Method for secondary molding of polymer NANO oriented crystal material

Patent metadata

Field	Value
Publication number	US-9605116-B2
Application number	US-201113877787-A
Country	US
Kind code	B2
Filing date	Oct 7, 2011
Priority date	Oct 8, 2010
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

A method for secondary-molding a polymer nano oriented crystal material in accordance with an embodiment of the present invention includes the steps of: heating the polymer nano oriented crystal material so that the polymer nano oriented crystal material changes into a mobile phase or a melt having a dense entanglement network structure; molding the polymer nano oriented crystal material which changed into the mobile phase or the melt including the dense entanglement network in the step; and cooling the polymer nano oriented crystal material, which has undergone the step, until the polymer nano oriented crystal material changes into an ordered phase.

First claim

The invention claimed is:

1. A method for secondary-molding a polymer nano oriented crystal material, comprising the steps of:
(1) providing a polymer nano oriented crystal material by (i) elongating a polymer melt at an elongation strain rate not slower than a critical elongation strain rate, to thereby obtain an oriented polymer melt and (ii) crystallizing the oriented polymer melt;
(2) heating the polymer nano oriented crystal material so that the polymer nano oriented crystal material changes into a melt having a dense entanglement network structure;
(3) molding the polymer nano oriented crystal material which changed into the melt having the dense entanglement network structure in the step (2); and
(4) cooling the polymer nano oriented crystal material, which has undergone the step (3), under a restrained condition, until the polymer nano oriented crystal material changes into an ordered phase, wherein
the restrained condition is a condition under which the melt having a dense entanglement network structure is restricted to make no volume change,
the polymer nano oriented crystal material comprises polymer nano oriented crystals having a crystal size d of not more than 300 nm and an orientation function f c of not less than 0.7, the orientation function f c representing a degree of orientation of polymer chains in crystals,
the polymer nano oriented crystal material comprises a cylindrical high order structure, and
the cylindrical high order structure comprises a bundle of strings each of which is constituted by nano oriented crystal particles connected together.

2. The method according to claim 1 , wherein the polymer nano oriented crystal material is made of polyolefin.

3. The method according to claim 1 , wherein the polymer nano oriented crystal material is made of polypropylene.

4. The method according to claim 1 , wherein the step (3) is fusing a plurality of polymer nano oriented crystal materials together.

5. The method according to claim 1 , wherein the step (3) is stacking a plurality of sheet-shape polymer nano oriented crystal materials on top of each other and fusing the plurality of sheet-shape polymer nano oriented crystal materials.

6. The method according to claim 1 , wherein the step (3) is molding the polymer nano oriented crystal material by press molding, stretch molding, roll molding, drawing molding, welding molding, fusion molding or vacuum molding.

7. The method according to claim 1 , wherein the polymer nano oriented crystal material has a crystallinity of more than 90%.

Assignees

• Hikosaka Masamichi
• Okada Kiyoka
• Washiyama Junichiro
• Nakajima Takeshi
• Akiyama Yuka
• Ueno Shingo
• Sunallomer Ltd
• Univ Hiroshima

Inventors

• Hikosaka Masamichi
• Okada Kiyoka
• Washiyama Junichiro
• Nakajima Takeshi
• Akiyama Yuka
• Ueno Shingo

Classifications

• B29C43/222 Primary

  characterised by the shape of the surface · CPC title

• B29C43/52 Primary

  Heating or cooling · CPC title

• B29C43/24

  Calendering · CPC title

• Y10T428/31913

  Monoolefin polymer · CPC title

• C08F10/02

  Ethene · CPC title