Ceramic matrix composite material part

Patent metadata

Field	Value
Publication number	US-9604886-B2
Application number	US-201214365252-A
Country	US
Kind code	B2
Filing date	Nov 22, 2012
Priority date	Dec 13, 2011
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

A part made of ceramic matrix composite material has fiber reinforcement of carbon or ceramic fibers and a majority-ceramic sequenced matrix having first matrix layers made of crack-deflector material alternating with second matrix layers made of ceramic material. An interphase coating is interposed between the fibers and the matrix, and the interphase coating adheres to the fibers and to the matrix, and is formed of at least one sequence constituted by a first elementary layer made of carbon, possibly doped with boron, surmounted by a second elementary layer made of ceramic. The outer elementary interphase layer of the coating is a ceramic layer having an outer surface formed by ceramic grains of size lying essentially in the range 20 nm to 200 nm, with the presence of grains of size greater than 50 nm conferring roughness on the outer surface ensuring mechanical attachment with the adjacent matrix phase.

First claim

The invention claimed is:

1. A part made of ceramic matrix composite material comprising:
fiber reinforcement of carbon or ceramic fibers and a majority-ceramic sequenced matrix having first matrix layers made of crack-deflector material alternating with second matrix layers made of ceramic material;
wherein an interphase coating is interposed between the fibers and the majority-ceramic sequenced matrix, the interphase coating adhering to the fibers and to the majority-ceramic sequenced matrix and being formed of at least one sequence constituted by a first elementary interphase layer made of carbon surmounted by a second elementary interphase layer made of ceramic, the outer second elementary layer of the interphase coating being a ceramic layer having an outer surface formed by ceramic grains of size lying essentially in the range of 20 nm to 200 nm, with the presence of grains of size greater than 50 nm conferring roughness on the outer surface ensuring mechanical attachment with an adjacent first matrix layer.

2. A part according to claim 1 , wherein the first matrix layer adjacent to the interphase coating is made of PyC or BC crack-deflector material.

3. A part according to claim 1 , wherein the interphase coating is made of first elementary interphase layers of boron-doped carbon alternating with second elementary interphase layers of ceramic, and in each first elementary interphase layer, the atomic percentage of boron lies in the range of 5% to 20%.

4. A part according to claim 1 , wherein the or each first elementary interphase layer of the interphase coating has mean thickness lying in the range of 20 nm to 500 nm.

5. A part according to claim 1 , wherein the or each second elementary interphase layer of the interphase coating is made of silicon carbide.

6. A part according to claim 1 , wherein the or each second elementary interphase layer of the interphase coating has mean thickness lying in the range of 20 nm to 500 nm.

7. A part according to claim 1 , wherein the total mean thickness of the interphase coating lies in the range of 0.10 μm to 4 μm.

Assignees

• Herakles
• Centre Nat Rech Scient

Inventors

• Lamouroux Franck
• Bertrand Sebastien
• Jacques Sylvain
• Louchet Caroline

Classifications

• C04B35/62894

  with more than one coating layer · CPC title

• C04B35/6286

  Carbides · CPC title

• C04B2235/96

  Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance · CPC title

• Y10T428/259

  Silicic material · CPC title

• C04B35/62897

  Coatings characterised by their thickness · CPC title