Integrated hydrocracking and slurry hydroconversion of heavy oils

Patent metadata

Field	Value
Publication number	US-9605218-B2
Application number	US-201414308893-A
Country	US
Kind code	B2
Filing date	Jun 19, 2014
Priority date	Jun 20, 2013
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Improved yields of fuels and/or lubricants from a resid or other heavy oil feed can be achieved using slurry hydroconversion to convert at least about 90 wt % of the feed. The converted portion of the feed can then be passed into one or more hydroprocessing stages. An initial processing stage can be a hydrotreatment stage for additional removal of contaminants and for passivation of high activity functional groups that may be created during slurry hydroconversion. The hydrotreatment effluent can then be fractionated to separate naphtha boiling range fractions from distillate fuel boiling range fractions and lubricant boiling range fractions. At least the lubricant boiling range fraction can then be hydrocracked to improve the viscosity properties. The hydrocracking effluent can also be dewaxed to improve the cold flow properties. The hydrocracked and/or dewaxed product can then be optionally hydrofinished.

First claim

What is claimed is:

1. A method for processing a heavy oil feedstock, comprising:
providing a heavy oil feedstock having a 5 wt % boiling point of at least about 650° F. (343° C.) and a first Conradson carbon residue wt %;
exposing the heavy oil feedstock to a catalyst under effective slurry hydroconversion conditions to form at least a first liquid product, the effective slurry hydroconversion conditions being effective for conversion of at least about 90 wt % of the heavy oil feedstock relative to a conversion temperature;
hydrotreating the first liquid product under effective hydrotreating conditions to form a first hydrotreated liquid product;
fractionating the first hydrotreated liquid product to form one or more naphtha boiling range products, one or more distillate fuel boiling range products, and one or more lubricating base oil boiling range products; and
hydrocracking at least a portion of the one or more lubricating base oil boiling range products to form at least one hydrocracked fuel product and a hydrocracking bottoms product.

2. The method of claim 1 , further comprising recycling at least a portion of the hydrocracking bottoms product, the hydrocracking of the at least a portion of the one or more lubricating base oil boiling range products further comprising hydrocracking the hydrocracking bottoms product.

3. The method of claim 1 , further comprising dewaxing at least a portion of the hydrocracking bottoms product.

4. The method of claim 3 , further comprising hydrofinishing at least a portion of the hydrocracking bottoms product.

5. The method of claim 1 , wherein the heavy oil feedstock has a 10% distillation point of at least about 900° F. (482° C.), a Conradson carbon residue of at least about 27.5 wt %, or a combination thereof.

6. The method of claim 1 , wherein exposing the heavy oil feedstock to a catalyst under effective slurry hydroconversion conditions further comprises forming an unconverted slurry hydroconversion pitch.

7. The method of claim 1 , wherein the hydrocracking catalyst comprises a molecular sieve selected from USY, ZSM-48, or a combination thereof.

8. The method of claim 1 , further comprising dewaxing a portion of at least one of the one or more distillate fuel products under effective distillate fuel dewaxing conditions.

9. The method of claim 1 , wherein exposing the heavy oil feedstock to a catalyst under effective slurry hydroconversion conditions to form at least a first liquid product comprises:
exposing the heavy oil feedstock to a first catalyst under first effective slurry hydroconversion conditions to form a first slurry hydroconversion effluent; and
exposing at least a portion of the first slurry hydroconversion effluent to a second catalyst under second effective slurry hydroconversion conditions to form a second slurry hydroconversion effluent, the first liquid product comprising at least a portion of the second slurry hydroconversion effluent.

10. The method of claim 9 , wherein a temperature of the second effective slurry hydroconversion conditions is greater than a temperature of the first effective slurry hydroconversion conditions by about 10° C. to about 80° C.

11. The method of claim 9 , further comprising fractionating the first slurry hydroconversion effluent to form at least one of a naphtha fraction or a distillate fuel fraction, and at least one slurry resid or bottoms fraction, the slurry resid or bottoms fraction containing a portion of the first catalyst corresponding to at least about 50% of the first catalyst in the first slurry hydroconversion effluent, wherein exposing at least a portion of the first slurry hydroconversion effluent to the second catalyst comprises exposing at least a portion of the slurry resid or bottoms fraction to the second catalyst.

12. The method of claim 11 , wherein the second catalyst comprises the portion of the first catalyst contained in the slurry resid or bottoms fraction.

13. The method of claim 11 , further comprising separating the slurry resid or bottoms fraction to form a first catalyst fraction and a catalyst-depleted resid or bottoms fraction, the catalyst-depleted resid or bottoms fraction containing about 25 wt % or less of the catalyst in the slurry resid or bottoms fraction prior to separation, wherein exposing at least a portion of the slurry resid or bottoms fraction to the second catalyst comprises exposing at least a portion of the catalyst-depleted resid or bottoms fraction to the second catalyst.

14. The method of claim 13 , further comprising introducing the second catalyst into the catalyst-depleted resid or bottoms fraction.

15. The method of claim 11 , wherein the first slurry hydroconversion effluent is fractionated in a divided wall fractionator, the method further comprising fractionating the second slurry hydroconversion effluent in the divided wall fractionator.

Assignees

• Smiley Randolph J
• Dandekar Ajit Bhaskar
• Sundararaman Ramanathan
• Billimoria Rustom Merwan
• Degnan Jr Thomas Francis
• Exxonmobil Res & Eng Co

Inventors

• Smiley Randolph J
• Dandekar Ajit Bhaskar
• Sundararaman Ramanathan
• Billimoria Rustom Merwan
• Degnan Jr Thomas Francis

Classifications

• C10G47/26

  suspended in the oil, e.g. slurries · CPC title

• C10G45/16

  suspended in the oil, e.g. slurries · CPC title

• C10G49/12

  suspended in the oil, e.g. slurries · CPC title

• C10G65/12 Primary

  including cracking steps and other hydrotreatment steps · CPC title