Halogen-free flame-retardant resin composition, wire and cable

Patent metadata

Field	Value
Publication number	US-9598554-B2
Application number	US-201213475058-A
Country	US
Kind code	B2
Filing date	May 18, 2012
Priority date	May 19, 2011
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

A halogen-free flame-retardant resin composition includes a polyolefin-based resin, a phenolic antioxidant, a metal hydroxide, a pigment comprising one of titanium dioxide, monoazo yellow, benzimidazolone yellow, isoindolinone yellow, quinacridone red and perylene red, and an additive including an amide bond. The additive having the amide bond is added in an amount of 0.01 to 2 parts by weight relative to 100 parts by weight of the polyolefin-based resin.

First claim

What is claimed is:

1. A halogen-free flame-retardant resin composition, consisting of:
a polyolefin-based resin consisting of an ethylene-vinyl acetate copolymer (EVA), or an ethylene-vinyl acetate copolymer (EVA) and a low-density polyethylene (LDPE);
a phenolic antioxidant comprising one of dibutylhydroxytoluene (BHT) and thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], present in an amount of from 1 to 3 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a metal hydroxide present in an amount of from 150 to 300 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a pigment comprising one of monoazo yellow, benzimidazolone yellow, isoindolinone yellow, quinacridone red, and perylene red;
at least one an additive comprising an amide bond selected from the group consisting of 1,3-benzenedicarboxylic acid bis[2-(1-oxo-2-phenoxypropyl)hydrazide], 2-3-bis[[3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl]] propionohydrazide, and dodecanedioic acid bis[N2-(2-hydroxybenzoyl)hydrazide], the at least one additive is present in an amount of from 0.01 to 2 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a 1,3,5-triazine derivative present in an amount of from 5 to 40 parts by weight relative to 100 parts by weight of the polyolefin-based resin,
wherein there is no discoloration between sheets thereof kneaded in temperature conditions of an initiation temperature of 40° C. and a termination temperature of 240° C.

2. The halogen-free flame-retardant resin composition according to claim 1 , wherein the metal hydroxide comprises one of magnesium hydroxide, aluminum hydroxide, and calcium hydroxide.

3. The halogen-free flame-retardant resin composition according to claim 1 , wherein the 1,3,5-triazine derivative comprises one of melamine, cyanuric acid, isocyanuric acid, melamine cyanurate, and melamine sulfate.

4. The halogen-free flame-retardant resin composition according to claim 1 , further comprising a crosslinking agent.

5. A wire, comprising:
a conductor; and
an insulation layer provided over an outer periphery of the conductor, consisting of
a polyolefin-based resin consisting of an ethylene-vinyl acetate copolymer (EVA), or an ethylene-vinyl acetate copolymer (EVA) and a low-density polyethylene (LDPE);
a phenolic antioxidant comprising one of dibutylhydroxytoluene (BHT) and thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], present in an amount of from 1 to 3 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a metal hydroxide present in an amount of from 150 to 300 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a pigment comprising one of monoazo yellow, benzimidazolone yellow, isoindolinone yellow, quinacridone red and perylene red;
at least one an additive comprising an amide bond selected from the group consisting of 1,3-benzenedicarboxylic acid bis[2-(1-oxo-2-phenoxypropyl)hydrazide], 2-3-bis[[3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl]] propionohydrazide, and dodecanedioic acid bis[N2-(2-hydroxybenzoyl)hydrazide], the at least one additive is present in an amount of from 0.01 to 2 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a 1,3,5-triazine derivative present in an amount of from 5 to 40 parts by weight relative to 100 parts by weight of the polyolefin-based resin.

6. The wire according to claim 5 , wherein the insulation layer has a tensile strength of not less than 10 MPa, and an elongation of not less than 150% in tensile testing in compliance with JIS C 3005.

7. The wire according to claim 5 , wherein the burning time thereof in vertical flame testing in compliance with UL subject 758 is less than 1 minute.

8. The wire according to claim 5 , further comprising a sulfur-based antioxidant.

9. The wire according to claim 5 , further comprising a crosslinking agent.

10. A cable, comprising:
one or more wires, each wire comprising
a conductor, and
an insulation layer provided over an outer periphery of the conductor; and

a sheath provided over an outer periphery of the one or more wires, the sheath consisting of
a polyolefin-based resin consisting of an ethylene-vinyl acetate copolymer (EVA), or an ethylene-vinyl acetate copolymer (EVA) and a low-density polyethylene (LDPE);
a phenolic antioxidant comprising one of dibutylhydroxytoluene (BHT) and thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], present in an amount of from 1 to 3 parts by weight relative to 100 parts by weight of the polyolefin-based resin;
a metal hydroxide present in an amount of from 150 to 300 parts by weight relative to 100 parts by weight of the polyolefin-based resin, wherein the metal hydroxides is not a surface-treated metal hydroxide;
a pigment comprising one of monoazo yellow, benzimidazolone yellow, isoindolinone yellow, quinacridone red and perylene red;
at least one an additive comprising an amide bond selected from the group consisting of 1,3-benzenedicarboxylic acid bis[2-(1-oxo-2-phenoxypropyl)hydrazide], 2-3-bis[[3,5-di-tert-butyl-4-hydroxyphenyl] propionyl]] propionohydrazide, and dodecanedioic acid bis[N2-(2-hydroxybenzoyl)hydrazide], the at least one additive is present in an amount of from 0.01 to 2 parts by weight relative to 100 parts by weight of the polyolefin-based resin; and
a 1,3,5-triazine derivative present in an amount of from 5 to 40 parts by weight relative to 100 parts by weight of the polyolefin-based resin.

11. The cable according to claim 10 , wherein the 1,3,5-triazine derivative comprises one of melamine, cyanuric acid, isocyanuric acid, melamine cyanurate, and melamine sulfate.

12. The cable according to claim 10 , wherein the sheath has a tensile strength of not less than 10 MPa, and an elongation of not less than 150% in tensile testing in compliance with JIS C 3005.

13. The cable according to claim 10 , wherein the burning time thereof in vertical flame testing in compliance with UL subject 758 is less than 1 minute.

14. The cable according to claim 10 , further comprising a sulfur-based antioxidant.

15. The cable according to claim 10 , further comprising a crosslinking agent.

Assignees

• Kibe Tamotsu
• Kikuchi Ryutaro
• Hitachi Metals Ltd

Inventors

• Kibe Tamotsu
• Kikuchi Ryutaro

Classifications

• C08K5/13

  Phenols; Phenolates · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title

• C08K5/25

  Carboxylic acid hydrazides · CPC title

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08K3/22 Primary

  of metals · CPC title