Composition containing a particular diene elastomer and a carbon black having a particular specific surface area

Patent metadata

Field	Value
Publication number	US-9593226-B2
Application number	US-201113989167-A
Country	US
Kind code	B2
Filing date	Nov 23, 2011
Priority date	Nov 23, 2010
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

The invention relates to a rubber composition based on one or more specific functionalized diene elastomers and on one or more carbon blacks with a CTAB specific surface varying from 100 to 200 m 2 /g, the functionalized diene elastomer or elastomers being composed of a specific diene elastomer functionalized, at the chain end or in the middle of the chain, by a tin functional group and of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a non-tin functional elastomer. The diene elastomer exhibits a monomodal distribution of molecular weights before functionalization and a polydispersity index before functionalization of less than or equal to 1.3. This composition makes it possible to obtain tires having an improved wear resistance and which are characterized by decrease in rolling resistance, without damaging the processing and the wet grip.

First claim

The invention claimed is:

1. A rubber composition based on one or more functionalized diene elastomers and, as predominant filler, on one or more carbon blacks with a CTAB specific surface varying from 100 to 200 m 2 /g, the functionalized diene elastomer or elastomers being composed:
a) of a diene elastomer functionalized, in the middle of the chain, by a tin functional group and corresponding to the following formula:
[A] n -X-[A] m

where n and m are integers of greater than 0, such that n+m=2,
b) of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a non-tin-functional elastomer corresponding to the following formula:
[A]

where:
A is a diene elastomer, the A blocks being identical to one another,
X is a tin-comprising group,
the elastomer A exhibits a monomodal distribution of molecular weights before optional functionalization and a polydispersity index before optional functionalization of less than or equal to 1.3.

2. The composition according to claim 1 , wherein the functionalized diene elastomer further comprises a diene elastomer star-branched by tin c) corresponding to the following formula:
[A] o -Y-[A]- p where:
o and p are integers of greater than or equal to 0 and such that o+p≧3 and o+p≦6,
A is the diene elastomer as defined in claim 1 , it being understood that it exhibits a monomodal distribution of molecular weights before star-branching and a polydispersity index before star-branching of less than or equal to 1.3,
Y is a tin-comprising group.

3. The composition according to claim 2 , wherein the functionalized diene elastomer comprises from 5% to 45% by weight, with respect to the total weight of the functionalized diene elastomer, of the elastomer star-branched by tin c).

4. The composition according to claim 1 , wherein the functionalized diene elastomer comprises a content strictly of greater than 0% by weight and of less than 10% by weight, with respect to the total weight of the functionalized diene elastomer, of the non-tin-functional elastomer b).

5. The composition according to claim 1 , wherein the functionalization of the diene elastomer a) is obtained with a dihalotin functionalization agent.

6. The composition according to claim 2 , wherein the star-branching of the diene elastomer star-branched by tin c) is obtained with a tri- or tetrahalotin star-branching agent.

7. The composition according to claim 2 , wherein the diene elastomer star-branched by tin c) is a star-branched elastomer having 4 branches.

8. The composition according to claim 1 , wherein the diene elastomer is selected from the group consisting of polybutadienes, random or block butadiene/styrene copolymers, random or block butadiene/isoprene copolymers, random or block butadiene/styrene/isoprene copolymers, random or block styrene/isoprene copolymers and synthetic polyisoprene.

9. The composition according to claim 1 , wherein the diene elastomer [A]- corresponds to the following formula:
[B-C]-
where:
the B block is composed of a polyisoprene or of a polybutadiene,
the C block is composed of a diene elastomer, the molar content of units resulting from conjugated dienes of which is greater than 15%,
the number-average molecular weight Mn1 of the B block varies from 2,500 to 20,000 g/mol,
the number-average molecular weight Mn2 of the C block varies from 80,000 to 350,000 g/mol,
the content of 1,2 linkages in the B block is between 1% and 20% in the case where B is a polybutadiene block,
the content of 3,4 linkages in each B block is between 1% and 25% in the case where B is a polyisoprene block,
the B-C copolymer exhibits a monomodal distribution of molecular weights before optional functionalization or optional star-branching and a polydispersity index before optional functionalization or optional star-branching of less than or equal to 1.3.

10. The composition according to claim 9 , wherein the number-average molecular weight Mn1 of each end polybutadiene or polyisoprene B block is from 5% to 20% of the number-average molecular weight Mn2 of each of the C blocks.

11. The composition according to claim 9 , wherein the C block is selected from the group consisting of copolymers of styrene and butadiene, copolymers of styrene and isoprene, copolymers of butadiene and isoprene, styrene/butadiene/isoprene copolymers, polyisoprene when the neighbouring B block is a polybutadiene and polybutadiene when the neighbouring B block is a polyisoprene.

12. The composition according to claim 1 , wherein the diene elastomer a) comprises an amine functional group at one or all of the ends of chains not functionalized by tin.

13. The composition according to claim 1 , wherein the diene elastomer b) comprises an amine functional group at one of the ends of the chains.

14. The composition according to claim 2 , wherein the diene elastomer star-branched by tin c) comprises an amine functional group at the ends of chains not star-branched by tin.

15. The composition according to claim 1 , wherein the functionalized diene elastomer or elastomers represent from 30 to 100 phr of the composition.

16. The composition according to claim 1 , wherein the carbon black or blacks with a CTAB specific surface varying from 100 to 200 m 2 /g represent from 30 to 100 phr.

17. The composition according to claim 1 , wherein it further comprises a chemical crosslinking agent.

18. A semi-finished article made of rubber for a tire, comprising a rubber composition as defined in claim 1 .

19. A semi-finished article according to claim 18 , wherein the article is a tread.

20. A tire, wherein the tire comprises a semi-finished article as defined in claim 18 .

Assignees

• Cambon Stéphanie
• Thomasson Damien
• Michelin & Cie
• Michelin Rech Tech

Inventors

• Cambon Stéphanie
• Thomasson Damien

Classifications

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title

• B60C1/0016

  Compositions of the tread · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L15/00 Primary

  Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title