Methods and systems for distributing a slurry catalyst in cellulosic biomass solids

Patent metadata

Field	Value
Publication number	US-9593242-B2
Application number	US-201314067309-A
Country	US
Kind code	B2
Filing date	Oct 30, 2013
Priority date	Oct 31, 2012
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

Digestion of cellulosic biomass solids may be complicated by release of lignin therefrom. Methods for digesting cellulosic biomass solids may comprise: heating cellulosic biomass solids and a digestion solvent in the presence of molecular hydrogen and a slurry catalyst capable of activating molecular hydrogen, thereby forming a phenolics liquid phase comprising lignin, an aqueous phase comprising an alcoholic component derived from the cellulosic biomass solids, and an optional light organics phase, the slurry catalyst being distributed in the cellulosic biomass solids and at least a portion of the slurry catalyst accumulating in the phenolics liquid phase as it forms; conveying at least a portion of the phenolics liquid phase and the slurry catalyst to a location above at least a portion of the cellulosic biomass solids; and after conveying the phenolics liquid phase and the slurry catalyst, releasing them such that they come in contact with the cellulosic biomass solids.

First claim

What is claimed is:

1. A method comprising:
providing cellulosic biomass solids in a digestion solvent;
heating the cellulosic biomass solids and the digestion solvent in the presence of molecular hydrogen and a slurry catalyst capable of activating molecular hydrogen, thereby forming a phenolics liquid phase comprising lignin, an aqueous phase comprising an alcoholic component derived from the cellulosic biomass solids, and an optional light organics phase, the slurry catalyst being distributed in the cellulosic biomass solids and at least a portion of the slurry catalyst accumulating in the phenolics liquid phase as it forms;
supplying upwardly directed fluid flow through the cellulosic biomass solids wherein at least a portion of the slurry catalyst is upwardly conveyed by the upwardly directed fluid flow into at least a portion of the cellulosic biomass solids;
conveying at least a portion of the phenolics liquid phase and the slurry catalyst therein to a location above at least a portion of the cellulosic biomass solids; and
after conveying the phenolics liquid phase and the slurry catalyst, releasing them such that they come in contact with the cellulosic biomass solids.

2. The method of claim 1 , wherein the phenolics liquid phase and the slurry catalyst are conveyed external to the cellulosic biomass solids.

3. The method of claim 1 , wherein the alcoholic component is formed by a catalytic reduction reaction of soluble carbohydrates, the soluble carbohydrates being derived from the cellulosic biomass solids.

4. The method of claim 3 , wherein the alcoholic component comprises a monohydric alcohol, a glycol, a triol, or any combination thereof.

5. The method of claim 3 , wherein the alcoholic component comprises a glycol.

6. The method of claim 1 , wherein the upwardly directed fluid flow comprises a gas stream, a liquid stream, or any combination thereof.

7. The method of claim 1 , wherein the upwardly directed fluid flow comprises a stream of the aqueous phase, the phenolics liquid phase, or any combination thereof.

8. The method of claim 1 , wherein the upwardly directed fluid flow passes through the phenolics liquid phase.

9. The method of claim 1 , further comprising:
at least partially depolymerizing the lignin in at least a portion of the phenolics liquid phase.

10. The method of claim 9 , further comprising:
before or after at least partially depolymerizing the lignin, separating at least a portion of the phenolics liquid phase from the aqueous phase.

11. The method of claim 9 , further comprising:
after at least partially depolymerizing the lignin, removing the slurry catalyst from the phenolics liquid phase.

12. The method of claim 1 , further comprising:
separating at least a portion of the phenolics liquid phase from the aqueous phase.

13. The method of claim 1 , wherein the slurry catalyst comprises a poison-tolerant catalyst.

14. The method of claim 13 , wherein the poison-tolerant catalyst comprises a sulfided catalyst.

15. The method of claim 1 , wherein after being released, the phenolics liquid phase and the slurry catalyst downwardly percolate through the cellulosic biomass solids.

16. The method of claim 15 , wherein after being released, the phenolics liquid phase forms droplets containing the slurry catalyst that downwardly percolate through the cellulosic biomass solids.

17. The method of claim 1 , wherein heating the cellulosic biomass solids and the digestion solvent in the presence of molecular hydrogen and the slurry catalyst takes place in a hydrothermal digestion unit, the hydrothermal digestion unit comprising a fluid conduit for conveying the phenolics liquid phase from a lower portion of the hydrothermal digestion unit to a location above at least a portion of the cellulosic biomass solids.

18. The method of claim 17 , wherein the fluid conduit conveys the phenolics liquid phase to an upper portion of the hydrothermal digestion unit.

19. The method of claim 18 , wherein an exit of the fluid conduit is operably connected to a flow dispersal system in the upper portion of the hydrothermal digestion unit.

20. The method of claim 17 , wherein the fluid conduit conveys the phenolics liquid phase to a location above at least a portion of the cellulosic biomass solids at a location before the cellulosic biomass solids are introduced to the hydrothermal digestion unit.

21. The method of claim 1 , wherein conveying and releasing at least a portion of the phenolics liquid phase and the slurry catalyst comprises circulating the phenolics liquid phase through the cellulosic biomass solids.

22. A method comprising:
providing cellulosic biomass solids in a digestion solvent;
heating the cellulosic biomass solids and the digestion solvent in the presence of molecular hydrogen and a slurry catalyst capable of activating molecular hydrogen, thereby forming a phenolics liquid phase comprising lignin, an aqueous phase comprising an alcoholic component derived from the cellulosic biomass solids, and an optional light organics phase, at least a portion of the slurry catalyst accumulating in the phenolics liquid phase as it forms;
supplying upwardly directed fluid flow through the cellulosic biomass solids wherein at least a portion of the slurry catalyst is upwardly conveyed by the upwardly directed fluid flow into at least a portion of the cellulosic biomass solids;
conveying at least a portion of the phenolics liquid phase and the slurry catalyst therein to a location above at least a portion of the cellulosic biomass solids; and
after conveying the phenolics liquid phase and the slurry catalyst, releasing them and downwardly percolating the phenolics liquid phase and the slurry catalyst through the cellulosic biomass solids.

23. The method of claim 22 , wherein the phenolics liquid phase and the slurry catalyst are conveyed external to the cellulosic biomass solids.

24. The method of claim 22 , wherein the alcoholic component is formed by a catalytic reduction reaction of soluble carbohydrates, the soluble carbohydrates being derived from the cellulosic biomass solids.

25. The method of claim 24 , wherein the alcoholic component comprises a monohydric alcohol, a glycol, a triol, or any combination thereof.

26. The method of claim 24 , wherein the alcoholic component comprises a glycol.

27. The method of claim 22 , wherein the upwardly directed fluid flow comprises a gas stream, a liquid stream, or any combination thereof.

28. The method of claim 22 , wherein the upwardly directed fluid flow passes through the phenolics liquid phase.

29. The method of claim 22 , wherein the upwardly directed fluid flow comprises a stream of the aqueous phase, the phenolics liquid phase, or any combination thereof.

30. The method of claim 22 , further comprising:
at least partially depolymerizing the lignin in at least a portion of the phenolics liquid phase.

31. The method of claim 30 , further comprising:
before or after at least partially depolymerizing the lignin, separating at least a portion of the phenolics liquid phase from the aqueous phase.

32. The method of claim 30 , further comprising:
after at least partially depolymerizing the lignin, removing the slurry catalyst from a portion of the phenolics liquid phase.

33. The m

Assignees

• Shell Oil Co

Inventors

• Powell Joseph Broun
• Komplin Glenn Charles

Classifications

• C08H6/00

  Macromolecular compounds derived from lignin, e.g. tannins, humic acids · CPC title

• C08L97/005 Primary

  Lignin · CPC title

• C10G2400/02

  Gasoline · CPC title

• C10G2400/06

  Gasoil · CPC title

• C10G2300/1014

  of vegetal origin · CPC title