Lubricant composition having improved non-Newtonian viscometrics

Patent metadata

Field	Value
Publication number	US-9598658-B2
Application number	US-201213428919-A
Country	US
Kind code	B2
Filing date	Mar 23, 2012
Priority date	Mar 25, 2011
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C 8 -C 10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C 8 -C 10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C 8 -C 10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.

First claim

What is claimed is:

1. A lubricant composition having improved non-Newtonian viscometrics and comprising:
A. at least 85 weight percent of base oil based on a total weight of said composition; and
B. 2 to 10 weight percent of a lubricant additive based on a total weight of said composition and comprising;
(i) 10 to 80 weight percent of a diluent oil based on a total weight of said additive, and
(ii) 50 to 80 weight percent of a random co-polymeric viscosity index improver based on a total weight of said additive, said viscosity index improver being the free-radical polymerization product of at least:
a) 5 to 13 weight percent of methyl methacrylate based on a total weight of the viscosity index improver,
b) 5 to 66 weight percent of 2-propylheptyl methacrylate based on a total weight of the viscosity index improver,
c) 21 to 78 weight percent of a C 12 -C 18 alkyl (meth)acrylate based on a total weight of the viscosity index improver, and
d) optionally 3.5 to 7 weight percent of a secondary or tertiary amine functional (meth)acrylate based on a total weight of said viscosity index improver; and

wherein said lubricant composition has a Brookfield Viscosity of less than 23,000 mPa·s measured at −40° C. according to ASTM D2983, and wherein said C 12 -C 18 alkyl (meth)acrylate comprises 62 to 78 wt % of molecules having C 12 chain length, 22 to 38 wt % of molecules having C 14 chain length, 0 to 10 wt % of molecules having C 16 chain length, and 0 to 10 wt % of molecules having C 18 chain length.

2. A lubricant composition as set forth in claim 1 having a kinematic viscosity of 2 to 50 mm 2 /s measured at 100° C. according to ASTM D445.

3. A lubricant composition as set forth in claim 2 having a DKA oxidation increase of less than 30 percent measured according to CEC-L-48-00.

4. A lubricant composition as set forth in claim 3 wherein said viscosity index improver has a number average molecular weight of from about 10,000 to about 200,000 g/mol and a weight average molecular weight of from about 20,000 to about 500,000 g/mol.

5. A lubricant composition as set forth in claim 3 wherein said viscosity index improver has a number average molecular weight of from about 10,000 to about 15,000 g/mol and a weight average molecular weight of from about 20,000 to about 30,000 g/mol.

6. A lubricant composition as set forth in claim 3 wherein said viscosity index improver has number average molecular weight of from about 10,000 to about 30,000 g/mol, a weight average molecular weight of from about 20,000 to about 50,000 g/mol, and polydispersity index of from about 1.7 to about 1.8.

Assignees

• Scanlon Eugene
• Desantis Kevin
• Bette Virginie
• Petzoldt Jochen
• Basf Se

Inventors

• Scanlon Eugene
• Desantis Kevin
• Bette Virginie
• Petzoldt Jochen

Classifications

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• C10N2030/08

  Resistance to extreme temperature · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10M149/04

  containing monomers having an unsaturated radical bound to an amino group · CPC title