Suspension of solid catalyst component used in propylene polymerization, method of preparing the same, and method of propylene polymerization

Patent metadata

Field	Value
Publication number	US-9593185-B2
Application number	US-201414561617-A
Country	US
Kind code	B2
Filing date	Dec 5, 2014
Priority date	Dec 6, 2013
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

The present disclosure provides a suspension of a solid catalyst component used in propylene polymerization and a method for preparing the same. The suspension includes the solid catalyst component and a liquid medium containing propylene and an alkane, and is preferably prepared by mixing the solid catalyst component and the alkane to obtain a mixed slurry, which is further mixed with liquid propylene. Using of a proper liquid dispersing agent at a proper proportion and amount enables the solid catalyst component to be more homogeneously dispersed, thus preventing the phenomenon of agglomeration in the polymerization process without using a large amount of the dispersing agent or any additional mixer. The present disclosure further provides a method of propylene polymerization, including feeding the suspension into a reaction system of propylene polymerization, wherein propylene polymerization is initiated under polymerization conditions.

First claim

The invention claimed is:

1. A stable suspension of a solid catalyst component used in propylene polymerization, wherein said suspension comprises said solid catalyst component and a liquid medium containing propylene and an alkane for dispersing said solid catalyst component.

2. The stable suspension according to claim 1 , wherein said alkane comprises at least one selected from C 6 -C 100 alkanes.

3. The stable suspension according to claim 1 , wherein said alkane is white oil.

4. The stable suspension according to claim 1 , wherein the weight ratio of the propylene to the alkane is in the range from 0.1:1 to 45:1.

5. The stable suspension according to claim 1 , wherein the weight ratio of the solid catalyst component to the alkane is in the range from 1:0.5 to 1:20.

6. The stable suspension according to claim 1 , wherein said solid catalyst component comprises magnesium, titanium, a halogen, and an internal electron donor, which is at least one selected from the group consisting of aliphatic ethers, cycloaliphatic ethers, aliphatic ketones, and monobasic acid esters or polybasic acid esters formed from aliphatic or aromatic carboxylic acids.

7. A method for preparing a stable suspension of a solid catalyst component used in propylene polymerization, comprising dispersing said solid catalyst component into a liquid medium containing propylene and an alkane to form the stable suspension.

8. The method according to claim 7 , comprising the steps of:
1) mixing the solid catalyst component and a dispersant which contains the alkane to form a mixed slurry, the alkane accounting for more than 98% by of said dispersant; and
2) mixing said mixed slurry and liquid propylene to form said suspension.

9. The method according to claim 7 , comprising the steps of:
1) adding a mixed slurry of the solid catalyst component and the alkane directly into a catalyst storage tank of a propylene polymerization apparatus, or adding said solid catalyst component and the alkane respectively into the catalyst storage tank of the propylene polymerization apparatus and mixing the same to obtain the mixed slurry; and
2) adding liquid propylene which is to be mixed with the mixed slurry to obtain said suspension.

10. The method according to claim 8 , wherein said alkane comprises at least one selected from C 6 -C 100 alkanes.

11. The method according to claim 8 , wherein the weight ratio of the propylene to the alkane is in the range from 0.1:1 to 45:1.

12. The method according to claim 8 , wherein the weight ratio of the solid catalyst component to the alkane is in the range from 1:0.5 to 1:20.

13. The method according to claim 8 , wherein the mixing temperature in step 1) ranges from 30 to 90° C.

14. The method according to claim 9 , wherein the mixing temperature in step 1) ranges from 30 to 90° C.

15. The method according to claim 8 , wherein a concentration of the solid catalyst component in the mixed slurry obtained in step 1) ranges from 20 to 40 wt %, and a weight ratio of the propylene to the mixed slurry in step 2) ranges from 3:1 to 10:1.

16. A method for propylene polymerization, comprising the steps of:
a) mixing a solid catalyst component and a dispersant which contains an alkane to form a mixed slurry, the alkane accounting for more than 98% by weight of said dispersant;
b) mixing said mixed slurry and liquid propylene to form a stable suspension;
c) introducing the stable suspension into a propylene polymerization system;
d) adding an aluminum alkyl compound and an external electron donor into the system; and
e) initiating propylene polymerization under polymerization conditions.

17. The method according to claim 16 , wherein the weight ratio of the propylene to the alkane is in the range from 0.1:1 to 45:1.

18. The method according to claim 16 , wherein a concentration of the solid catalyst component in the mixed slurry of step a) ranges from 20 to 40 wt %, and a weight ratio of the propylene to the mixed slurry in step b) ranges from 3:1 to 10:1.

19. The method according to claim 16 , wherein said polymerization conditions comprise a temperature in the range from 0 to 150° C. and a pressure in the range from 0.1 to 10 MPa.

20. The method according to claim 16 , wherein said aluminum alkyl compound is at least one selected from the group consisting of compounds having a general formula of AlR 1 n X 1 3-n , with “n” equaling 2 or 3, “R 1 ”, identical to or different from one another, being hydrogen or a C 1 -C 20 straight or branched alkyl group, and “X 1 ” being a halogen; and
wherein said external electron donor is at least one selected from the group consisting of compounds having a general formula of R 2 p Si(OR 3 ) 4-p , with “p” as an integer in the range from 0 to 3, “R 2 ”, identical to or different from one another, being selected from the group consisting of C 1 -C 10 straight or branched alkyl groups, substituted or unsubstituted C 3 -C 10 cyclic hydrocarbyl groups, substituted or unsubstituted C 6 -C 12 aryl groups, and C 1 -C 10 halogenated alkyl groups, and “R 3 ”, identical to or different from one another, being selected from the group consisting of halogens, hydrogen, C 1 -C 10 straight or branched alkyl groups, substituted or unsubstituted C 3 -C 10 cyclic alkyl groups, substituted or unsubstituted C 6 -C 12 aryl groups, and C 1 -C 10 halogenated alkyl groups.

Assignees

• China Petroleum & Chem Corp
• Sinopec Catalyst Co Ltd
• Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp

Inventors

• Qin Jinlai
• Cui Haixiang
• Wang Xiaodong
• Gao Mingzhi
• Xiao Cuiling
• Sun Yanju
• Pan Liang
• Chen Xin
• Wang Ziqiang

Classifications

• C08F110/06 Primary

  Propene · CPC title