Hydrogen storage heat pump and hydrogen storage heat pump system

Patent metadata

Field	Value
Publication number	US-9599373-B2
Application number	US-201514658031-A
Country	US
Kind code	B2
Filing date	Mar 13, 2015
Priority date	May 30, 2014
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

A hydrogen storage heat pump, including: a hydrogen storage unit in which hydrogen gas is stored in a compressed state; a hydrogen flow tube through which the hydrogen gas, which is supplied from the hydrogen storage unit, flows; plural hydrogen absorbing materials that are provided at the hydrogen flow tube, that each have a different absorption pressure at which hydrogen is absorbed, and that are arranged in an order such that the absorption pressure decreases in a hydrogen gas flow direction from the hydrogen storage unit; and a switching valve that is disposed between the hydrogen absorbing materials in the hydrogen flow tube and that switches a flow rate of the hydrogen gas.

First claim

What is claimed:

1. A hydrogen storage heat pump, comprising:
a hydrogen storage unit in which hydrogen gas is stored in a compressed state;
a hydrogen flow tube through which the hydrogen gas, which is supplied from the hydrogen storage unit, flows;
a plurality of hydrogen absorbing materials that are provided at the hydrogen flow tube, that each have a different absorption pressure at which hydrogen is absorbed, and that are arranged in an order such that the absorption pressure decreases in a hydrogen gas flow direction from the hydrogen storage unit; and
a switching valve that is disposed between the hydrogen absorbing materials in the hydrogen flow tube and that switches a flow rate of the hydrogen gas.

2. The hydrogen storage heat pump according to claim 1 , wherein each of the hydrogen absorbing materials is a fibrous carbon material or a hydrogen absorbing alloy.

3. The hydrogen storage heat pump according to claim 1 , wherein each of the hydrogen absorbing materials is a hydrogen absorbing alloy, and the plurality of hydrogen absorbing alloys are arranged in an order such that a hydrogen equilibrium pressure, which corresponds to the absorption pressure, decreases in the hydrogen flow direction from the hydrogen storage unit.

4. The hydrogen storage heat pump according to claim 1 , wherein a plurality of the hydrogen flow tubes are provided, and a plurality of the hydrogen absorbing materials, that each have a different absorption pressure at which hydrogen is absorbed, and that are arranged in an order such that the absorption pressure decreases in the hydrogen flow direction from the hydrogen storage unit, are provided in each of the plurality of hydrogen flow tubes.

5. The hydrogen storage heat pump according to claim 4 , wherein, in the plurality of hydrogen absorbing materials that are arranged at the respective hydrogen flow tubes, the respective hydrogen absorbing materials that are located at an m-th position, wherein m≧1, from the hydrogen storage unit comprise the same hydrogen absorbing material as each other.

6. The hydrogen storage heat pump according to claim 4 , wherein the plurality of hydrogen absorbing materials that are arranged at the respective hydrogen flow tubes alternately desorb and absorb hydrogen gas in the hydrogen gas flow direction of the respective hydrogen flow tubes.

7. The hydrogen storage heat pump according to claim 6 , wherein the plurality of hydrogen flow tubes are configured such that the plurality of hydrogen absorbing materials on the plurality of hydrogen gas flow tubes located in odd-numbered positions alternately desorb and absorb hydrogen gas in this order in the hydrogen gas flow direction from the hydrogen storage unit side, and the plurality of hydrogen absorbing materials on the plurality of hydrogen flow tubes located in even-numbered positions alternately absorb and desorb hydrogen gas in this order in the hydrogen gas flow direction from the hydrogen storage unit side.

8. The hydrogen storage heat pump according to claim 4 , wherein a first hydrogen flow tube and a second hydrogen flow tube are provided, and in a case in which the hydrogen absorbing materials that are located at odd-numbered positions from the hydrogen storage unit side desorb hydrogen gas and the hydrogen absorbing materials located at even-numbered positions from the hydrogen storage unit side absorb hydrogen gas in the first hydrogen flow tube, the hydrogen absorbing materials that are located at odd-numbered positions from the hydrogen storage unit side absorb hydrogen gas and the hydrogen absorbing materials located at even-numbered positions from the hydrogen storage unit side desorb hydrogen gas in the second hydrogen flow tube.

9. The hydrogen storage heat pump according to claim 1 , further comprising:
a first heat source that is thermally connected to a hydrogen absorbing material in a case in which the hydrogen absorbing material desorbs hydrogen, and recovers cold heat from the hydrogen absorbing material in order to utilize the cold heat in a cold heat utilization apparatus; and
a second heat source that is thermally connected to the hydrogen absorbing material in a case in which the hydrogen absorbing material absorbs hydrogen, and recovers hot heat from the hydrogen absorbing material for utilizing the hot heat in a hot heat utilization apparatus.

10. The hydrogen storage heat pump according to claim 9 , wherein a temperature t 1 of the first heat source and a temperature t 2 of the second heat source satisfy a relationship of temperature t 1 ≦temperature t 2 .

11. The hydrogen storage heat pump according to claim 10 , wherein an absorption pressure p 1 at which hydrogen is absorbed at a temperature of the first heat source and an absorption pressure p 2 at which hydrogen is absorbed at a temperature of the second heat source satisfy a relationship of p 1 ≧p 2 .

12. A heat pump system comprising:
the hydrogen storage heat pump according to claim 1 ; and
a hydrogen utilization apparatus that is connected to the hydrogen flow tube of the hydrogen storage heat pump and to which depressurized hydrogen gas is supplied.

Assignees

• Toyota Chuo Kenkyusho Kk

Inventors

• Yamauchi Takafumi
• Hirota Yasuki
• Aoki Masakazu
• Shimazu Takashi

Classifications

• Y02B30/62

  Absorption based systems · CPC title

• Y02E60/324

  Cross-Sectional Technologies · mapped topic

• F25B17/12 Primary

  using desorption of hydrogen from a hydride · CPC title

• Y02A30/27

  Relating to heating, ventilation or air conditioning [HVAC] technologies · CPC title

• Y02E60/32

  Hydrogen storage · CPC title