Alkali-free glass
US-9023744-B2 · May 5, 2015 · US
US9598307B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9598307-B2 |
| Application number | US-201314441280-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 6, 2013 |
| Priority date | Dec 14, 2012 |
| Publication date | Mar 21, 2017 |
| Grant date | Mar 21, 2017 |
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Devised are a glass and glass substrate, which contain an alkaline component at a low content, are low in density and thermal expansion coefficient, are high in strain point and Young's modulus, and are excellent in devitrification resistance, meltability, formability, and the like. That is, the glass of the present invention includes as a glass composition, in terms of mass %, 58 to 70% of SiO 2 , 16 to 25% of Al 2 O 3 , 3 to 8% of B 2 O 3 , 0 to 5% of MgO, 3 to 13% of CaO, 0 to 6% of SrO, 0 to 6% of BaO, 0 to 5% of ZnO, 0 to 5% of ZrO 2 , 0 to 5% of TiO 2 , and 0 to 5% of P 2 O 5 .
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The invention claimed is: 1. A glass, comprising as a glass composition, in terms of mass %, 58 to 70% of SiO 2 , 16 to 25% of Al 2 O 3 , 3 to 8% of B 2 O 3 , 0 to 5% of MgO, 3 to 13% of CaO, 0 to 6% of SrO, 0 to 6% of BaO, 0 to 5% of ZnO, 0 to 5% of ZrO 2 , 0 to 0.05% of TiO 2 , 0 to 5% of P 2 O 5 , 0.005 to 0.5% of Fe 2 O 3 , 0.01 to 1% of SnO 2 , 0 to less than 0.1% of Sb 2 O 3 , and 0.00001-0.0005% of Rh 2 O 3 , and having a liquid phase viscosity of 10 5.0 dPa·s or more. 2. A glass, comprising as a glass composition, in terms of mass %, 58 to 70% of SiO 2 , 16 to 25% of Al 2 O 3 , 3 to 8% of B 2 O 3 , 0 to 5% of MgO, 3 to 13% of CaO, 0 to 6% of SrO, 0 to 6% of BaO, 0 to 5% of ZnO, 0 to 5% of ZrO 2 , 0 to 0.05% of TiO 2 , 0 to 5% of P 2 O 5 , 0.005 to 0.5% of Fe 2 O 3 , 0.01 to 1% of SnO 2 , 0 to less than 0.1% of Sb 2 O 3 , and 0.00001-0.0005% of Rh 2 O 3 , being substantially free of a Li component and a Na component, and having a liquid phase viscosity of 10 5.0 dPa·s or more, a density of from 2.43 to 2.52 g/cm 3 and a strain point of 680° C. or more. 3. The glass according to claim 1 or 2 , being substantially free of a Li component and a Na component, and having a density of from 2.43 to 2.52 g/cm 3 , a thermal expansion coefficient of from 30 to 40×10 −7 /° C., a Young's modulus of 75 GPa or more, a strain point of 680° C. or more and less than 740° C., a temperature at 10 5.0 dPa·s of 1,250° C. or less, and a temperature at 10 2.5 dPa·s of 1,650° C. or less. 4. The glass according to claim 1 or 2 , comprising as a glass composition, in terms of mass %, 59 to 67% of SiO 2 , 17 to 22% of Al 2 O 3 , 5 to 7% of B 2 O 3 , 0 to 4% of MgO, 3 to 12% of CaO, 0 to 5% of SrO, 0.1 to 5% of BaO, 0 to 5% of ZnO, 0 to 5% of ZrO 2 , 0 to 0.05% of TiO 2 , 0 to 5% of P 2 O 5 , 0.005 to 0.5% of Fe 2 O 3 , 0.01 to 1% of SnO 2 , and 0 to less than 0.1% of Sb 2 O 3 , and being substantially free of a Li component and a Na component. 5. The glass according to claim 1 or 2 , comprising as a glass composition, in terms of mass %, 60 to 65% of SiO 2 , 17 to 20% of Al 2 O 3 , 5 to 7% of B 2 O 3 , 0 to 3% of MgO, 4 to 10% of CaO, 0 to 5% of SrO, 0.1 to 5% of BaO, 0 to 1% of ZnO, 0 to 1% of ZrO 2 , 0 to 0.05% of TiO 2 , 0 to 3% of P 2 O 5 , 0.005 to 0.5% of Fe 2 O 3 , 0.01 to 1% of SnO 2 , and 0 to less than 0.1% of Sb 2 O 3 , and being substantially free of a Li component and a Na component. 6. A glass substrate, comprising the glass according to claim 1 or 2 . 7. The glass substrate according to claim 6 , wherein the glass substrate is used for an OLED display. 8. The glass substrate according to claim 6 , wherein the glass substrate is used for a liquid crystal display. 9. The glass substrate according to claim 6 , wherein the glass substrate is used for a display driven by an oxide TFT.
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