and [S] in unit mass %,
the following formula 7 is satisfied,
T ×ln( t )/(1.7×[Mn]+[S])>1500  (7).

12. The manufacturing method of manufacturing a cold rolled steel sheet according to claim 9 or 10 , further comprising:
hot dip galvanizing on the steel is further provided between the annealing and the temper rolling.

13. The manufacturing method of manufacturing a cold rolled steel sheet according to claim 12 , further comprising:
alloying the steel between the hot dip galvanizing and the temper rolling.

14. The manufacturing method of manufacturing a cold rolled steel sheet according to claim 9 or 10 , further comprising:
electrogalvanizing the steel after the temper rolling.

15. The manufacturing method of manufacturing a cold rolled steel sheet according to claim 9 or 10 , further comprising:
aluminizing the steel between the annealing and the temper rolling.

16. The manufacturing method of manufacturing a cold rolled steel sheet acc

Assignees

• Nippon Steel & Sumitomo Metal Corp

Inventors

• Nonaka Toshiki
• Kato Satoshi
• Kawasaki Kaoru
• Tomokiyo Toshimasa

Classifications

• C23C2/28

  Thermal after-treatment, e.g. treatment in oil bath · CPC title

• C21D9/48

  deep-drawing sheets · CPC title

• C22C38/38

  with more than 1.5% by weight of manganese · CPC title

• C21D8/0273

  Final recrystallisation annealing · CPC title

• C22C38/22

  with molybdenum or tungsten · CPC title