Production of para-xylene

Patent metadata

Field	Value
Publication number	US-9598332-B2
Application number	US-201414533856-A
Country	US
Kind code	B2
Filing date	Nov 5, 2014
Priority date	Dec 20, 2013
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

In a process for producing para-xylene, a feed comprising a mixture of xylene isomers, olefinic unsaturated contaminants and oxygenate contaminants is supplied to a para-xylene recovery unit to recover para-xylene and produce a para-xylene depleted residual stream. The para-xylene depleted residual stream is then contacted with a xylene isomerization catalyst in a xylene isomerization zone under liquid phase conditions effective to isomerize xylenes and produce an isomerized product having a higher para-xylene content than the para-xylene depleted residual stream. The isomerized product is then recycled to the para-xylene recovery unit. At least one of the feed, the para-xylene depleted residual stream and the isomerized product is contacted with a solid acid catalyst in a treatment zone under conditions effective to reduce the level of olefinic unsaturated contaminants and oxygenate contaminants therein and produce a treated stream.

First claim

The invention claimed is:

1. A process for producing para-xylene, the process comprising:
(a) supplying a feed comprising a mixture of xylene isomers to a para-xylene recovery unit to recover para-xylene from the feed and produce a para-xylene depleted residual stream, wherein the feed has a Bromine Index from 5 to 2000 and comprises from 5 to 2000 ppm by weight of oxygenate contaminants;
(b) contacting at least part of the para-xylene depleted residual stream with a xylene isomerization catalyst in a xylene isomerization zone under substantially liquid phase conditions effective to isomerize xylenes in the para-xylene depleted residual stream and produce an isomerized product having a higher para-xylene content than the para-xylene depleted residual stream;
(c) recycling at least part of the isomerized product to the para-xylene recovery unit; and
(d) contacting at least one stream selected from the feed, the para-xylene depleted residual stream and the isomerized product with a solid acid catalyst in a treatment zone in the presence of 3-15 wt-ppm hydrogen and under conditions to reduce a level of olefinic unsaturated contaminants and oxygenate contaminants therein and produce a treated stream.

2. The process of claim 1 , wherein the treated stream has a Bromine Index less than that of the feed and comprises a Bromine Index of less than 20.

3. The process of claim 1 , wherein the olefinic unsaturated contaminants comprise styrene.

4. The process of claim 1 , wherein the treated stream has a lower oxygenate content than the feed and comprises less than 50 ppm by weight of oxygenate contaminants.

5. The process of claim 1 , wherein the oxygenate contaminants comprise phenol and/or substituted phenols.

6. The process of claim 1 , wherein the solid acid catalyst comprises a clay, a molecular sieve or a mixture thereof.

7. The process of claim 1 , wherein the solid acid catalyst comprises a molecular sieve selected from the group consisting of ZSM-12, mordenite, Zeolite Beta, USY, a MWW structure type molecular sieve, and mixtures thereof.

8. The process of claim 1 , wherein the solid acid catalyst comprises a MWW structure type molecular sieve.

9. The process of claim 1 , wherein the xylene isomerization zone and the treatment zone are connected in series.

10. The process of claim 1 , wherein the contacting steps (b) and (d) are conducted in a single reaction zone.

11. The process of claim 1 , wherein the contacting steps (b) and (d) are conducted in a separate reaction zones connected in series without intermediate separation.

12. The process of claim 1 , wherein the contacting step (d) is conducted on the para-xylene depleted residual stream.

13. The process of claim 1 , wherein the contacting step (d) is conducted on the isomerized product.

14. The process of claim 1 , wherein the conditions in contacting step (d) include a temperature from 150° C. to 370° C.

15. The process of claim 1 and further comprising:
(e) contacting benzene and/or toluene with methanol and/or dimethyl ether in the presence of a molecular sieve catalyst under alkylation conditions effective to react at least part of the methanol and/or dimethyl ether with at least part of the benzene and/or toluene to produce an alkylation effluent comprising xylenes; and
(f) supplying at least part of the alkylation effluent as at least part of the feed in step (a).

16. The process of claim 15 , wherein the catalyst employed in step (e) has a Diffusion Parameter for 2,2-dimethylbutane of about 0.1-15 sec −1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 60 torr (8 kPa).

17. A process for reducing the level of contaminants in an aromatic hydrocarbon feed, wherein the feed has a Bromine Index from 5 to 2000 and comprises from 5 to 2000 ppm by weight of oxygenate contaminants, comprising contacting the feed in the presence of 3-15 wt-ppm hydrogen with a solid acid catalyst under conditions effective to reduce a level of olefinic unsaturated contaminants and oxygenate contaminants in the feed and produce a treated feed.

18. The process of claim 17 , wherein the treated feed has a Bromine Index of less than 5 and comprises less than 5 ppm by weight of oxygenate contaminants.

19. The process of claim 17 , wherein the solid acid catalyst comprises a molecular sieve selected from the group consisting of ZSM-12, mordenite, Zeolite Beta, USY, a MWW structure type molecular sieve and mixtures thereof.

20. The process of claim 17 , wherein the conditions in the contacting step include a temperature from 150° C. to 370° C.

21. The process of claim 17 , wherein the feed comprises C 8 aromatic hydrocarbons and the process further comprises supplying the treated feed to a para-xylene production loop comprising a para-xylene recovery unit and a liquid phase xylene isomerization unit.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Bender Timothy P
• Tinger Robert G

Classifications

• C07C2529/08

  of the faujasite type, e.g. type X or Y · CPC title

• C07C7/13 Primary

  by molecular-sieve technique · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• C07C15/08

  Xylenes · CPC title

• C07C2/864

  the non-hydrocarbon is an alcohol · CPC title