BOPP film with high AC breakdown strength

Patent metadata

Field	Value
Publication number	US-9595388-B2
Application number	US-201113813769-A
Country	US
Kind code	B2
Filing date	Aug 1, 2011
Priority date	Aug 6, 2010
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

Polypropylene composition comprising a polypropylene and an α-nucleating agent, wherein the polypropylene composition has • a comonomer content of equal or below 1.0 wt.- %, •<2,1> erythro regiodefects of more than 0.1 mol.- %, and • at least 9.0 wt- % of a crystalline fraction crystallizing in the temperature range of above 160 to 170° C., wherein said fraction is determined by the stepwise isothermal segregation technique (SIST).

First claim

The invention claimed is:

1. A capacitor comprising at least one layer comprising a capacitor film comprising a biaxially oriented polypropylene (BOPP) film comprising a polypropylene composition (PP-C), the polypropylene composition (PP-C) comprising:
(i) at least 70 wt. % of a polypropylene (PP) and
(ii) 0.005 to 1.5 wt. % of an α-nucleating agent (N) based on the polypropylene composition (PP-C), wherein the polypropylene composition (PP-C) and/or the polypropylene (PP) has/have
(a) a comonomer content of equal or below 1.0 wt. %, the comonomers are ethylene and/or at least one C 4 to C 20 α-olefin, and
(b) <2,1> erythro regiodefects of more than 0.1 mol. % determined by 13 C-spectroscopy,
and wherein further
(c) the polypropylene composition (PP-C) and/or the polypropylene (PP) has/have a pentad isotacticity <mmmm> of at least 98 mol. %, and/or
(d) the polypropylene composition (PP-C) comprises at least 9.0 wt % of a crystalline fraction crystallizing in the temperature range of above 160 to 170° C., wherein said fraction is determined by the stepwise isothermal segregation technique (SIST),
wherein the biaxially oriented (BOPP) film has an electrical breakdown strength EB63% derived from data measured according to IEC 60243 part 1 (1998) and evaluated according to IEC 60727, part 1 & 2 of at least 310 kV/mm obtained on a biaxially oriented direction of 5.0.

2. The capacitor according to claim 1 , wherein the polypropylene (PP) is the only polymer within the polypropylene composition (PP-C).

3. The capacitor according to claim 1 , wherein:
(a) the polypropylene composition (PP-C) comprises crystalline fractions crystallizing in the temperature range of;
(i) above 140 to 150° C.
(ii) above 150 to 160° C.
(iii) above 160 to 170° C.
wherein the amount of the three crystalline fractions [wt. %] differ from each other of not more than 5.0 wt. %, and/or
(b) the amount of the crystalline fraction of the polypropylene composition (PP-C) crystallizing in the temperature range of above 160 to 170° C., is not more than 35 wt. %, and/or
(c) the polypropylene composition (PP-C) has a crystalline fraction crystallizing above 170° C. of not more than 5.0 wt. %,
wherein said fractions are determined by the stepwise isothermal segregation technique (SIST).

4. The capacitor according to claim 1 , wherein the polypropylene composition (PP-C) and/or the polypropylene (PP) has/have:
(a) a melting temperature (T m ) measured by differential scanning calorimetry (DSC) of at least 150.0° C., and/or
(b) a crystallization temperature (T c ) measured by differential scanning calorimetry (DSC)of at least 110° C.

5. The capacitor according to claim 1 , wherein the polypropylene composition (PP-C) has
(a) a heat resistance Vicat B measured according to ISO 306 (50 N) of at least 95° C., and/or
(b) a heat distortion temperature (HDT-B) measured according to ISO 75-2 of at least 89° C.

6. The capacitor according to claim 1 , wherein the polypropylene composition (PP-C) has:
(a) a γ-phase of more than 10 to 60% wherein said γ-phase has been measured after stepwise isothermal segregation (SIST) by wide angle x-ray scattering (WAXS), and/or
(b) an ash content measured according to ISO 3451-1 (1997) of below 60 ppm.

7. The capacitor according to claim 1 , wherein the polypropylene composition(PP-C) and/or the polypropylene (PP) has/have:
(a) a molecular weight distribution (MWD) measured according to ISO 16014 of at least 3.0, and/or
(b) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of more than 1.5 g/10 min, and/or
(c) a xylene cold soluble fraction (XCS) determined at 23° C. according ISO 6427 of equal or below 1.5 wt. %.

8. The capacitor according to claim 1 , wherein the polypropylene composition (PP-C) and/or the polypropylene (PP) has/have a branching index g′ of at least 0.9.

9. The capacitor according to claim 1 , wherein the α-nucleating agent (N) is selected from the grouwp consisting of sorbitol derivatives, nonitol derivatives, benzene-trisamides, and mixtures thereof.

10. The capacitor according to claim 1 , wherein the α-nucleating agent (N):
(a) is soluble in the polypropylene (PP) and/or
(b) has a molecular symmetry classified as C 3h .

11. The capacitor according to claim 1 , comprising at least 90 wt. % of the polypropylene composition(PP-C).

12. The capacitor according to claim 1 , wherein said film has:
a draw ratio in machine direction of at least 4.0 and a draw ratio in transverse direction of at least 4.0.

13. Process for the preparation of a capacitor comprising a capacitor film comprising a polypropylene composition (PP-C), comprising the step of preparation of a polypropylene (PP) by:
(a) polymerizing propylene and optionally ethylene and/or at least one C 4 to C 20 α-olefin in the presence of a solid catalyst system, said solid catalyst system comprises:
(i) a transition metal compound of formula (I)
( Cp ′) 2 R n MX 2   (I)

wherein
“M” is zirconium (Zr) or hafnium (Hf),
each “X” is independently a monovalent anionic σ-ligand,
each “Cp'” is a cyclopentadienyl-type organic ligand independently selected from the group consisting of substituted cyclopentadienyl, substituted indenyl, substituted tetrahydroindenyl, and substituted or unsubstituted fluorenyl, said organic ligands coordinate to the transition metal (M),
“R” is a bivalent bridging group linking said organic ligands (Cp′), and
“n” is 1 or 2, preferably 1, and
(ii) optionally a cocatalyst comprising an element of group 13 of the periodic table (IUPAC),
(b) melt mixing said polypropylene (PP) obtained in step (a) with an α-nucleating agent (N) obtaining the polypropylene composition (PP-C), and
(c) stretching said polypropylene composition (PP-C) to a biaxially oriented film,
wherein the polypropylene (PP) and the α-nucleating agent (N) are defined according to claim 1 .

Assignees

• Gloger Dietrich
• Klimke Katja
• Fiebig Joachim
• Grein Christelle
• Persson Robert
• Borealis Ag

Inventors

• Gloger Dietrich
• Klimke Katja
• Fiebig Joachim
• Grein Christelle
• Persson Robert

Classifications

• B29K2223/10

  Polymers of propylene · CPC title

• C08F110/06

  Propene · CPC title

• H01B3/441

  from alkenes · CPC title

• C08J2323/12

  Polypropene · CPC title

• B29C55/12

  biaxial · CPC title