Method and system for separation of a polymer from multiple compounds

Patent metadata

Field	Value
Publication number	US-9604156-B2
Application number	US-201414481229-A
Country	US
Kind code	B2
Filing date	Sep 9, 2014
Priority date	Sep 25, 2013
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Methods, devices, and systems that can be utilized in separating a polymer from other compounds of a polymer formation process are described. The methods utilize multiple sedimentors in a countercurrent flow design in conjunction with different solvent solutions in the multiple sedimentors to separate a product polymer from other compounds of a polymer formation process. The sedimentors include feed inlets that can encourage contact between countercurrent flows and improve mass transfer rates between the countercurrent flows.

First claim

What is claimed is:

1. A method for washing a polyarylene sulfide, the method comprising:
introducing a first slurry into a first sedimentor, wherein the first slurry contains a solid polyarylene sulfide and a liquid;
flowing a first solvent that contains an organic amide through the first sedimentor in a direction countercurrent to the first slurry, wherein the first slurry contacts the first solvent to form a second slurry;
introducing the second slurry into a second sedimentor; and
flowing a second solvent that contains water through the second sedimentor in a direction countercurrent to the second slurry, wherein the second slurry contacts the third solvent to form a third slurry, wherein at least one of the first sedimentor and the second sedimentor contain a fluidized bed that includes the solid polymer, the method further comprising monitoring and controlling the height of the fluidized bed.

2. The method of claim 1 , wherein the solvent ratio of the first sedimentor is from about 1.5 to about 3.

3. The method of claim 1 , wherein the solvent ratio of the first and/or the second sedimentor is from about 3 to about 4.5.

4. The method of claim 1 , wherein the first slurry is introduced into a middle section of the first sedimentor via a slurry inlet, the slurry inlet being substantially tangent to a wall of the middle section.

5. The method of claim 1 , wherein the polyarylene sulfide is a polyphenylene sulfide.

6. The method of claim 1 , further comprising agitating the contents of the first sedimentor and the second sedimentor.

7. The method of claim 1 , the first and the second sedimentor each have a middle section having a first and second height, respectively, wherein variation in the height of the fluidized bed during the process is less than about 10% of the height of the middle section.

8. The method of claim 1 , further comprising heating the one or more components of the contents of at least one of the first sedimentor and the second sedimentor.

9. The method of claim 1 , wherein a liquid that exits the second sedimentor is recycled to the first sedimentor.

10. The method of claim 1 , further comprising introducing the third slurry into a third sedimentor and flowing a third solvent that contains water through the third sedimentor in a direction countercurrent to the third slurry.

11. The method of claim 10 , further comprising agitating the contents of the third sedimentor.

12. The method of claim 10 , further comprising heating the third solvent.

13. The method of claim 10 , wherein the third sedimentor contains a fluidized bed that includes the polyarylene sulfide, the method further comprising monitoring and controlling the height of the fluidized bed.

14. The method of claim 13 , the third sedimentor including a middle section having a height, wherein variation in the height of the fluidized bed during the process is less than about 10% of the height of the middle section.

15. The method of claim 10 , wherein a liquid that exits the third sedimentor is recycled to the second sedimentor.

16. The method of claim 1 , further comprising feeding a slurry to one or more additional sedimentors, the one or more additional sedimentors being in series with the first and second sedimentors.

17. The method of claim 1 , wherein the liquid in the first slurry is N-methylpyrrolidone.

18. The method of claim 1 , wherein the organic amide of the first solvent is N-methylpyrrolidone.

19. The method of claim 1 , wherein the first solvent contains a mixture of the organic amide and water.

20. The method of claim 1 , wherein the second solvent contains only water.

21. The method of claim 1 , wherein the second solvent contains water and an acid.

22. The method of claim 10 , wherein the third solvent contains only water.

23. The method of claim 1 , further comprising removing a first liquid from the first sedimentor, the first liquid comprising an organic amide.

24. The method of claim 23 , wherein the first liquid contains a mixture of the organic amide and water.

25. The method of claim 1 , further comprising removing a second liquid from the second sedimentor, the second liquid comprising an organic amide.

26. The method of claim 25 , wherein the first liquid contains a mixture of the organic amide and water.

27. A method for separating a solid polymer from multiple compounds comprising:
introducing a first slurry into a first sedimentor, the first slurry including the solid polymer, a liquid carrier, and multiple compounds of formation of the polymer;
introducing a first solvent into the first sedimentor, the first slurry flowing through the first sedimentor countercurrent to the first solvent within at least a portion of the first sedimentor, one or more compounds of formation of the polymer being soluble in the first solvent, the one or more first solvent soluble compounds transferring from the first slurry to the first solvent within the first sedimentor, the first slurry thus being transformed and forming a second slurry;
introducing the second slurry into a second sedimentor wherein at least one of the first sedimentor and the second sedimentor contain a fluidized bed that includes the solid polymer,
introducing a second solvent into the second sedimentor, the second solvent differing from the first solvent, the second slurry flowing through the second sedimentor countercurrent to the second solvent within at least a portion of the second sedimentor, one or more compounds of formation of the polymer being soluble in the second solvent, the one or more second solvent soluble compounds transferring from the second slurry to the second solvent within the second sedimentor, the second slurry thus being transformed and forming a third slurry; and
monitoring and controlling the height of the fluidized bed in the first sedimentor, the second sedimentor, or both.

28. The method of claim 27 , wherein the first slurry is introduced into a middle section of the first sedimentor via a slurry inlet, the slurry inlet being substantially tangent to a wall of the middle section.

29. The method of claim 27 , wherein the polymer is a polyphenylene sulfide.

30. The method of claim 27 , further comprising agitating the contents of the first sedimentor and the second sedimentor.

31. The method of claim 27 , the first and the second sedimentor each have a middle section having a first and second height, respectively, wherein variation in the height of the fluidized bed during the process is less than about 10% of the height of the middle section.

32. The method of claim 27 , further comprising heating the one or more components of the contents of at least one of the first sedimentor and the second sedimentor.

33. The method of claim 27 , wherein a liquid that exits the second sedimentor is recycled to the first sedimentor.

34. The method of claim 27 , further comprising introducing the third slurry into a third sedimentor and introducing a third solvent into the third sedimentor, the third slurry flowing through the third sedimentor countercurrent to the third solvent within at least a portion of the third sedimentor.

35. The method of claim 34 , further comprising agitating the contents of the third sedimentor.

Assignees

• Ticona Llc

Inventors

• Nekkanti Venkata
• Haubs Michael

Classifications

• B03B5/623

  Upward current classifiers · CPC title

• B01D11/0242 Primary

  in towers, e.g. comprising contacting elements · CPC title