Glass and optical element production method

Patent metadata

Field	Value
Publication number	US-9604872-B2
Application number	US-201314410519-A
Country	US
Kind code	B2
Filing date	Jun 21, 2013
Priority date	Jun 22, 2012
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

[Problem] The transmittance of glass can be dramatically improved as a result of this glass production method. In addition, the amount of rare metal, such as platinum, that melts into glass can be greatly reduced. [Solution] A glass production method whereby the water content in molten glass is increased, in a melting step (i) in which a glass raw material including at least one type of component among TiO 2 , Nb 2 O 5 , WO 3 , and Bi 2 O 3 is heated inside a melting container and melted, and a molten glass is obtained.

First claim

The invention claimed is:

1. An optical glass production method comprising carrying out a procedure to increase a water content in a molten glass during a melting step (i) of a glass raw material including at least one of TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 in a melting container to thereby obtain the molten glass, wherein the optical glass has a total content of TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 of 20 mol % or more and a P 2 O 5 content of 7 to 40 mol %, and the optical glass satisfies at least one selected from a group consisting of the following (a), (b), (c) and (d):
(a) a total amount of P 2 O 5 , SiO 2 , B 2 O 3 , TiO 2 , Nb 2 O 5 , WO 3 , Bi 2 O 3 , MgO, CaO, SrO, BaO, ZnO, Li 2 O, Na 2 O, K 2 O, Al 2 O 3 , ZrO 2 , GeO 2 , TeO 2 and Sb 2 O 3 is 90 mol % or more,
(b) a glass transition temperature Tg is 541° C. or more,
(c) a content of Nb 2 O 5 is 5 mol % or more, and
(d) a content of TiO 2 is 1 mol % or more.

2. The optical glass production method as set forth in claim 1 , wherein said optical glass is phosphate glass.

3. The optical glass production method as set forth in claim 2 , wherein said optical glass has a content of P 2 O 5 larger than a content of SiO 2 , and larger than a content of B 2 O 3 in terms of mol % expression.

4. The optical glass production method as set forth in claim 1 , wherein said optical glass is substantially free of vanadium.

5. The optical glass production method as set forth in claim 1 , wherein said procedure to increase the water content in said molten glass is carried out by at least one of a treatment of adding water vapor in a melting atmosphere and a treatment of bubbling a gas including water vapor in a molten material of the optical glass.

6. The optical glass production method as set forth in claim 1 , wherein said melting container is made of a metal material.

7. The optical glass production method as set forth in claim 1 , wherein an oxygen partial pressure within the melting container during said melting step (i) is lower than an oxygen partial pressure in air.

8. The optical glass production method as set forth in claim 1 further comprising
step (ii) of draining out said molten glass from said melting container,
step (iii) of molding said molten glass; and at least one of said step (ii) and said step (iii) are carried out under oxidizing atmosphere.

9. The optical glass production method as set forth in claim 8 , wherein said oxidizing atmosphere is an air atmosphere or an atmosphere having higher oxygen partial pressure than air.

10. The optical glass production method as set forth in claim 1 , further comprising step (iv) of heat treating said optical glass; and said step (iv) is carried out under oxidizing atmosphere.

11. A production method of an optical element comprising,
step of producing an optical glass by the production method as set forth in claim 1 , and
step of further molding or processing said optical glass.

12. The optical glass production method as set forth in claim 1 , wherein said procedure to increase the water content in said molten glass is carried out by at least one of a treatment of adding water vapor in a melting atmosphere, a treatment of bubbling a gas including water vapor in a molten material of the optical glass, and a treatment of melting the optical glass containing water in a sealed space.

13. A glass production method comprising a melting step (i) carrying out a heating and melting a glass raw material including at least one of TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 in a melting container to thereby obtaining a molten glass, and
a step (iv) of heat treating the obtained glass, wherein a procedure to increase a water content in a molten glass is carried out during the melting step (i),
wherein the glass has a P 2 O 5 content of 7 to 40 mol %, and the glass satisfies at least one selected from a group consisting of the following (a), (b), (c) and (d):
(a) a total amount of P 2 O 5 , SiO 2 , B 2 O 3 , TiO 2 , Nb 2 O 5 , WO 3 , Bi 2 O 3 , MgO, CaO, SrO, BaO, ZnO, Li 2 O, Na 2 O, K 2 O, Al 2 O 3 , ZrO 2 , GeO 2 , TeO 2 and Sb 2 O 3 is 90 mol % or more,
(b) a glass transition temperature Tg is 541° C. or more,
(c) a content of Nb 2 O 5 is 5 mol % or more, and
(d) a content of TiO 2 is 1 mol % or more.

14. The glass production method as set forth in claim 13 , wherein a total content of TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 included in said glass is 20 mol % or more.

15. The glass production method as set forth in claim 13 , wherein said glass is phosphate glass.

16. The glass production method as set forth in claim 15 , wherein said glass has a content of P 2 O 5 larger than a content of SiO 2 , and larger than a content of B 2 O 3 in terms of mol % expression.

17. The glass production method as set forth in claim 13 , wherein said glass is substantially free of vanadium.

18. The glass production method as set forth in claim 13 , wherein said procedure to increase the water content in said molten glass is carried out by at least one of a treatment of adding water vapor in a melting atmosphere and a treatment of bubbling a gas including water vapor in a molten material of the optical glass.

19. The glass production method as set forth in claim 13 , wherein said melting container is made of a metal material.

20. The glass production method as set forth in claim 13 , wherein an oxygen partial pressure within the melting container during said melting step (i) is lower than the oxygen partial pressure in air.

21. The glass production method as set forth in claim 13 , further comprising
step (ii) of draining out said molten glass from said melting container,
step (iii) of molding said molten glass; and at least one of said step (ii) and said step (iii) are carried out under oxidizing atmosphere.

22. The glass production method as set forth in claim 21 , wherein said oxidizing atmosphere is an air atmosphere or an atmosphere having higher oxygen partial pressure than air.

23. A production method of an optical element comprising,
step of producing a glass by the production method as set forth in claim 13 , and
step of further molding or processing said glass.

Assignees

• Mikami Shuhei
• Fujiwara Yasuhiro
• Hoya Corp

Inventors

• Mikami Shuhei
• Fujiwara Yasuhiro

Classifications

• C03C3/21 Primary

  containing titanium, zirconium, vanadium, tungsten or molybdenum · CPC title

• C03B5/16 Primary

  Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces · CPC title

• C03B5/43

  Use of materials for furnace walls, e.g. fire-bricks · CPC title

• C03C3/064 Primary

  containing boron · CPC title

• C03C3/068

  containing rare earths · CPC title