System and method for two and three way mixed metal oxide ZPGM catalyst
US-9216408-B2 · Dec 22, 2015 · US
US9597660B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9597660-B2 |
| Application number | US-201414912967-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 12, 2014 |
| Priority date | Aug 22, 2013 |
| Publication date | Mar 21, 2017 |
| Grant date | Mar 21, 2017 |
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A catalytic converter ( 10 ) includes a base material and a catalyst layer ( 3 ). The catalyst layer has a lower catalyst layer ( 4 ) and an upper catalyst layer ( 5 ). The upper catalyst layer is constituted by a first upper catalyst layer ( 6 ) and a second upper catalyst layer ( 7 ). The first upper catalyst layer is formed of a first carrier, which is formed of a ceria-containing oxide, and rhodium supported on the first carrier. The second upper catalyst layer is formed of a second carrier and rhodium supported on the second carrier. The second carrier does not contain ceria and is formed of one oxide selected from among zirconia and alumina. A length of the first upper catalyst layer is X % (30 to 70%) of an overall length of the base material. A length of the second upper catalyst layer is 100−X % of the overall length of the base material.
Opening claim text (preview).
The invention claimed is: 1. A catalytic converter comprising: a base material having a cellular structure through which exhaust gases flow; and a catalyst layer formed on a surface of a cell wall in the base material, wherein the catalyst layer has a lower catalyst layer and an upper catalyst layer, the lower catalyst layer is formed on a surface of the base material along an entire length of the base material, the upper catalyst layer is constituted by a first upper catalyst layer and a second upper catalyst layer, the first upper catalyst layer is formed on an upstream side of a surface of the lower catalyst layer in a direction of exhaust gas flow, an upstream side end of the base material is a starting point of the first upper catalyst layer, the second upper catalyst layer is formed on a downstream side of the surface of the lower catalyst layer in the direction of the exhaust gas flow, a downstream side end of the base material is a starting point of the second upper catalyst layer, the lower catalyst layer is formed of a carrier and palladium supported on the carrier, the first upper catalyst layer is formed of a first carrier and rhodium supported on the first carrier, the first carrier is formed of a complex oxide comprising Al 2 O 3 , CeO 2 , ZrO 2 , La 2 O 3 , Y 2 O 3 , and Nd 2 O 3 , the second upper catalyst layer is formed of a second carrier and rhodium supported on the second carrier, the second carrier being formed of a complex oxide comprising Al 2 O 3 , ZrO 2 , La 2 O 3 , and Nd 2 O 3 , a length of the first upper catalyst layer in the direction of the exhaust gas flow is 30 to 70% of an overall length of the base material, and a length of the second upper catalyst layer in the direction of the exhaust gas flow is a length obtained by subtracting the length of the first upper catalyst layer from the overall length of the base material, wherein the first carrier is formed of a ceria-containing zirconia complex oxide, and the second carrier is formed of a zirconia complex oxide that does not contain ceria.
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Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat) · CPC title
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