Asphalt compositions for roofing applications, methods for making the same, and filled asphalt material comprising the same

Patent metadata

Field	Value
Publication number	US-9605152-B2
Application number	US-201514794263-A
Country	US
Kind code	B2
Filing date	Jul 8, 2015
Priority date	Jul 16, 2014
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Asphalt compositions for roofing applications are provided, as well as filled asphalt material comprising the asphalt compositions and methods for making asphalt compositions and filled asphalt material. More particularly, the asphalt compositions comprise non-oxidized base asphalt; and a low molecular weight polyolefin present in an amount of from about 0.5 to about 15 wt % based on the total weight of the asphalt composition. The asphalt composition has a softening point from about 87.8 to about 160° C. (about 190 to about 320° F.), a penetration of greater than 12 deci-millimeters @ 25° C., as well as improved stain resistance and heat resistance.

First claim

What is claimed is:

1. An asphalt composition for use in roofing applications comprising:
non-oxidized base asphalt; and
a low MW polyolefin present in an amount of no more than about 1.8 wt % based on the total weight of the asphalt composition, wherein said asphalt composition has a softening point from about 87.8 to about 160° C. (about 190 to about 320° F.), and a penetration of greater than about 12 deci-millimeters (dmm, or 0.1 mm) @ 25° C., and wherein the low MW polyolefin has a crystallinity of from about 30 to about 100 percent (%).

2. The asphalt composition according to claim 1 , wherein the asphalt composition has a stain index of less than about 20.

3. The asphalt composition according to claim 2 , further comprising a second type of asphalt chosen from: uintahite, Lake Trinidad Asphalt, Buton Asphalt, and combinations thereof, present in an amount of from about 5 to about 20 wt %, based on the total weight of the asphalt composition, and wherein the asphalt composition has a penetration of from about 12 to about 26 dmm, @ 25° C.

4. The asphalt composition according to claim 2 , wherein the asphalt composition has a stain index of less than about 15.

5. The asphalt composition according to claim 1 , further comprising one or more performance additives in a total amount of from about 5 to about 15 wt %, based on the total weight of the asphalt composition, and wherein the asphalt composition has a heat resistance of less than about 20 mm.

6. The asphalt composition according to claim 5 , wherein the low MW polyolefin is present in an amount of from about 0.5 to about 1.2 wt % based on the total weight of the asphalt composition, and wherein the asphalt composition has a heat resistance of less than about 10 mm and a cold bending temperature of about −20° C. or lower.

7. The asphalt composition according to claim 6 , wherein the one or more performance additives comprise an SBS copolymer present in an amount of from about 6 to about 12 wt %, based on the total weight of the asphalt composition.

8. The asphalt composition according to claim 1 , wherein the low MW polyolefin has a weight average molecular weight (M w ) of from about 500 to about 20,000 Daltons.

9. The asphalt composition according to claim 1 , wherein the low MW polyolefin is selected from: polyethylene homopolymer, polypropylene homopolymer, copolymers of two or more of ethylene, propylene butene, hexene, and octene, functionalized derivatives of said homopolymers, functionalized derivatives of said copolymers, or combinations of unfunctionalized and functionalized low MW polyolefins.

10. A filled asphalt material for use in roofing applications comprising:
an asphalt composition present in an amount of about 30 to about 99 wt. % of the filled asphalt material, the asphalt composition comprising non-oxidized base asphalt and a low MW polyolefin which is present in an amount of no more than about 1.8 wt %, based on the total weight of the asphalt composition, wherein said asphalt composition has a softening point from about 87.8 to about 160° C. (about 190 to about 320° F.), and a penetration of greater than about 12 dmm @ 25° C., and wherein the low MW polyolefin has a crystallinity of from about 30 to about 100 percent (%); and
an inorganic filler, recycled asphalt materials, or a combination thereof, which are present in a total amount of from about 1 to about 70 wt % of the filled asphalt material.

11. The filled asphalt material according to claim 10 , wherein the asphalt composition has a stain index of less than about 20.

12. The filled asphalt material according to claim 10 , wherein the asphalt composition further comprises one or more performance additives in a total amount of from about 5 to about 15 wt %, based on the total weight of the asphalt composition, and wherein the asphalt composition has a heat resistance of less than about 20 mm.

13. The filled asphalt material according to claim 12 , wherein the asphalt composition has a heat resistance of less than about 10 mm and a cold bending temperature of about −20° C. or lower.

14. A method for making an asphalt composition for use in roofing applications, the method comprising the step of combining a low MW polyolefin and a non-oxidized base asphalt at an elevated temperature to form the asphalt composition, wherein the low MW polyolefin is present in an amount of no more than about 1.8 wt %, based on the total weight of the asphalt composition, wherein the asphalt composition has a softening point from about 87.8 to about 160° C. (about 90 to about 320° F.), and a penetration of greater than about 12 dmm @ 25° C., and wherein the low MW polyolefin has a crystallinity of from about 30 to about 100 percent (%).

15. The method according to claim 14 , further comprising combining, at an elevated temperature, one or more performance additives in an amount of from about 5 to about 15 wt %, based on the total weight of the asphalt composition, with the low MW polyolefin, the non-oxidized base asphalt, the combined low MW polyolefin and non-oxidized base asphalt, or any combination thereof, to form the asphalt composition.

16. The asphalt composition according to claim 1 wherein the non-oxidized base asphalt is further defined as roofing flux having a penetration of greater than about 150 dmm.

17. The asphalt composition according to claim 1 wherein the functionalized low MW polyolefin comprises one or more functional groups selected from: an acid, an ester, an amine, an amide, an ether, and anhydride.

18. The asphalt composition according to claim 1 wherein the functionalized low MW polyolefin comprises maleated polyethylene, maleated polypropylene, ethylene acrylic acid copolymers, ethylene vinyl acetate copolymers, oxidized polyethylene, or combinations thereof.

19. The asphalt composition according to claim 1 , wherein the low MW polyolefin is present in an amount of from about 0.5 to about 1.8 wt %.

Assignees

• Honeywell Int Inc

Inventors

• Ruan Yonghong
• Hacker Scott Martin
• Lem Paul Chi

Classifications

• C08L95/00 Primary

  Compositions of bituminous materials, e.g. asphalt, tar, pitch · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title

• C08L23/02

  not modified by chemical after-treatment · CPC title

• D06N5/003

  coated with bitumen · CPC title

• C08L2555/86

  Polymers containing aliphatic hydrocarbons only, e.g. polyethylene, polypropylene or ethylene-propylene-diene copolymers · CPC title