Solution comprising organofunctional alkali siliconates, silicates and method of production thereof

Patent metadata

Field	Value
Publication number	US-9598316-B2
Application number	US-201214111185-A
Country	US
Kind code	B2
Filing date	Feb 27, 2012
Priority date	Apr 11, 2011
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

The invention relates to a method for producing a solution comprising organofunctional siliconates, silicates and, optionally, the cocondensation products thereof, and to the solutions and an installation for the production thereof.

First claim

The invention claimed is:

1. A method of preparing a solution comprising an organofunctional alkali siliconate, an organofunctional alkali silicate and optionally a co-condensation product thereof, the method comprising:
preparing a mixture comprising an organofunctional silane of the formula I:
(R 1 ) x SiHal (y-x)   (I),

with a halosilane of the formula II:
Si(Hal) 4   (II),

an alcohol, and optionally water, to obtain a reacted mixture,
wherein
R 1 is independently an organofunctional residue,
Hal is a hydrolysable residue, which is independently chlorine or bromine,
x is 1 or 2, and
y is 4; and

introducing the reacted mixture in the presence of an inert gas into an aqueous alkali hydroxide solution, wherein the inert gas is supplied so that it introduces a portion of the reacted mixture directly into the aqueous alkaline solution.

2. The method according to claim 1 , further comprising stirring vigorously the mixture in the preparing, the solution in the introducing, or both.

3. The method according to claim 1 , wherein the organofunctional radical R 1 each independently comprises 1 to 18 carbon atoms.

4. The method according to claim 1 , wherein a solution comprising the organofunctional alkali siliconate, the organofunctional alkali silicate and optionally a co-condensation product thereof is obtained in the introducing.

5. The method according to claim 1 , wherein the organofunctional silane of the formula I and the halosilane of the formula II have a molar ratio of from 0.5:10 to 10:0.5.

6. The method according to claim 1 , wherein the alcohol is added in a ratio of from 1 to 100 mol. % relative to the hydrolysable residue in mol.

7. The method according to claim 1 , wherein the mixture from the preparing is introduced immediately into an aqueous, alkaline solution and is reacted to a solution comprising an organofunctional siliconate, an organofunctional silicate and optionally a co-condensation product thereof.

8. The method according to claim 1 , wherein the temperature in the preparing, the introducing, or both, does not exceed 80° C.

9. The method according to claim 4 , wherein the alcohol is removed from the solution comprising the organofunctional alkali siliconate, the organofunctional alkali silicate and optionally co-condensation product thereof.

10. The method according to claim 7 , wherein a proportion of the organofunctional siliconate, organofunctional silicate and co-condensation product thereof in the solution is between 1 and 40 wt. %, relative to a total weight of the solution, wherein a content is optionally adjusted by adding water.

11. The method according claim 1 , wherein the alcohol comprises at least one selected from the group consisting of ethanol, methanol, and propanol, and an alcohol content in the solution is between 1 ppm by weight and 25% by weight, based on a total weight of the solution.

12. The method according to claim 1 , wherein the inert gas comprises nitrogen, argon, or both, or further gases which do not react with the mixture, the solution, or both.

13. The method according to claim 1 , wherein
the portion of the mixture from the preparing is supplied to the introducing by means of a metering device, in the presence of inert gas, to a device which has a delivery means and is blanketed with inert gas, an end of which is immersed into the alkaline solution, or
the mixture from the preparing is transferred into a metering device and is blanketed with inert gas, in which the portion of the mixture is introduced from the metering device to a device which has delivery means and is blanketed with inert gas, an end of which is immersed into the alkaline solution.

14. The method according to claim 13 , wherein an inert gas stream is divided and a portion of the inert gas stream is transferred into the metering device and another portion of the inert gas stream into the device with delivery means.

15. The method according to claim 13 , wherein the portion of the mixture from the preparing is transferred by means of a metering device into a device with a delivery means and there it is forced by means of the inert gas through the delivery means into the alkaline solution.

16. The method according to claim 1 , wherein the organofunctional radical R 1 each independently comprises a linear, branched or cyclic alkyl radical having 1 to 18 carbon atoms, an alkylene radical having 1 to 18 carbon atoms, an aryl radical having 6, 10, 12 or 13 carbon atoms, or an alkylaryl or arylalkyl radical having 7 to 18 carbon atoms.

Assignees

• Friedel Manuel
• Ljesic Spomenko
• Waβmer Christian
• Zölitz Susanne
• Evonik Degussa Gmbh

Inventors

• Friedel Manuel
• Ljesic Spomenko
• Waβmer Christian
• Zölitz Susanne

Classifications

• C07F7/188 Primary

  by reactions involving the formation of Si-O linkages · CPC title

• C04B24/42 Primary

  Organo-silicon compounds · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• B01J19/0006

  Controlling or regulating processes (controlling or regulating in general G05) · CPC title

• C08G77/24

  halogen-containing groups · CPC title