Polymer nanofiber-based electronic nose

Patent metadata

Field	Value
Publication number	US-9598282-B2
Application number	US-201113243257-A
Country	US
Kind code	B2
Filing date	Sep 23, 2011
Priority date	Apr 8, 2004
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

A chemical sensor and a system and method for sensing a chemical species. The chemical sensor includes a plurality of nanofibers whose electrical impedance varies upon exposure to the chemical species, a substrate supporting and electrically isolating the fibers, and a set of electrodes connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured. The system includes the chemical sensor, an impedance measuring device coupled to the electrodes and configured to determine an electrical impedance of the plurality of fibers, and an analyzer configured to identify the chemical species based on a change in the electrical impedance. The method measures at least one change in an electrical impedance between spatially separated electrodes, and identifies the chemical species based on the measured change in the electrical impedance.

First claim

The invention claimed is:

1. A chemical sensor comprising:
a plurality of fibers whose electrical impedance varies upon exposure to a chemical species;
a substrate supporting and electrically isolating the fibers;
a set of printed electrodes disposed on at least one of the substrate and the plurality of fibers and connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured; and
a polymer layer disposed in contact with the plurality of fibers to transport the chemical species from air outside the polymer layer through the polymer layer to provide a higher concentration of the chemical species at the fibers than in the air, wherein
the fibers comprise conductive fibers,
the conductive fibers comprise a non-conducting medium and a conducting additive medium dispersed in the non-conducting medium, and
the conducting additive medium has a density which permits electrical conduction by percolation of charge carriers through regions of the conducting medium in the conductive fibers.

2. The sensor of claim 1 , wherein the polymer layer comprises a material that sorbs and concentrates the chemical species.

3. The sensor of claim 1 , wherein the polymer layer concentrates the chemical species next to the fibers.

4. The sensor of claim 1 , wherein the polymer layer has partition coefficients selected for the chemical species to be sensed such that the chemical species to be sensed are transmitted through the polymer layer.

5. The sensor of claim 3 , wherein the polymer layer has partition coefficients which relative to the chemical species to be sensed exclude other chemical species.

6. The sensor of claim 1 , wherein the polymer layer comprises a silicone layer.

7. The sensor of claim 1 , wherein the polymer layer comprises a cross-linked polydimethylsiloxane (PDMS) film.

8. The sensor of claim 1 , wherein the polymer layer has a thickness from 200 nm to 2 μm.

9. The sensor of claim 1 , wherein the electrodes comprise an interdigitated microelectrode.

10. The sensor of claim 1 , wherein the fibers comprise nanofibers whose average fiber diameter is less than 500 nm.

11. The sensor of claim 1 , wherein the fibers comprise nanofibers whose average fiber diameter is less than 100 nm.

12. The sensor of claim 1 , wherein the fibers have an electrical impedance which changes due to at least one of an increase in volumetric size of the fibers by sorption of the chemical species or a change in electrical conduction by a chemical reaction of the chemical species with a material of the fiber.

13. The sensor of claim 1 , wherein the conducting additive medium comprises a weight percentage of the conductive fibers less than 5%.

14. The sensor of claim 1 , wherein the conducting additive medium comprises carbon tubes.

15. The sensor of claim 14 , wherein the carbon tubes are disposed in a body of the fibers at a concentration that is within 10% of a conduction percolation threshold.

16. The sensor of claim 1 , wherein the non-conducting medium comprises an organic polymer.

17. The sensor of claim 1 , wherein the conducting additive medium comprises at least one of carbon black, carbon nanotubes, fullerenes and conducting metals, including at least one of Ag, Au, Cu, and Al.

18. The sensor of claim 1 , wherein the plurality of fibers comprises aligned fibers.

19. The sensor of claim 1 , further comprising:
plural sets of the electrodes to which respective groups of the fibers are connected at spatially separated points.

20. The sensor of claim 1 , wherein the electrodes comprise electrodes printed on the plurality of fibers.

21. A system for sensing a chemical species, comprising:
a chemical sensor including,
a plurality of fibers whose electrical impedance varies upon exposure to a chemical species,
a substrate supporting and electrically isolating the fibers,
a set of printed electrodes disposed on at least one of the substrate and the plurality of fibers and connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured, and
a polymer layer disposed in contact with the plurality of fibers to transport the chemical species from air outside the polymer layer through the polymer layer to provide a higher concentration of the chemical species at the fibers than in the air; and
an analyzer configured to identify the chemical species based on a change in the electrical impedance, wherein
the fibers comprise conductive fibers,
the conductive fibers comprise a non-conducting medium and a conducting additive medium dispersed in the non-conducting medium, and
the conducting additive medium has a density which permits electrical conduction by percolation of charge carriers through regions of the conducting medium in the conductive fibers.

22. The system of claim 21 , wherein the analyzer compares existing saved databases for identification of the chemical species.

23. The sensor of claim 1 , wherein the substrate comprises a fabric, and the set of printed electrodes is disposed on the fabric.

24. The sensor of claim 1 , wherein
the substrate comprises a fabric,
the set of printed electrodes is disposed on the fabric, and
the fabric, the fibers, the electrodes, and the polymer layer comprise a wearable sensor.

25. The system of claim 21 , wherein the substrate comprises a fabric, and the set of printed electrodes is disposed on the fabric.

26. The system of claim 21 , wherein
the substrate comprises a fabric,
the set of printed electrodes is disposed on the fabric, and
the fabric, the fibers, the electrodes, and the polymer layer comprise a wearable sensor.

27. A chemical sensor comprising:
a plurality of fibers whose electrical impedance varies upon exposure to a chemical species;
a substrate supporting and electrically isolating the fibers;
a set of printed electrodes disposed on at least one of the substrate and the plurality of fibers and connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured; and
an encapsulation layer disposed in contact with the plurality of fibers, wherein
the fibers comprise conductive fibers,
the conductive fibers comprise a non-conducting medium and a conducting additive medium dispersed in the non-conducting medium, and
the conducting additive medium has a density which permits electrical conduction by percolation of charge carriers through regions of the conducting medium in the conductive fibers.

28. The sensor of claim 1 , wherein the conducting additive medium comprises a weight percentage of the conductive fibers ranging from 1% to 30%.

29. The chemical sensor of claim 1 , wherein the fibers comprise conducting polymers with a conductive additive.

30. The chemical sensor of claim 1 , wherein the fibers comprise conducting polymers without a conductive additive.

Assignees

• Han Li
• Andrady Anthony L
• Ensor David S
• Res Triangle Inst

Inventors

• Han Li
• Andrady Anthony L
• Ensor David S

Classifications

• Y10S977/957

  Of chemical property or presence · CPC title

• G01N27/127 Primary

  comprising nanoparticles · CPC title

• B82Y15/00 Primary

  Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors · CPC title

• G01N27/02 Primary

  by investigating impedance · CPC title

• B82B3/00

  Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units · CPC title