Method for producing olefin block polymer using group 4 transition metal complex

Patent metadata

Field	Value
Publication number	US-9593194-B2
Application number	US-201414176537-A
Country	US
Kind code	B2
Filing date	Feb 10, 2014
Priority date	Aug 11, 2011
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

A method for producing an olefin block polymer, the method including: polymerizing olefins using a polymerization catalyst (X) and an organometallic compound (C) containing an atom of any of Groups 2, 12, and 13 of the periodic table of the elements, the organometallic compound (C) excluding an activating co-catalyst agent (B), wherein the polymerization catalyst (X) is formed by bringing a transition metal compound (A) into contact with the activating co-catalyst agent (B), the transition metal compound (A) is represented by the following general formula (1), and the activating co-catalyst agent (B) is selected from among an organoaluminumoxy compound (B-1), an organoboron compound (B-2), a zinc co-catalyst component (B-3), and ion-exchange layered silicate (B-4).

First claim

The invention claimed is:

1. A method for producing an olefin block polymer, the method comprising:
polymerizing olefins using a polymerization catalyst (X) and an organometallic compound (C) containing an atom of any of Groups 2, 12, and 13 of the periodic table of the elements, the organometallic compound (C) excluding an activating co-catalyst agent (B),
wherein the polymerization catalyst (X) is formed by bringing a transition metal compound (A) into contact with the activating co-catalyst agent (B), and the transition metal compound (A) is represented by the following general formula (1),

where
n is 1, 2, or 3;
M X represents a titanium atom, a zirconium atom, or a hafnium atom;
R X1 to R X8 are independently:
a hydrogen atom,
a halogen atom,
an alkyl group having 1 to 20 carbon atoms,
a cycloalkyl group having 3 to 10 ring carbon atoms,
an alkenyl group having 2 to 20 carbon atoms,
an alkynyl group having 2 to 20 carbon atoms,
an aralkyl group having 7 to 30 carbon atoms,
an aryl group having 6 to 30 carbon atoms,
an alkoxy group having 1 to 20 carbon atoms,
an aralkyloxy group having 7 to 30 carbon atoms,
an aryloxy group having 6 to 30 carbon atoms,
a substituted silyl group, or
a heterocyclic compound residue having 3 to 20 ring carbon atoms;

the alkyl groups, the cycloalkyl groups, the alkenyl groups, the alkynyl groups, the aralkyl groups, the aryl groups, the alkoxy groups, the aralkyloxy groups, the aryloxy groups, and the heterocyclic compound residues represented by R X1 to R X8 each optionally have a substituent;
notwithstanding the above definitions of R X1 to R X8 , each of the following pairs, R X1 and R X2 , R X2 and R X3 , R X3 and R X4 , R X5 and R X6 , R X6 and R X7 , and R X7 and R X8 , are optionally linked to each other to form a ring optionally having a substituent;
each X X is independently:
a hydrogen atom,
a halogen atom,
an alkyl group having 1 to 20 carbon atoms,
a cycloalkyl group having 3 to 10 ring carbon atoms,
an alkenyl group having 2 to 20 carbon atoms,
an aralkyl group having 7 to 30 carbon atoms,
an aryl group having 6 to 30 carbon atoms,
an alkoxy group having 1 to 20 carbon atoms,
an aralkyloxy group having 7 to 30 carbon atoms,
an aryloxy group having 6 to 30 carbon atoms,
a substituted silyl group having 1 to 20 carbon atoms,
a substituted amino group having 1 to 20 carbon atoms,
a substituted thiolate group having 1 to 20 carbon atoms, or
a carboxylate group having 1 to 20 carbon atoms;

the alkyl group, the cycloalkyl group, the alkenyl group, the aralkyl group, the aryl group, the alkoxy group, the aralkyloxy group, the aryloxy group, and the carboxylate group represented by X X optionally have a substituent;
X X groups are optionally linked to each other to form a ring;
E X is independently a neutral Lewis base, and the subscript x representing the number of E X groups is 0, 1, or 2; when the subscript x is 2, the E X groups are the same or different,
the activating co-catalyst agent (B) is selected from among an organoaluminumoxy compound (B-1), an organoboron compound (B-2), a zinc co-catalyst component (B-3), and ion-exchange layered silicate (B-4), wherein the olefin block polymer is an ethylene/propylene copolymer composition that satisfies the following requirements (1) through (5):
(1) EP CXIS ≧3.0 wt %;
(2) ΔEP≦20%;
(3) 15.0≧M w /M n ≧1.7;
(4) (T m of the ethylene/propylene copolymer composition)≧135° C.; and
(5) (T g of the ethylene/propylene copolymer composition)≦−30° C. where:
EP CXIS represents an EP (ethylene/propylene random copolymer) content in a room temperature xylene insoluble component;
ΔEP is an arithmetic mean of absolute values of ratio differences of five triads, excluding PPP (propylene triad), each of the ratio differences being a difference between a ratio of one of the five triads in the room-temperature xylene-insoluble component and a ratio of the triad in the room-temperature xylene-soluble component;
M w /M n represents a molecular weight distribution;
T m represents a melting point; and
T g represents a glass transition point.

2. The method as set forth in claim 1 , wherein:
R X1 and R X5 are independently:
a hydrogen atom,
a halogen atom,
an alkyl group having 1 to 20 carbon atoms,
a cycloalkyl group having 3 to 10 ring carbon atoms,
an aralkyl group having 7 to 30 carbon atoms,
an alkoxy group having 1 to 20 carbon atoms,
an aralkyloxy group having 7 to 30 carbon atoms,
an aryloxy group having 6 to 30 carbon atoms, or
a substituted silyl group.

3. The method as set forth in claim 1 , wherein n is 3.

4. The method as set forth in claim 1 , wherein:
the organometallic compound (C) contains an organoaluminum compound and/or an organozinc compound.

5. The method as set forth in claim 4 , wherein:
the organometallic compound (C) contains an organoaluminum compound having 3 to 24 carbon atoms and/or an organozinc compound having 2 to 16 carbon atoms.

6. The method as set forth in claim 1 , wherein:
the method is multistage polymerization including a plurality of polymerization steps;
any two adjacent polymerization steps differ in the polymerization catalyst (X) to be formed and/or olefin composition; and
in each of the polymerization steps, the olefins are polymerized in the presence of a polymer obtained by the last preceding polymerization step.

7. The method as set forth in claim 6 , wherein:
in the multistage polymerization, each polymerization step is carried out in the same reaction vessel or the same reaction zone in the presence of a polymer produced by the last preceding polymerization step.

8. The method as set forth in claim 6 , wherein:
the multistage polymerization is two-stage polymerization, wherein the former stage and the latter stage differ in the polymerization catalyst (X) to be formed and/or olefin composition; and the olefins are polymerized in the presence of a polymer obtained by the last preceding polymerization step.

9. The method as set forth in claim 8 , wherein:
the former stage and the latter stage of the two-stage polymerization differ in olefin composition.

10. The method as set forth in claim 9 , wherein:
copolymerization of two or more olefins is carried out in one of the former stage and the latter stage of the two-stage polymerization; and
homopolymerization of one olefin is carried out in the other one of the former stage and the latter stage.

11. The method as set forth in claim 10 , wherein:
copolymerization of ethylene and propylene is carried out in one of the former stage and the latter stage of the two-stage polymerization; and
homopolymerization of propylene is carried out in the other one of the former stage and the latter stage.

12. An ethylene/propylene copolymer composition that satisfies the following requirements (1) through (5):
(1) EP CXIS ≧3.0 wt %;
(2) ΔEP≦20%;
(3) 15.0≧M w /M n ≧1.7;
(4) (T m of the ethylene/propylene copolymer composition)≧135° C.; and
(5) (T g of the ethylene/propylene copolymer composition)≦−30° C. where:
EP CXIS represents an EP (ethylene/propylene random copolymer) content in a room temperature xylene insoluble component;
ΔEP is an arithmetic mean of absolute values of ratio differences of five triads, excluding PPP (propylene triad), each of the ratio differences being a difference between a r

Assignees

• Sumitomo Chemical Co

Inventors

• Ishiwata Koji
• Takano Masato
• Takaoki Kazuo

Classifications

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08L23/0807

  with unsaturated hydrocarbons only containing four or more carbon atoms · CPC title

• C08L2308/00

  Chemical blending or stepwise polymerisation process with the same catalyst · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08F255/04 Primary

  on to ethylene-propylene copolymers {(C08F255/023 takes precedence)} · CPC title