Stabilizing aqueous inkjet ink compositions
US-2024400846-A1 · Dec 5, 2024 · US
US9605168B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9605168-B2 |
| Application number | US-201514610256-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 30, 2015 |
| Priority date | Jan 31, 2014 |
| Publication date | Mar 28, 2017 |
| Grant date | Mar 28, 2017 |
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Water-based ink comprising a pigment mix and a method to form a digital print on a substrate with a pigment mix comprising large pigments and a Piezo ink head equipped with an ink circulation system, the method including: providing a water-based ink including an aqueous pigment mix including settling pigments, a binder including an acrylic resin dispersion, and a viscosity increasing substance including glycol and/or glycerine, providing a steric stabilization of the pigments and adapting the size of the pigments and the viscosity of the water-based ink such that a settling velocity of the pigments exceeds about 0.001 mm/min at 25° C., circulating said water-based ink within said at least one Piezo print head, and printing a digital image with said at least one Piezo print head by applying ink drops of said water-based ink on the substrate.
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The invention claimed is: 1. A method of printing a digital image on a substrate attached to a panel with at least one Piezo print head, the method comprising: providing a water-based ink comprising: an aqueous pigment mix comprising pigments, a binder comprising an acrylic resin dispersion and a viscosity increasing substance comprising glycol and/or glycerine, providing a steric stabilisation of the pigments and adapting the size of the pigments and the viscosity of the water-based ink such that a settling velocity of the pigments exceeds about 0.001 mm/min at 25° C., circulating said water-based ink within said at least one Piezo print head, and printing a digital image with said at least one Piezo print head by applying ink drops of said water-based ink on the substrate. 2. The method as claimed in claim 1 , wherein the pigments have an average diameter of about 200-500 nm and a diameter variation of at least 90% of the pigments is within 100 nm-1000 nm. 3. The method as claimed in claim 1 , wherein at least 90% of the pigments have a diameter exceeding 250 nm. 4. The method as claimed in claim 1 , wherein at least 90% of the pigments have a diameter smaller than 800 nm. 5. The method as claimed in claim 1 , wherein the viscosity of the water-based ink is about 5-50 cps at 25° C. 6. The method as claimed in claim 1 , wherein the digital image is a wood design comprising a first and a second base colour, and wherein at least one of the first and second base colour is formed by said water-based ink comprising said aqueous pigment mix. 7. The method as claimed in claim 1 , wherein the water-based ink comprises a spot colour. 8. The method as claimed in claim 7 , wherein the spot colour is applied as overlapping drops comprising a drop size of at least 30 picoliters. 9. The method as claimed in claim 1 , further comprising applying heat and pressure to the substrate after printing. 10. The method as claimed in claim 1 , wherein the substrate comprises a thermosetting resin. 11. The method as claimed in claim 1 , wherein the substrate is powder based. 12. The method as claimed in claim 1 , wherein the substrate comprises a paper. 13. The method as claimed in claim 1 , wherein the Piezo print head comprises a nozzle opening with a diameter of at least 30 microns. 14. The method as claimed in claim 1 , wherein settling velocity of the pigments is 0.01-1 mm/min at 25° C. 15. The method as claimed in claim 1 , wherein providing steric stabilization of the pigments comprises including a dispersing agent in the water-based ink. 16. The method as claimed in claim 1 , wherein the viscosity increasing substance comprises at least 30 wt % of glycol and/or glycerine. 17. A method of printing a digital image on a substrate attached to a panel with at least one Piezo print head, the method comprising: providing a water-based ink comprising: an aqueous pigment mix comprising pigments, a binder comprising an acrylic resin dispersion, and a viscosity increasing substance comprising glycol and/or glycerine, adapting the size of the pigments such that the average diameter of the pigments is about 200-500 nm and such that a diameter variation of at least 90% of the pigments is within 100 nm-1000 nm and providing a steric stabilisation of the pigments, circulating said water-based ink within said at least one Piezo print head, and printing a digital image with said at least one Piezo print head by applying ink drops of said water-based ink on the substrate. 18. The method as claimed in claim 17 , wherein the viscosity of the water-based ink is about 5-50 cps at 25° C. 19. The method as claimed in claim 17 , wherein at least 90% of the pigments have a diameter exceeding 250 nm. 20. The method as claimed in claim 17 , wherein at least 90% of the pigments have a diameter smaller than 800 nm. 21. The method as claimed in claim 17 , wherein the digital image is a wood design comprising a first and a second base colour, and wherein at least one of the first and the second base colour is formed by said water-based ink comprising said aqueous pigment mix. 22. The method as claimed in claim 17 , wherein the water-based ink comprises a spot colour. 23. The method as claimed in claim 22 , wherein the spot colour is applied as overlapping drops comprising a drop size of at least 30 picoliters. 24. The method as claimed in claim 17 , further comprising applying heat and pressure to the substrate after printing. 25. The method as claimed in claim 17 , wherein the substrate comprises a thermosetting resin. 26. The method as claimed in claim 17 , wherein the substrate is powder based. 27. The method as claimed in claim 17 , wherein the substrate comprises a paper. 28. The method as claimed in claim 17 , wherein the Piezo print head comprises a nozzle opening with a diameter of at least 30 microns. 29. The method as claimed in claim 17 , wherein providing steric stabilization of the pigments comprises including a dispersing agent in the water-based ink. 30. The method as claimed in claim 17 , wherein the viscosity increasing substance comprises at least 30 wt % of glycol and/or glycerine.
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