Light transmitting metal oxide sintered body manufacturing method and light transmitting metal oxide sintered body

Patent metadata

Field	Value
Publication number	US-9604853-B2
Application number	US-201314766196-A
Country	US
Kind code	B2
Filing date	Dec 19, 2013
Priority date	Feb 8, 2013
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Provided is a light transmitting metal oxide sintered body manufacturing method for obtaining a light transmitting sintered body, the main component of which is metal oxide, by carrying out hot isostatic pressing at a HIP heat processing temperature (T) set in a temperature range of 1000-2000° C. The light transmitting metal oxide sintered body manufacturing method, by which light transmitting properties can be improved, is characterized by the following: in the temperature elevating step of the hot isostatic pressing, a temperature range (S) from room temperature to the HIP heat processing temperature (T) is divided into a plurality of stages; for each divided stage the temperature elevation rate is controlled; and the temperature elevation rate of a final stage (14) that includes at least the HIP heat processing temperature (T) is 10° C./h to 180° C./h.

First claim

The invention claimed is:

1. A method for manufacturing a light-transmissive metal oxide sintered body comprising:
subjecting a sintered body composed mainly of metal oxide to hot isostatic pressing (HIP) treatment at a HIP heat treatment temperature T set in a range of 1,000 to 2,000° C. to form a light-transmissive sintered body,
wherein the HIP treatment includes heating at a ramp rate over a temperature range from room temperature to the HIP heat treatment temperature T, the temperature range is divided into a plurality of stages, the ramp rate is controlled in each divided stage, and the ramp rate of at least a final stage inclusive of the HIP heat treatment temperature T is 10° C./h to 60° C./h.

2. The method of claim 1 wherein the temperature range of the heating step is equally divided into 2 to 20 stages.

3. The method of claim 1 wherein in the heating step of the HIP treatment, the final stage is conducted at a ramp rate of 10° C./h to 60° C./h and the remaining stages are conducted at a ramp rate of 200° C./h to 800° C./h.

4. The method of claim 1 wherein in the heating step of the HIP treatment, all stages are conducted at a ramp rate of 10° C./h to 60° C./h.

5. The method of claim 1 wherein the sintered body is prepared using a particulate oxide of at least one metal element selected from the group consisting of Mg, Y, Sc, lanthanides, Ti, Zr, Al, Ga, Si, Ge, Pb, and Bi.

6. The method of claim 5 , comprising press molding the metal oxide particles into a body of predetermined shape, sintering the body, and subjecting the sintered body to the HIP treatment.

7. The method of claim 1 wherein the sintered body is a sesquioxide sintered body which is prepared using a powder consisting of particulate oxides of at least one rare earth element selected from the group consisting of Y, Sc, Lu, Tb, Yb, Gd, Nd, Eu, Ho, Dy, Tm, Sm, Pr, Ce, and Er and particulate Zr oxide, wherein the amount of the particulate Zr oxide added is up to 1% by weight, exclusive of 0% by weight.

8. The method of claim 1 wherein the sintered body is prepared using a particulate oxide of yttria-stabilized zirconia, Al 2 O 3 -26 wt % MgO, lead lanthanum zirconate titanate, alumina, Y 3 Al 5 O 12 , Lu 3 Al 5 O 12 , Tb 3 Ga 5 O 12 , Bi 4 Ge 3 O 12 or Gd 2 SiO 5 .

Assignees

• Shinetsu Chemical Co

Inventors

• Ikari Masanori
• Shimada Tadakatsu

Classifications

• C04B2235/786

  Micrometer sized grains, i.e. from 1 to 100 micron · CPC title

• C04B2235/3296

  Lead oxides, plumbates or oxide forming salts thereof, e.g. silver plumbate · CPC title

• C04B2235/3232

  Titanium oxides or titanates, e.g. rutile or anatase · CPC title

• C04B2235/3224

  Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide · CPC title

• C04B35/505

  based on yttrium oxide · CPC title