Method to produce high corrosion and wear resistant cast iron components by water jet surface activation, nitrocarburization and thermal spray coating
US-2024084430-A1 · Mar 14, 2024 · US
US9593404B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9593404-B2 |
| Application number | US-201414263254-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 28, 2014 |
| Priority date | May 1, 2013 |
| Publication date | Mar 14, 2017 |
| Grant date | Mar 14, 2017 |
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Provided is a method of manufacturing a nitrocarburized crankshaft which is obtained by subjecting a bainitic microalloyed steel to a forging and a machining, and further subjecting the bainitic microalloyed steel to at least a strain releasing heat treatment and a subsequent nitrocarburizing treatment, the bainitic microalloyed steel containing, as essentially added elements, in terms of mass %: 0.10% to 0.40% of C; 0.10% to 1.0% of Si; 1.0% to 2.0% of Mn; 0.05% to 0.40% of Mo; and 0.05% to 0.40% of V, and the bainitic microalloyed steel optionally further containing, as arbitrarily added elements, in terms of mass %: 0.01% to 0.1% of S; 0.005% to 0.2% of Ti; 0.001% to 0.03% of Al; 0.50% or less of Cr; 0.5% or less of Cu; and 0.5% or less of Ni, with the balance being Fe and unavoidable impurities.
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What is claimed is: 1. A nitrocarburized crankshaft obtained by subjecting a bainitic microalloyed steel to a forging and a machining and further subjecting the bainitic microalloyed steel to at least a strain releasing heat treatment and a subsequent nitrocarburizing treatment, the bainitic microalloyed steel containing, as essentially added elements, in terms of mass %: 0.16% to 0.40% of C; 0.13% to 1.0% of Si; 1.0% to 2.0% of Mn; 0.05% to 0.40% of Mo; and 0.05% to 0.30% of V, and the bainitic microalloyed steel optionally further containing, as arbitrarily added elements, in terms of mass %: 0.01% to 0.1% of S; 0.005% to 0.2% of Ti; 0.001% to 0.03% of Al; 0.50% or less of Cr; 0.5% or less of Cu; and 0.5% or less of Ni, with the balance being Fe and unavoidable impurities, wherein at least a content of P as one of the unavoidable impurities is suppressed to be 0.025% or less, wherein the microalloyed steel satisfies the following expressions: [C]+0.27[Mn]+0.32[Cr]+0.27[Mo]+0.38[V]≧0.72, [C]+0.01[Si]+0.09[Mn]+0.13[Cr]+0.12[Mo]+0.28[V]<0.65, and [C]+0.11[Si]+0.11[Mn]+0.09[Cr]+0.21[Mo]+0.60[V]≧0.54, in which [M] represents a content of element M in terms of % by mass, and wherein an amount of residual γ is controlled to be less than 5.0%, and a core part has a hardness of 270 HV or greater. 2. A method of manufacturing a nitrocarburized crankshaft which is obtained by subjecting a bainitic microalloyed steel to a forging and a machining, and further subjecting the bainitic microalloyed steel to at least a strain releasing heat treatment and a subsequent nitrocarburizing treatment, the bainitic microalloyed steel containing, as essentially added elements, in terms of mass %: 0.16% to 0.40% of C; 0.13% to 1.0% of Si; 1.0% to 2.0% of Mn; 0.05% to 0.40% of Mo; and 0.05% to 0.30% of V, and the bainitic microalloyed steel optionally further containing, as arbitrarily added elements, in terms of mass %: 0.01% to 0.1% of S; 0.005% to 0.2% of Ti; 0.001% to 0.03% of Al; 0.50% or less of Cr; 0.5% or less of Cu; and 0.5% or less of Ni, with the balance being Fe and unavoidable impurities, wherein at least a content of P as one of the unavoidable impurities is suppressed to be 0.025% or less, wherein the microalloyed steel is selected so as to satisfy: [C]+0.27[Mn]+0.32[Cr]+0.27[Mo]+0.38[V]≧0.72, [C]+0.01[Si]+0.09[Mn]+0.13[Cr]+0.12[Mo]+0.28[V]<0.65, and [C]+0.11[Si]+0.11[Mn]+0.09[Cr]+0.21[Mo]+0.60[V]≧0.54, in which [M] represents a content of element M in terms of % by mass, and wherein the strain releasing heat treatment is performed to satisfy the following expressions regarding a holding temperature T (° C.) and a holding time t (hr): 21.6+14.2[C]+1.5[Si]+2.6[Mn]+6.5[Cr]+2.7[Mo]+1.6[V]+10 −7 ×γ h1 2 −3.7×10 −3 ×γ h1 <0.70, and γ h1 =( T+ 273)×(20+Log( t ). 3. The method of manufacturing a nitrocarburized crankshaft according to claim 2 , wherein the nitrocarburizing treatment is performed for 0.5 hours or longer under a gas atmosphere at a temperature in a range of from 550° C. to 650° C., and a core part has a hardness of 270 HV or greater. 4. The method of manufacturing a nitrocarburized crankshaft according to claim 2 , wherein the bainitic microalloyed steel is subjected to the forging after heating the bainitic microalloyed steel to a temperature in a range of 1150° C. or more and lower than 1350° C., and then the forged steel is at least cooled at a cooling rate controlled to be within a range of from 0.25° C./sec to 1.50° C./sec in a carbon diffusion temperature range, thereby obtaining a hardness of less than 33.0 HRC. 5. The method of manufacturing a nitrocarburized crankshaft according to claim 4 , wherein in the strain releasing heat treatment, the holding temperature T is set in a range of from 400° C. to 600° C. and the holding time t is set in a range of from 0.5 hours to 5.0 hours so as to control an amount of residual γ to less than 5.0%. 6. The method of manufacturing a nitrocarburized crankshaft according to claim 4 , wherein the nitrocarburizing treatment is performed for 0.5 hours or longer under a gas atmosphere at a temperature in a range of from 550° C. to 650° C., and a core part has a hardness of 270 HV or greater. 7. The method of manufacturing a nitrocarburized crankshaft according to claim 5 , wherein the nitrocarburizing treatment is performed for 0.5 hours or longer under a gas atmosphere at a temperature in a range of from 550° C. to 650° C., and a core part has a hardness of 270 HV or greater. 8. The method of manufacturing a nitrocarburized crankshaft according to claim 2 , wherein in the strain releasing heat treatment, the holding temperature T is set in a range of from 400° C. to 600° C. and the holding time t is set in a range of from 0.5 hours to 5.0 hours so as to control an amount of residual γ to less than 5.0%. 9. The method of manufacturing a nitrocarburized crankshaft according to claim 8 , wherein the nitrocarburizing treatment is performed for 0.5 hours or longer under a gas atmosphere at a temperature in a range of from 550° C. to 650° C., and a core part has a hardness of 270 HV or greater.
for crankshafts; for camshafts · CPC title
Pretreatment of the material to be coated (C23C8/04 takes precedence) · CPC title
made in one piece (features relating to lubrication F16C3/14, to cooling F16C3/16) · CPC title
of ferrous surfaces · CPC title
Crankshafts · CPC title
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