Ammonia synthesis catalyst

Patent metadata

Field	Value
Publication number	US-9592495-B2
Application number	US-201414573439-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Dec 24, 2013
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

An ammonia synthesis catalyst synthesizing ammonia from nitrogen in a presence of moisture is provided. The ammonia synthesis catalysis includes a catalyst particle including an inorganic material that has a photocatalytic function and an inorganic acid. The catalyst particle is preferably an n-type semiconductor and includes oxide material including at least titanium preferably. The inorganic acid preferably corresponds to at least one of perchloric acid, hydrochloric acid, sulfuric acid, and phosphoric acid.

First claim

What is claimed is:

1. An ammonia synthesis catalyst synthesizing ammonia from nitrogen in a presence of moisture comprising:
a catalyst particle including an inorganic material that has a photocatalytic function; and
an inorganic acid.

2. The ammonia synthesis catalyst according to claim 1 , wherein the catalyst particle comprises an n-type semiconductor.

3. The ammonia synthesis catalyst according to claim 1 , wherein the catalyst particle includes oxide that includes at least titanium.

4. The ammonia synthesis catalyst according to claim 1 , wherein the inorganic acid comprises at least one of perchloric acid, hydrochloric acid, sulfuric acid and phosphoric acid.

5. The ammonia synthesis catalyst according to claim 1 , wherein the inorganic acid comprises at least perchloric acid.

6. The ammonia synthesis catalyst according to claim 1 , wherein the inorganic acid is attached to a surface of the catalyst particle.

7. The ammonia synthesis catalyst according to claim 6 , wherein the catalyst particle comprises at least one of the rutile-type titanium oxide and an anatase-type titanium oxide.

8. The ammonia synthesis catalyst according to claim 7 , wherein the inorganic acid comprises at least perchloric acid.

9. The ammonia synthesis catalyst according to claim 7 , wherein the inorganic acid comprises at least hydrochloric acid.

10. The ammonia synthesis catalyst according to claim 7 , wherein the inorganic acid comprises at least sulfuric acid.

11. The ammonia synthesis catalyst according to claim 7 , wherein the inorganic acid comprises at least phosphoric acid.

12. The ammonia synthesis catalyst according to claim 1 , wherein the inorganic material that has the photo catalytic function comprises at least one of titanium oxide, sodium titanate, strontium titanate, barium titanate, iron titanate, and zirconium titanate; and
the inorganic acid comprises at least one of hydrofluoric acid, hydrochloric acid, hydroiodic acid, boric acid, carbonic acid, perchloric acid, nitric acid, sulfuric acid, and phosphoric acid.

13. The ammonia synthesis catalyst according to claim 1 , wherein the inorganic material that has the photocatalytic function comprises titanium oxide; and
the inorganic acid comprises at least one of hydrochloric acid, perchloric acid, nitric acid, sulfuric acid, and phosphoric acid.

14. An ammonia synthesis catalyst that synthesizes ammonia from nitrogen in presence of moisture, comprising:
a catalyst particle including titanium oxide as an inorganic material that has a photocatalytic function; and
at least one of hydrochloric acid, perchloric acid, nitric acid, sulfuric acid, and phosphoric acid as an inorganic acid,
wherein when the ammonia synthesis catalyst is irradiated with light in atmosphere including nitrogen and moisture, ammonia is generated from water and nitrogen.

15. An ammonia synthesis catalyst synthesizing ammonia from nitrogen in a presence of moisture, the ammonia synthesis catalyst comprising:
a catalyst particle including an inorganic material that has a photocatalytic function, the catalyst particle being selected from the group consisting of tungstic oxide, tin oxide, copper oxide, zinc oxide, gallium oxide, zirconium oxide, tantalum oxide, niobium oxide, molybdenum oxide, vanadium oxide, titanium oxide, sodium titanate, strontium titanate, barium titanate, iron titanate, and zirconium titanate; and
an inorganic acid selected from the group consisting of hydrofluoric acid, hydrochloric acid, hydroiodic acid, boric acid, carbonic acid, perchloric acid, nitric acid, sulfuric acid, and phosphoric acid.

Assignees

• Denso Corp

Inventors

• Yoshinaga Masaki
• Yotou Hiroaki
• Iijima Goh
• Hijikata Yoshimasa

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J23/38

  of noble metals · CPC title

• B01J23/70

  of the iron group metals or copper · CPC title

• B01J27/18 Primary

  with metals {other than Al or Zr} · CPC title

• B01J27/053

  Sulfates · CPC title