Preparation method of thermoplastic resin composition and thermoplastic resin composition prepared therefrom

Patent metadata

Field	Value
Publication number	US-9593236-B2
Application number	US-201414583986-A
Country	US
Kind code	B2
Filing date	Dec 29, 2014
Priority date	Dec 31, 2013
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

Provided are a preparation method of a thermoplastic resin composition and a thermoplastic resin composition prepared therefrom. The preparation method includes: feeding a first thermoplastic resin in a molten state into a first hopper and feeding an impact reinforcing agent including a predetermined content of moisture into a second hopper, followed by kneading and extruding processes, and removing the moisture in a first vent port and a second vent port, wherein the first hopper, the first vent port, the second hopper, a first kneading zone, and the second vent port are sequentially formed in a moving direction of an extruder. The thermoplastic resin composition prepared therefrom can have improved appearance property and improved color property by removing moisture of an impact reinforcing agent added to the thermoplastic resin composition.

First claim

What is claimed is:

1. A preparation method of a thermoplastic resin composition comprising:
feeding a first thermoplastic resin in a molten state into a first hopper and feeding an impact reinforcing agent including a predetermined content of moisture into a second hopper, followed by kneading and extruding processes, and
removing the moisture in a first vent port and a second vent port,
wherein the first hopper, the first vent port, the second hopper, a first kneading zone, and the second vent port are sequentially formed in a moving direction of an extruder.

2. The preparation method of claim 1 , wherein the first vent port is an opened vent without a separate apparatus, and the second vent port is provided with an apparatus selectively extracting steam only.

3. The preparation method of claim 1 , wherein a moisture content W 1 removed in the first vent port and a moisture content W 2 removed in the second vent port have a weight ratio (W 1 /W 2 ) of about 0.5 to about 25.

4. The preparation method of claim 1 , wherein a moisture content removed in the first vent port corresponds to about 60 to about 90 wt % of the total moisture content of the first thermoplastic resin and the impact reinforcing agent, and a moisture content removed in the second vent port corresponds to about 10 to about 40 wt % of the total moisture content of the first thermoplastic resin and the impact reinforcing agent.

5. The preparation method of claim 1 , wherein the first thermoplastic resin is an aromatic vinyl-vinyl cyanide-based copolymer, and the impact reinforcing agent is a rubber-modified vinyl-based graft copolymer.

6. The preparation method of claim 5 , wherein the first thermoplastic resin is at least one selected from the group consisting of a styrene-acrylonitrile copolymer, an α-methyl styrene-acrylonitrile copolymer, and a styrene-a-methyl styrene-acrylonitrile copolymer, and
the impact reinforcing agent is an acrylonitrile-butadiene-styrene graft copolymer (g-ABS) obtained by graft copolymerization with about 30 to about 70 wt % of a mixture containing an aromatic vinyl-based compound and a vinyl cyanide-based compound in the presence of about 30 to about 70 wt % of a rubber-like polymer, using emulsion polymerization.

7. The preparation method of claim 1 , wherein a second kneading zone and a third vent port are further formed after the second vent port.

8. The preparation method of claim 7 , wherein the third vent port includes a vacuum vent, and removes at least one selected from the group consisting of residual water, unreacted monomers, oligomers, and decomposition gases.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Hong Jae Keun
• Kim Beom Ho
• Park Jun Hong
• Chang Ki Bo
• Kim Sung Hun
• Lee Gwang Hwan

Classifications

• B29K2077/10

  Aromatic polyamides [polyaramides] or derivatives thereof · CPC title

• B29C48/767

  through a degassing opening of a barrel · CPC title

• B29C48/297

  at several locations, e.g. using several hoppers or using a separate additive feeding · CPC title

• B29C48/022

  characterised by the choice of material · CPC title

• B29B2009/168

  Removing undesirable residual components, e.g. solvents, unreacted monomers; Degassing · CPC title