Refrigerant mixtures comprising difluoromethane, pentafluoroethane, and tetrafluoropropene and uses thereof

Patent metadata

Field	Value
Publication number	US-9598621-B2
Application number	US-201415025741-A
Country	US
Kind code	B2
Filing date	Oct 6, 2014
Priority date	Oct 10, 2013
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

In accordance with the present invention refrigerant compositions are disclosed. The refrigerant compositions contain comprise 11-28 weight percent difluoromethane; 34-59 weight percent pentafluoroethane; and 21-38 weight percent 2,3,3,3-tetrafluoropropene. The refrigerant compositions are useful in processes to produce cooling, in methods for replacing refrigerant R-404A or R-507A, and in refrigeration systems. These inventive refrigerant compositions can be used in stationary and mobile refrigeration equipment, and are particularly useful for transport refrigeration units.

First claim

What is claimed is:

1. A refrigerant composition comprising:
a. 11-22 weight percent difluoromethane;
b. 46-59 weight percent pentafluoroethane; and
c. 21-35 weight percent 2,3,3,3-tetrafluoropropene;
wherein the composition is non-flammable as formulated and determined by ASTM E681 at 60° C.

2. The refrigerant composition of claim 1 , wherein the composition is non-flammable as formulated and after fractionation as determined by ASTM E681 at 60° C.

3. The refrigerant composition of claim 1 further comprising one or more components selected from the group consisting of lubricants, dyes, solubilizing agents, compatibilizers, stabilizers, tracers, perfluoropolyethers, anti-wear agents, extreme pressure agents, corrosion and oxidation inhibitors, metal surface energy reducers, metal surface deactivators, free radical scavengers, foam control agents, viscosity index improvers, pour point depressants, detergents, viscosity adjusters, and mixtures thereof.

4. A refrigeration system comprising an evaporator, a condenser, a compressor and an expansion device, wherein the system contains the composition of claim 1 .

5. The refrigeration system of claim 4 , wherein the compressor discharge temperature is within 20 K of the compressor discharge temperature when R-404A is run at the same operating conditions.

6. The refrigeration system of claim 4 , wherein the compressor discharge temperature is lower than the compressor discharge temperature when either R-407A or R-407F is run at the same operating conditions.

7. The refrigeration system of claim 4 , wherein the average temperature glide in the condenser and evaporator is less than 4.0 K.

8. The refrigeration system of claim 4 , wherein the mass flow is within 10% of the mass flow when R-404A is run at the same operating conditions.

9. The refrigeration system of claim 4 that is a transport refrigeration unit.

10. A method for producing refrigeration comprising evaporating the composition of claim 1 in the vicinity of a body to be cooled and thereafter condensing said composition.

11. A method for replacing R-404A in a refrigeration system comprising removing the R-404A from the refrigeration system and charging the system with the refrigerant composition of claim 1 .

12. The method of claim 11 , wherein the refrigeration capacity produced by the refrigerant composition is within about 10% of that produced by R-404A under the same operating conditions.

13. The method of claim 11 , wherein the coefficient of performance obtained is within about 5% of that produced by R-404A under the same operating conditions.

14. A method for replacing R-507A in a refrigeration system comprising replacing R-507A with the refrigerant composition of claim 1 .

15. The method of claim 14 , wherein the refrigeration capacity produced by the refrigerant composition is within about 10% of that produced by R-507A under the same operating conditions.

16. The method of claim 14 , wherein the coefficient of performance obtained is within about 5% of that produced by R-507A under the same operating conditions.

17. The composition of claim 1 consisting essentially of:
a. 11 weight percent difluoromethane;
b. 59 weight percent pentafluoroethane; and
c. 30 weight percent 2,3,3,3-tetrafluoropropene;
wherein the composition is non-flammable as formulated and after fractionation as determined by ASTM E681 at 60° C.

18. A method of replacing R-404A in a refrigeration system comprising removing the R-404A from the refrigeration system and charging the system with the refrigerant composition of claim 17 , wherein the GWP of the refrigerant composition is less than 2150.

19. A refrigeration system comprising an evaporator, a condenser, a compressor and an expansion device, wherein the system contains the composition of claim 17 ; wherein the GWP of the refrigerant composition is less than 2150; and wherein the average temperature glide in the condenser and evaporator is less than 4.0 K.

20. The refrigeration system of claim 19 that is a transport refrigeration unit.

Assignees

• Chemours Co Fc Llc

Inventors

• Minor Barbara Haviland
• Schultz Kenneth J

Classifications

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• C09K2205/40

  Replacement mixtures · CPC title

• C09K2205/22

  All components of a mixture being fluoro compounds · CPC title

• F25B45/00

  Arrangements for charging or discharging refrigerant · CPC title

• C09K5/045 Primary

  containing only fluorine as halogen · CPC title