Detection using microwave assisted NQR

Patent metadata

Field	Value
Publication number	US-9588201-B1
Application number	US-201414154293-A
Country	US
Kind code	B1
Filing date	Jan 14, 2014
Priority date	Jan 14, 2013
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

A system and method for detecting at least one compound in a material under test (MUT) is presented. The system includes a Nuclear Quadrupole Resonance (NQR) frequency generator that generates an NQR frequency (f NQR ) and propagates the f NQR frequency toward the MUT. A microwave frequency generator generates a microwave frequency (f mw ) and propagates the f mw frequency toward the MUT. A RF output probe detects radio frequency (RF) emissions returned from the MUT. A detector detects the at least one compound based, at least in part, on whether the RF emissions returned from the MUT include any frequencies corresponding to f mw +/−(n×f NQR ), where n is an integer of 2 or greater. In the preferred embodiment, n=2.

First claim

What is claimed is:

1. A system for detecting at least one compound in a material under test comprising:
a Nuclear Quadrupole Resonance frequency generator configured to generate an Nuclear Quadrupole Resonance frequency (f NQR ) and adapted to propagate the Nuclear Quadrupole Resonance frequency to the material under test;
a microwave frequency generator to generate a microwave frequency (f MW ) and adapted to propagate the microwave frequency to the material under test;
a radio frequency input probe for to propagate the Nuclear Quadrupole Resonance frequency to the material under test;
a radio frequency output probe adapted to detect returned radio frequency signals which are returned from the material under test;
a waveguide for receiving the returned radio frequency signals which are returned from the material under test;
wherein the radio frequency input probe is near a first end of the waveguide and the radio frequency output probe is near a second end of the waveguide;
wherein the material under test is located in the waveguide and located between the radio frequency input probe and the radio frequency output probe; and
a detector adapted to detect the at least one compound based, at least in part, on whether the returned radio frequency signals which are returned from the material under test include frequencies corresponding to f MW +/−(n×f NQR ), where n is an integer of 2 or greater.

2. The system for detecting the at least one compound of claim 1 wherein n=2.

3. The system for detecting at least one compound of claim 1 further comprising:
a coil of wire wrapped inside the waveguide, wherein the Nuclear Quadrupole Resonance frequency generator is configured to propagate the Nuclear Quadrupole Resonance frequency to the material under test through the coil of wire.

4. The system for detecting at least one compound of claim 3 further comprising:
a balun connected between the Nuclear Quadrupole Resonance frequency generator and the coil of wire.

5. The system for detecting at least one compound of claim 3 wherein the waveguide is rectangular in shape with open opposite ends.

6. The system for detecting at least one compound of claim 3 wherein the coil is located near a center of the waveguide.

7. The system for detecting at least one compound of claim 1 wherein the waveguide is constructed to allow people to walk through within the waveguide without being aware the system is devised to detect at least one compound.

8. The system for detecting at least one compound of claim 1 wherein the detector further comprises:
a spectrum analyzer.

9. The system for detecting at least one compound of claim 8 wherein the spectrum analyzer further comprises:
a 1 kHz window filter and is configured to detect a return frequency of f MW +(2×f NQR ) with a single scan of the 1 kHz window filter.

10. The system for detecting at least one compound of claim 1 wherein f MW between 3 Gigahertz (GHz) and 7 GHz.

11. The system for detecting at least one compound of claim 1 further comprising:
a horn antenna configured to receive the radio frequency emissions returned from the material under test; and
a coil of wire configured to propagate the Nuclear Quadrupole Resonance frequency to the material under test.

12. The system for detecting at least one compound of claim 1 wherein the coil of wire is adjacent the horn antenna.

13. The system for detecting at least one compound of claim 1 further comprising:
a directional coupler connecting the horn antenna, the microwave frequency generator and the detector together.

14. The system for detecting at least one compound of claim 1 further comprising:
an elongated member;
a handle attached to the elongated member, wherein the entire system is handheld, and wherein the horn antenna and coil are adapted to be swept back and forth like a traditional metal detector antenna.

15. The system for detecting at least one compound of claim 1 wherein the compound further comprises:
nitrogen.

16. A method of determining at least one compound in a material under test comprising steps of:
providing a Nuclear Quadrupole Resonance frequency generator;
providing a radio frequency input probe for to propagate the Nuclear Quadrupole Resonance frequency to a material under test;
providing a radio frequency output probe to detect returned radio frequency signal returned from the material under test;
providing a waveguide for receiving the returned radio frequency signal;
wherein the radio frequency input probe is near a first end of the waveguide and the radio frequency output probe is near a second end of the waveguide;
propagating a Nuclear Quadrupole Resonance frequency (f NQR ) toward the material under test;
propagating a frequency that is at least double the Nuclear Quadrupole Resonance frequency (f DBL ) toward the material under test;
detecting the returned radio frequency signal from the material under test; and
determining if the returned radio frequency signal has a frequency of f DBL +/−(n×f NQR ) where n is an integer=2 or greater, and wherein the returned frequency radio signal of f DBL +/−(n×f NQR ) indicates the compound is present in the material under test.

17. The method of claim 16 further comprising a step of:
generating an indication the compound is present when there is the returned signal of f MW +/−(n×f NQR ).

18. The method of claim 17 wherein the indication further comprises:
at least one of the group of: a visual indicator and an audio indicator.

Assignees

• Bae Sys Inf & Elect Sys Integ

Inventors

• Harris Don A
• Bowers Ii Michael J
• Gilbert Roland A
• Kippeny Tadd C

Classifications

• G01R33/3607

  RF waveform generators, e.g. frequency generators, amplitude-, frequency- or phase modulators or shifters, pulse programmers, digital to analog converters for the RF signal, means for filtering or attenuating of the RF signal · CPC title

• G01R33/441 Primary

  Nuclear Quadrupole Resonance [NQR] Spectroscopy and Imaging · CPC title

• G01R33/34053

  Solenoid coils; Toroidal coils · CPC title

• G01R33/3635

  Multi-frequency operation · CPC title

• G01N24/084

  Detection of potentially hazardous samples, e.g. toxic samples, explosives, drugs, firearms, weapons · CPC title