Lithium disilicate glass-ceramic, method for production thereof and use thereof

Patent metadata

Field	Value
Publication number	US-9604873-B2
Application number	US-201414586229-A
Country	US
Kind code	B2
Filing date	Dec 30, 2014
Priority date	Dec 23, 2009
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallization and, after complete crystallization, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.

First claim

The invention claimed is:

1. A lithium silicate glass-ceramic having lithium disilicate as main crystal phase, comprising:
58 to 64% by weight of SiO 2 ,
11 to 13% by weight of Li 2 O,
10 to 15% by weight of a stabiliser selected from the group consisting of ZrO 2 , HfO 2 and mixtures thereof,
2 to 5% by weight of K 2 O,
2 to 5% by weight of Al 2 O 3 ,
0 to 5% by weight of additives selected from the group consisting of boron oxide, phosphorus oxide, fluorine, sodium oxide, barium oxide, strontium oxide, magnesium oxide, zinc oxide, calcium oxide, yttrium oxide, titanium oxide, niobium oxide, tantalum oxide, lanthanum oxide and mixtures thereof, and
0 to 10% by weight of colourants.

2. The lithium silicate glass-ceramic according to claim 1 , wherein the colourants are glass-colouring oxides and/or pigments.

3. The lithium silicate glass-ceramic according to claim 2 , wherein the glass-colouring oxides are selected from the group consisting of oxides of iron, titanium, cerium, copper, chromium, cobalt, nickel, manganese, selenium, silver, indium, gold, and rare earth metals.

4. The lithium silicate glass-ceramic according to claim 3 , wherein the rare earth metals are selected from the group consisting of neodymium, praseodymium, samarium and europium.

5. The lithium silicate glass-ceramic according to claim 2 , wherein the pigments are doped spinels.

6. A method for the production of a lithium silicate glass-ceramic of claim 1 , comprising the steps of:
a) producing an initial glass which comprises the composition of:
58 to 64% by weight of SiO 2 ,
11 to 13% by weight of Li 2 O,
10 to 15% by weight of the stabiliser selected from the group consisting of ZrO 2 , HfO 2 and mixtures thereof,
2 to 5% by weight of K 2 O,
2 to 5% by weight of Al 2 O 3 ,
0 to 5% by weight of additives selected from the group consisting of boron oxide, phosphorus oxide, fluorine, sodium oxide, barium oxide, strontium oxide, magnesium oxide, zinc oxide, calcium oxide, yttrium oxide, titanium oxide, niobium oxide, tantalum oxide, lanthanum oxide and mixtures thereof, and
0 to 10% by weight of colourants,

b) subjecting the initial glass to a first heat treatment in order to produce a glass-ceramic which has lithium metasilicate as main crystal phase,
c) subjecting the glass-ceramic of b) to a second heat treatment in which the lithium metasilicate is converted with SiO 2 from the initial glass into lithium disilicate and subsequently lithium disilicate is present as main crystal phase.

7. The method according to claim 6 , wherein the first heat treatment is effected at a temperature of 620° C. to 800° C. over a period of time of 1 to 200 min.

8. The method according to claim 7 , wherein the second heat treatment is effected at a temperature of 800° C. to 1,040° C. over a period of time of 5 to 200 min.

9. A dental material comprising the lithium silicate glass-ceramic according to claim 1 .

10. A shaped dental product comprising the lithium silicate glass-ceramic according to claim 1 .

11. The shaped dental product according claim 10 , which is an inlay, an onlay, a bridge, a pin construction, a veneer, or a crown.

Assignees

• Fraunhofer Ges Forschung
• Vita Zahnfabrik H Rauter Gmbh & Co Kg
• Degudent Gmbh

Inventors

• Durschang Bernhard
• Probst Jörn
• Thiel Norbert
• Bibus Joachim
• Vollmann Markus
• Schusser Udo

Classifications

• A61K6/824

  comprising transition metal oxides · CPC title

• A61K6/78

  Pigments · CPC title

• A61K6/822

  comprising rare earth metal oxides · CPC title

• A61K6/833

  Glass-ceramic composites · CPC title

• A61K6/816

  comprising titanium oxide · CPC title