Rubber tire compound production method

Patent metadata

Field	Value
Publication number	US-9598559-B2
Application number	US-201414905209-A
Country	US
Kind code	B2
Filing date	Jul 18, 2014
Priority date	Jul 18, 2013
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

A method of producing rubber compounds, in which the polymer base is composed partly of a first polymer material, which is either produced by emulsion polymerization or is natural rubber, and partly of a second polymer material produced by solution polymerization. The method includes a preliminary second polymer material treating step, in which the second polymer material, silica, a silane bonding agent, and at least one nucleophile agent are mixed with one another; a first mixing step, in which at least the first polymer material, silica, and a silane bonding agent are added to the compound resulting from the preliminary second polymer material treating step; and a second mixing step, in which stearic acid and a curing system are added to the compound being produced.

First claim

The invention claimed is:

1. A method for producing a rubber composition comprising a polymer base, in which the polymer base is comprised of a first polymer material which is either a natural rubber or a polymer produced by emulsion polymerization, and a second polymer material produced by solution polymerization; said method being characterized by comprising:
(A) a preliminary said second polymer material treating step, in which the said second polymer material, silica, a silane bonding agent, and at least one nucleophile agent are mixed with one another;
(B) a first polymer material treating step, in which at least the first polymer material, silica, and a silane bonding agent are added to the compound resulting from step (A), and
(C) adding stearic acid and a curing system to produce said rubber composition.

2. The method of producing a rubber composition, as claimed in claim 1 , characterized in that said nucleophile agent is a curing accelerant.

3. The method of producing a rubber composition, as claimed in claim 2 , characterized in that said nucleophile agent is in the guanidine class.

4. The method of producing a rubber composition, as claimed in claim 3 , characterized in that the guanidine class nucleophile agent is selected from the group consisting of diphenyl guanidine (DPG), triphenyl guanidine (TPG), diorthotolyl-guanidine (DOTG), o-tolylbiguanidine (OTBG), guanidine salts (nitrates, carbonates, acetates, thiocyanates, sulphates) and derivatives thereof.

5. The method of producing the rubber composition as claimed in claim 3 , characterized in that 0.6 to 5 phr of the guanidine class nucleophile agent is added in step (A).

6. The method of producing a rubber composition, as claimed in claim 1 , characterized by comprising a preliminary said first polymer material treating step parallel to said preliminary said second polymer material treating step, and in which said first polymer material, silica, a silane bonding agent, and at least one curing accelerant in the sulphenamide class are mixed with one another; at said first mixing step, the compound resulting from said preliminary said first polymer material treating step being mixed with the compound resulting from the preliminary said second polymer material treating step.

7. The method of producing a rubber composition, as claimed in claim 6 , characterized in that the sulphenamide class curing accelerant is selected from the group consisting of benzothiazyl-cyclohexyl-sulphenamide (CBS), N-tert-butyl-2-benzothiazyl sulphenamide (TBBS), 2-mercaptobenzothiazole (MBT), sodium or zinc salts of 2-mercaptobenzothiazole (ZMBT), benzothiazyl-2-dicyclohexyl sulphenamide (DCBS), benzothiazole disulphide (MBTS), tetrabenzylthiuramdisulphide (TBzTD), and mixtures thereof.

8. The method of producing a rubber composition, as claimed in claim 6 , characterized in that 0.6 to 5 phr of the sulphenamide class curing accelerant is mixed with said first polymer material.

9. The method of producing a rubber composition, as claimed in claim 1 , characterized in that said first polymer material and said second polymer material are styrene-butadiene copolymer (SBR)-based.

Assignees

• Bridgestone Corp

Inventors

• Agoretti Pasquale
• Privitera Davide

Classifications

• C08K2003/2296

  of zinc · CPC title

• C08K5/31

  Guanidine; Derivatives thereof · CPC title

• C08J3/24

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title

• B60C1/00

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• C08K5/548 Primary

  containing sulfur {(C08K5/5477 takes precedence)} · CPC title