Process for preparing an emulsion of elemental sulphur particles

Patent metadata

Field	Value
Publication number	US-9598322-B2
Application number	US-201314413232-A
Country	US
Kind code	B2
Filing date	Jul 8, 2013
Priority date	Jul 9, 2012
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

The invention provides a process for the preparation an emulsion of elemental sulphur particles, said process comprising the steps of: (a) providing a first stream comprising a liquid fertilizer and/or a liquid fertilizer precursor; (b) providing a second stream comprising liquid elemental sulphur; and (c) mixing the first stream and the second stream in a mixing device in the presence of a multifunctional ionic surfactant to form an emulsion comprising elemental sulphur particles which are coated with a layer of the multifunctional ionic surfactant and dispersed in the fertilizer and/or the fertilizer precursor, whereby a temperature is applied which maintains the elemental sulphur substantially in the liquid form in the mixing device. The invention further provides an elemental sulphur-containing fertilizer obtainable by a process according to the invention.

First claim

That which is claimed is:

1. A process for the preparation an emulsion of elemental sulphur particles, said process comprising the steps of:
(a) providing a first stream, having a first stream temperature in the range of from 60 to 200° C., and comprising urea that is in liquid form;
(b) providing a second stream, having a second stream temperature in the range of from 120 to 150° C., and comprising liquid elemental sulphur; and
(c) mixing the first stream and the second stream in a mixing device at a mixing temperature so that the elemental sulphur and urea are maintained in substantially liquid form in the mixing device and in the presence of a multifunctional ionic surfactant to form an emulsion comprising elemental sulphur particles which are coated with a layer of the multifunctional ionic surfactant and dispersed in the urea.

2. A process according to claim 1 in which the emulsion as obtained in step (c) is subjected to one or more further processing steps to obtain an elemental-sulphur fertilizer.

3. A process according to claim 2 , wherein the one or more further processing steps comprise subjecting the emulsion to a forming process to obtain the elemental-sulphur-containing fertilizer.

4. A process according to claim 3 , wherein the forming process is a granulating process, a prilling process, a compaction process, a tablet forming process or a compressing process.

5. A process according to claim 1 , wherein the multifunctional ionic surfactant comprises an anioic surfactant.

6. A process according to claim 5 , wherein the anionic surfactant comprises a lignosulphonate.

7. A process according to claim 1 , wherein the mixing device in step (c) is a static mixer or a dispersion mill wherein a rotor turns within a slotted stator.

8. A process according to claim 7 , wherein step (c) is carried out in a continuous mode of operation.

9. A process according to claim 1 , wherein the particle size and particle size distribution of the elemental sulphur particles in the emulsion as obtained in step (c) is controlled.

10. A process for the preparation of elemental sulfur fertilizer, wherein said process comprises:
(a) providing a first stream comprising an aqueous solution of from 1 to 60% phosphoric acid, wherein said first stream has a first stream temperature in the range of from 80 to 150° C.;
(b) providing a second stream comprising elemental sulfur in molten form and at a second stream temperature in the range of from 115 to 200° C.;
(c) mixing said first stream and said second stream in a mixing device in the presence of a multifunctional ionic surfactant at a mixing temperature greater than 115° C. and at most 200° C. to form an emulsion comprising elemental sulfur particles coated with said multifunctional ionic surfactant, wherein said mixing temperature is such that said elemental sulfur is maintained in substantially liquid form in the mixing device, and wherein said first stream and said second stream are mixed in such proportions that the weight percentage of said elemental sulfur is in the range of from 1 to 70 wt. %, based on the combined weight of said elemental sulfur and said aqueous solution; and
(d) forming said emulsion into granulated fertilizer particles of solid elemental sulfur-containing fertilizer particles by a method selected from the group consisting of granulating, prilling, compacting, tableting, and compressing.

11. A process as recited in claim 10 , wherein said multifunctional ionic surfactant is an anionic surfactant selected from the group consisting of soaps, sulphates, suphonates, phosphites, phosphates, phosphonates, ionic polymeric surfactants, and lignosulphonates.

12. A process as recited in claim 10 , wherein said multifunctional ionic surfactant is a lignosulfphonate selected from the group consisting of ammonium lignosulphonate, sodium lignosulphonate, calcium lignosulphonate, and potassium lignosulphonate.

13. A process as recited in claim 10 , wherein said lignosulfphonate is calcium lignosulphonate.

14. A process as recited in claim 10 , wherein said elemental sulfur particles in said emulsion have an average particle size in the range of from 1 to 500 micrometers.

15. A process as recited in claim 10 , wherein the amount of said multifunctional ionic surfactant mixed with said first stream and said second stream is such as to be from 0.001 to 5.0 wt. % of said multifunctional ionic surfactant of the total weight of said granulated fertilizer particles.

16. A process as recited in claim 10 , wherein said aqueous solution contains from 5 to 55% phosphoric acid; said second stream temperature is in the range of from 120to 150° C.; said mixing temperature is greater than 120° C.; said elemental sulfur based on the combined weight of said elemental sulfur and said aqueous solution is in the range of from 4 to 40 wt. %; said elemental sulfur particles in said emulsion have an average particle size in the range of from 5 to 200 micrometers; and the amount of said multifunctional ionic surfactant mixed with said first stream and said second stream is such as to be from 0.01 to 1.5 wt. % of said multifunctional ionic surfactant of the total weight of said granulated fertilizer particles.

17. A process as recited in claim 11 , wherein said aqueous solution contains from 5 to 55% phosphoric acid; said second stream temperature is in the range of from 120 to 150° C.; said mixing temperature is greater than 120° C.; said elemental sulfur based on the combined weight of said elemental sulfur and said aqueous solution is in the range of from 4 to 40 wt. %; said elemental sulfur particles in said emulsion have an average particle size in the range of from 5 to 200 micrometers; and the amount of said multifunctional ionic surfactant mixed with said first stream and said second stream is such as to be from 0.01 to 1.5 wt. % of said multifunctional ionic surfactant of the total weight of said granulated fertilizer particles.

18. A process as recited in claim 12 , wherein said aqueous solution contains from 5 to 55% phosphoric acid; said second stream temperature is in the range of from 120 to 150° C.; said mixing temperature is greater than 120° C.; said elemental sulfur based on the combined weight of said elemental sulfur and said aqueous solution is in the range of from 4 to 40 wt. %; said elemental sulfur particles in said emulsion have an average particle size in the range of from 5 to 200 micrometers; and the amount of said multifunctional ionic surfactant mixed with said first stream and said second stream is such as to be from 0.01 to 1.5 wt. % of said multifunctional ionic surfactant of the total weight of said granulated fertilizer particles.

19. A process as recited in claim 13 , wherein said aqueous solution contains from 5 to 55% phosphoric acid; said second stream temperature is in the range of from 120 to 150° C.; said mixing temperature is greater than 120° C.; said elemental sulfur based on the combined weight of said elemental sulfur and said aqueous solution is in the range of from 4 to 40 wt. %; said elemental sulfur particles in said emulsion have an average particle size in the range of from 5 to 200 micrometers; and the amount of said multifunctional ionic surfactant mixed with said first stream and said second stream is such as to be from 0.01 to 1.5 wt. % of said multifunctional ionic surfactant of the total weight of said granulated fertilizer particles.

20. A granulated fertilizer composition, comprising: granulated fertilizer particles formed from an emulsion of elemental

Assignees

• Shell Oil Co

Inventors

• Allais Cyrille Paul
• Hutter Klaas Jan
• Garcia Martinez Rafael Alberto

Classifications

• C05G5/27

  Dispersions, e.g. suspensions or emulsions · CPC title

• C05C9/005 Primary

  Post-treatment · CPC title

• C05C9/00

  Fertilisers containing urea or urea compounds · CPC title

• C05B7/00 Primary

  Fertilisers based essentially on alkali or ammonium orthophosphates (C05B11/00 takes precedence) · CPC title

• C05B17/00

  Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal · CPC title