Thermoplastic resin composition, molded article and coated molded article

Patent metadata

Field	Value
Publication number	US-9605146-B2
Application number	US-201414783661-A
Country	US
Kind code	B2
Filing date	Apr 22, 2014
Priority date	Apr 23, 2013
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

A thermoplastic resin composition, comprising:
an aromatic polycarbonate (A); a copolymer mixture (B) comprising a copolymer (b1) of a vinyl cyanide-based monomer and one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer, and a graft copolymer (b2) of a vinyl cyanide-based monomer, one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer and a rubbery polymer; and at least one kind of metal atom selected from the group consisting of Mg, Al and Ca, wherein the copolymer mixture (B) comprises an acetone-soluble component, wherein said acetone-soluble component has at least two peak tops, being peak top 1 and peak top 2, within the range of 15 to 50% of vinyl cyanide component content rate, when measuring the vinyl cyanide component content rate by high performance liquid chromatography, wherein the peak top 1 is present in the range of 15% or more to 30% or less of vinyl cyanide component content rate, wherein the peak top 2 is present in the range of from more than 30% to 50% or less of vinyl cyanide component content rate, and wherein the total content of the metal atoms is 10 to 1000 ppm, based on 100 parts by mass of total amount of the aromatic polycarbonate (A) and the copolymer mixture (B).

First claim

The invention claimed is:

1. A thermoplastic resin composition, comprising:
an aromatic polycarbonate (A);
a copolymer mixture (B) comprising a copolymer (b1) of a vinyl cyanide-based monomer and one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer, and a graft copolymer (b2) of a vinyl cyanide-based monomer, one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer and a rubbery polymer; and
at least one kind of metal atom selected from the group consisting of Mg, Al and Ca,
wherein the copolymer mixture (B) comprises an acetone-soluble component,
wherein said acetone-soluble component has at least two peak tops, being peak top 1 and peak top 2, within the range of 15 to 50% by mass of vinyl cyanide component content rate, when measuring the vinyl cyanide component content rate by high performance liquid chromatography,
wherein the peak top 1 is present in the range of 15% or more to 30% by mass or less of vinyl cyanide component content rate,
wherein the peak top 2 is present in the range of from more than 30% to 50% by mass or less of vinyl cyanide component content rate, and
wherein the total content of the metal atoms is 10 to 1000 ppm, based on 100 parts by mass of total amount of the aromatic polycarbonate (A) and the copolymer mixture (B).

2. The thermoplastic resin composition according to claim 1 , wherein a ratio of the peak area of the peak top 1 to the peak area of the peak top 2 is 90/10 to 10/90.

3. The thermoplastic resin composition according to claim 1 , wherein the difference between the vinyl cyanide component content rate of the peak top 1, and the vinyl cyanide component content rate of the peak top 2 is 5% by mass or more.

4. The thermoplastic resin composition according to claim 1 , wherein volume average particle size of the rubbery polymer is from 50 to 1000 nm.

5. The thermoplastic resin composition according to claim 1 , having one phase comprising the aromatic polycarbonate (A), and two phases comprising the copolymer (b1), in morphology observed by a transmission electron microscope.

6. A molded body obtained by injection molding of the thermoplastic resin composition according to claim 1 by a heating cylinder having a preset temperature of from 230 to 300° C.

7. A coated molded body comprising the molded body according to claim 6 , wherein the molded body has at least one coated layer.

8. The thermoplastic resin composition according to claim 2 , wherein the difference between the vinyl cyanide component content rate of the peak top 1, and the vinyl cyanide component content rate of the peak top 2 is 5% by mass or more.

9. The thermoplastic resin composition according to claim 2 , wherein volume average particle size of the rubbery polymer is from 50 to 1000 nm.

10. The thermoplastic resin composition according to claim 3 , wherein volume average particle size of the rubbery polymer is from 50 to 1000 nm.

11. The thermoplastic resin composition according to claim 2 , having one phase comprising the aromatic polycarbonate (A), and two phases comprising the copolymer (b1), in morphology observed by a transmission electron microscope.

12. The thermoplastic resin composition according to claim 3 , having one phase comprising the aromatic polycarbonate (A), and two phases comprising the copolymer (b1), in morphology observed by a transmission electron microscope.

13. The thermoplastic resin composition according to claim 4 , having one phase comprising the aromatic polycarbonate (A), and two phases comprising the copolymer (b1), in morphology observed by a transmission electron microscope.

14. A thermoplastic resin composition, comprising:
an aromatic polycarbonate (A);
a copolymer mixture (B) comprising a copolymer (b1) of a vinyl cyanide-based monomer and one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer, and a graft copolymer (b2) of a vinyl cyanide-based monomer, one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer and a rubbery polymer; and
at least one kind of metal atom selected from the group consisting of Mg, Al and Ca,
wherein the copolymer mixture (B) comprises an acetone-soluble component,
wherein the copolymer (b1) is a mixture of a copolymer (b1-2) having a vinyl cyanide component content rate of from 15% or more to 30% by mass or less and a copolymer (b1-1) having a vinyl cyanide component content rate of from more than 30% to 50% by mass or less,
wherein said acetone-soluble component has at least two peak tops, being peak top 1 and peak top 2, within the range of 15 to 50% by mass of vinyl cyanide component content rate, when measuring the vinyl cyanide component content rate by high performance liquid chromatography,
wherein the peak top 1 is present in the range of 15% or more to 30% by mass or less of vinyl cyanide component content rate,
wherein the peak top 2 is present in the range of from more than 30% to 50% by mass or less of vinyl cyanide component content rate, and
wherein the total content of the metal atoms is 10 to 1000 ppm, based on 100 parts by mass of total amount of the aromatic polycarbonate (A) and the copolymer mixture (B).

Assignees

• Asahi Kasei Chemicals Corp

Inventors

• Ueda Yoshikazu
• Wakita Takayuki

Classifications

• C08F236/06

  Butadiene · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08F220/44

  Acrylonitrile · CPC title

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title