Method for producing ferroalloy containing nickel

Patent metadata

Field	Value
Publication number	US-9598748-B2
Application number	US-201314136038-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Feb 11, 2009
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

The invention relates to a method for producing a ferroalloy containing nickel. From a fine-grained raw material containing iron and chromium and a fine-grained raw material containing nickel, a mixture is formed with binding agent, the mixture is agglomerated so that first formed objects of desired size are obtained. The objects formed are heat treated in order to strengthen the objects so that the heat treated objects withstand conveyance and loading into a smelter furnace. Further, the objects are smelted under reducing circumstances in order to achieve ferrochromenickel, a ferroalloy of a desired composition containing at least iron, chromium and nickel.

First claim

What is claimed is:

1. A method for producing a nickel containing ferroalloy, comprising:
forming a mixture of a raw material containing iron and chromium, a raw material containing nickel, and a binder material,
agglomerating the mixture at atmospheric pressure to form objects having a desired size,
heat-treating the objects for removal of water of crystallization bound in the raw material, whereby the raw material containing nickel is calcinated and the objects are strengthened so that the heat-treated objects are conveyable, and
smelting the objects under reducing conditions in order to produce ferrochromenickel containing chromium to nickel in a ratio between 2.6 and 3.0,
and wherein the raw material containing iron and chromium supplies substantially all the iron and chromium in the ferrochromenickel.

2. A method according to claim 1 , wherein agglomeration comprises pelletizing.

3. A method according to claim 1 , wherein heat-treating comprises sintering.

4. A method according to claim 1 , wherein a proportion of nickel-bearing material in the mixture is 10-25 weight %.

5. A method according to claim 1 , comprising heat-treating the objects at a temperature in the range from 1000−1400° C.

6. A method according to claim 1 , characterized in that what is used as the nickel containing raw material, is carbonate nickel materials, sulfate nickel materials, or sulfidic nickel materials.

7. A method according to claim 1 , characterized in that the pellet mixture formed of nickel containing material and iron containing chromite concentrate is simultaneously calcined and desulphurized in connection within the sintering process.

8. A method according to claim 1 , characterized in that the agglomerated and smelted ferrochromenickel contains 40-45 weight % chromium, 18-24 weight % nickel, 3-5 weight % carbon, the rest iron and inevitable impurities.

9. A method for producing a nickel containing ferroalloy, comprising:
forming a mixture of a raw material containing iron and chromium, a raw material containing nickel, and a binder material,
agglomerating the mixture to form objects having a desired size,
heat-treating the objects for removal of water of crystallization bound in the raw material, whereby the raw material containing nickel is calcinated and the objects are strengthened so that the heat-treated objects are conveyable, and
smelting the objects under reducing conditions in order to produce ferrochromenickel containing chromium and nickel in a ratio between 1.5 and 5,
and wherein the raw material containing iron and chromium supplies substantially all the iron and chromium in the ferrochromenickel, and further characterized in that what is used as a raw material containing nickel, is nickel-bearing hydroxidic intermediate products precipitated from leach liquors of at least one of hydrometallurgical processes of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

10. A method according to claim 9 , characterized in that what is used as a raw material containing nickel, is an intermediate product from pressure leaching of at least one of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

11. A method according to claim 9 , characterized in that what is used as a raw material containing nickel, is an intermediate product received from atmospheric leaching of at least one of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

12. A method according to claim 9 , characterized in that what is used as a raw material containing nickel, is an intermediate product received from heap leaching of at least one of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

13. A method according to claim 9 , characterized in that what is used as a raw material containing nickel, is an intermediate product received from a solvent extraction process of at least one of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

14. A method according to claim 9 , characterized in that what is used as a raw material containing nickel, is an intermediate product received from an ion exchange process of at least one of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

15. A method according to claim 9 , characterized in that what is used as a raw material containing nickel, is an intermediate product received from a refining process of at least one of lateritic nickel ores and nickel-bearing concentrates or process precipitates of lateritic nickel ores.

16. A method for producing a nickel containing ferroalloy, comprising:
forming a mixture of a raw material containing iron and chromium, a raw material containing nickel, and a binder material,
agglomerating the mixture to form objects having a desired size,
heat-treating the objects for removal of water of crystallization bound in the raw material, whereby the raw material containing nickel is calcinated and the objects are strengthened so that the heat-treated objects are conveyable, and
smelting the objects under reducing conditions in order to produce ferrochromenickel containing chromium and nickel in a ratio between 1.5 and 5,
and wherein the raw material containing iron and chromium supplies substantially all the iron and chromium in the ferrochromenickel, and further characterized in that what is used as a raw material containing nickel, is nickel-bearing hydroxidic intermediate products precipitated from leach liquors from at least one of hydrometallurgical processes of sulfidic nickel ores and nickel-bearing concentrates or process precipitates of sulfidic ores.

17. A method according to claim 16 , characterized in that what is used as the nickel containing raw material, is intermediate products received from the pressure leaching of at least one of sulfidic nickel ores and nickel-bearing concentrates or process precipitates of sulfidic ores.

18. A method according to claim 16 , characterized in that what is used as the nickel containing raw material, is intermediate products received from the atmospheric leaching of at least one of sulfidic nickel ores and nickel-bearing concentrates or process precipitates of sulfidic ores.

19. A method according to claim 16 , characterized in that what is used as the nickel containing raw material, is intermediate products received from the heap leaching of at least one of sulfidic nickel ores and nickel-bearing concentrates or process precipitates of sulfidic ores.

20. A method according to claim 16 , characterized in that what is used as the nickel containing raw material, is intermediate products received from the solvent extraction process of at least one of sulfidic nickel ores and nickel-bearing concentrates or process precipitates of sulfidic ores.

21. A method according to claim 16 , characterized in that what is used as the nickel containing raw material, is intermediate products received from the ion exchange process of at least one of sulfidic nickel ores and nickel-bearing concentrates or process precipitates of sulfidic ores.

22. A method according to claim 16 , characterized in that what is used as the nickel containing raw material is intermediate products received from the refining process of at least one of sulfidic nickel ores and nickel-bearing concentrates or process precipitates

Assignees

• Outokumpu Oy
• Outotec Oyj

Inventors

• Mäkelä Tuomo
• Niemelä Pekka
• Krogerus Helge

Classifications

• C22C1/02 Primary

  by melting {(C22C1/1036 takes precedence)} · CPC title

• C22C35/005

  based on iron, e.g. ferro-alloys · CPC title

• C22B1/20

  in sintering machines with movable grates · CPC title

• C22B1/243

  inorganic · CPC title

• C22C19/052

  with the maximum Cr content being at least 40% · CPC title