Anode materials for lithium-ion batteries

Patent metadata

Field	Value
Publication number	US-9601773-B2
Application number	US-201414182338-A
Country	US
Kind code	B2
Filing date	Feb 18, 2014
Priority date	Aug 19, 2011
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

The current disclosure relates to an anode material with the general formula M y Sb-M′O x —C, where M and M′ are metals and M′O x —C forms a matrix containing M y Sb. It also relates to an anode material with the general formula M y Sn-M′C x —C, where M and M′ are metals and M′C x —C forms a matrix containing M y Sn. It further relates to an anode material with the general formula Mo 3 Sb 7 —C, where —C forms a matrix containing Mo 3 Sb 7 . The disclosure also relates to an anode material with the general formula M y Sb-M′C x —C, where M and M′ are metals and M′C x —C forms a matrix containing M y Sb. Other embodiments of this disclosure relate to anodes or rechargeable batteries containing these materials as well as methods of making these materials using ball-milling techniques and furnace heating.

First claim

The invention claimed is:

1. An anode material comprising the general formula Cu 2 Sb—Al 2 O 3 —C, wherein Al 2 O 3 —C forms a matrix containing Cu 2 Sb.

2. An anode material comprising the general formula M y Sb-M′O x —C,
wherein M y Sb is a metal antinomide alloy and M is selected from the group consisting of copper (Cu), molybdenum (Mo), nickel (Ni), titanium (Ti), or tin (Sn), and combinations thereof,
wherein M′O x is a metal oxide and M′ is selected from the group consisting of aluminum (Al), magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), zirconium (Zr), molybdenum (Mo), tungsten (W), niobium (Nb), or tantalum (Ta), and combinations thereof, and
wherein M′O x —C forms a matrix containing particulate M y Sb formed after the anode material has been cycled in an electrochemical cell.

3. The anode material of claim 2 , wherein M y Sb comprises particles with an average diameter of 500 nm or less.

4. The anode material of claim 2 , wherein the matrix comprises a conductive framework of M y that supports Sb.

5. The anode material of claim 2 , wherein M y Sb comprises particles with an average diameter of 200 nm or less.

6. The anode material of claim 2 , wherein M y Sb comprises particles with an average diameter of 100 nm or less.

7. The anode material of claim 2 , wherein M y Sb comprises particles with an average diameter of between 1 nm and 20 nm.

8. The anode material of claim 2 , wherein the anode material has a tap density of greater than 1 g/cm 3 .

9. A rechargeable battery comprising an electrochemical cell comprising an anode comprising an anode material comprising the general formula M y Sb-M′O x —C,
wherein M y Sb is a metal antinomide alloy and M is selected from the group consisting of copper (Cu), molybdenum (Mo), nickel (Ni), titanium (Ti), or tin (Sn), and combinations thereof,
wherein M′O x is a metal oxide and M′ is selected from the group consisting of aluminum (Al), magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), zirconium (Zr), molybdenum (Mo), tungsten (W), niobium (Nb), or tantalum (Ta), and combinations thereof, and
wherein M′O x —C forms a matrix containing particulate M y Sb formed after the anode material has been cycled in the electrochemical cell.

10. A rechargeable battery of claim 9 , comprising the general formula Cu 2 Sb—Al 2 O 3 —C, wherein Al 2 O 3 —C forms a matrix containing Cu 2 Sb.

11. The rechargeable battery of claim 9 , wherein M y Sb comprises particles with an average diameter of 500 nm or less.

12. The rechargeable battery of claim 9 , wherein the matrix comprises a conductive framework of M y that supports Sb.

13. The rechargeable battery of claim 9 , wherein M y Sb comprises particles with an average diameter of 200 nm or less.

14. The rechargeable battery of claim 9 , wherein M y Sb comprises particles with an average diameter of 100 nm or less.

15. The rechargeable battery of claim 9 , wherein M y Sb comprises particles with an average diameter of between 1 nm and 20 nm.

16. The rechargeable battery of claim 9 , wherein the anode material has a tap density of greater than 1 g/cm 3 .

17. The rechargeable battery of claim 9 , wherein the anode has a gravimetric capacity of between 380 and 650 mAh/g.

18. The rechargeable battery of claim 9 , wherein the anode has a volumetric capacity of between 450 and 1,000 Ah/L.

19. The rechargeable battery of claim 9 , wherein the battery retains at least 70% of its gravimetric or volumetric capacity after at least 1000 cycles.

20. The rechargeable battery of claim 9 , wherein the battery retains at least 70% of its gravimetric or volumetric capacity after at least 2000 cycles.

Assignees

• Manthiram Arumugam
• Applestone Danielle
• Yoon Sukeun
• Univ Texas

Inventors

• Manthiram Arumugam
• Applestone Danielle
• Yoon Sukeun

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C01G39/006

  Compounds containing molybdenum, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• C01P2006/40

  Electric properties · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title