Noble metal-containing compound detection by catalysis of optical dye reduction
US-2024377333-A1 · Nov 14, 2024 · US
US9588053B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9588053-B2 |
| Application number | US-201314379668-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 28, 2013 |
| Priority date | Feb 29, 2012 |
| Publication date | Mar 7, 2017 |
| Grant date | Mar 7, 2017 |
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A replacement indicator can be operatively associated with an elastomeric article such that the replacement indicator is visually observable. In some cases, the replacement indicator can be secured on or along the elastomeric article. Gas spring assemblies and pneumatic tires including a replacement indicator, as well as methods of manufacture are also included.
Opening claim text (preview).
The invention claimed is: 1. A replacement indicator for use in cooperation with an associated elastomeric spring member having an associated exterior surface, said replacement indicator comprising a layer of material including a first side securable along the associated exterior surface of the associated elastomeric spring member and a second side facing opposite said first side such that said second side is exposable to one or more environmental agents to which the associated elastomeric spring member would be simultaneously exposed in an installed condition of said replacement indicator, said layer of material having a visually-observable characteristic that changes from a first color to a second color that is different from said first color upon exposure to a predetermined level of said one or more environmental agents with said change from said first color to said second color capable of being correlated to a change in a material characteristic of the associated elastomeric spring member. 2. A replacement indicator according to claim 1 , wherein said one or more environmental agents includes ozone (O 3 ). 3. A replacement indicator according to claim 1 , wherein said one or more environmental agents includes oxygen (O 2 ). 4. A replacement indicator according to claim 1 , wherein said one or more environmental agents includes heat. 5. A replacement indicator according to claim 1 further comprising an adhesive layer disposed along said first side of said layer of material and adapted to attach said replacement indicator to the associated exterior surface of the associated elastomeric spring member. 6. A replacement indicator according to claim 5 further comprising a removable protective layer extending across at least a portion of said adhesive layer such that said protective layer can at least partially inhibit inadvertent adhesion of said adhesive layer to an object prior to use. 7. A replacement indicator according to claim 1 further comprising a protective layer disposed along at least a portion of said second side of said layer of material and extending across at least a portion of said layer of material such that said protective layer can at least partially inhibit exposure of said layer of material to said one or more environmental agents prior to use. 8. A replacement indicator according to claim 1 , wherein said change of said visually-observable characteristic from said first color to said second color is presented as at least one of a pattern, one or more symbols and one or more characters in said layer of material having said visually-observable characteristic. 9. A replacement indicator according to claim 1 , wherein said layer of material is a color change material that includes at least one of an antioxidant and an antiozonant. 10. A replacement indicator according to claim 9 , wherein said layer of material includes a color static material that has a higher affinity for said one or more environmental agents than said color change material. 11. A method of manufacturing an assembly, said method comprising: providing a replacement indicator according to claim 1 ; providing an elastomeric spring member; and, attaching said replacement indicator to said elastomeric spring member. 12. A method according to claim 11 , wherein said replacement indicator includes a removable protective layer; and, said method further comprises one of: removing said removable protective layer prior to attaching said replacement indicator to said elastomeric spring member; and, removing said removable protective layer after attaching said replacement indicator to said elastomeric spring member. 13. A method of monitoring a characteristic of an elastomeric spring member, said method comprising: providing an elastomeric spring member to be monitored; providing a replacement indicator according to claim 1 ; and, correlating one or more visually-observable characteristics of said layer of material with one or more material characteristics of said elastomeric spring member, such that a material characteristic of said elastomeric spring member can be identified by said change in said visually-observable characteristic of said replacement indicator upon exposure of said replacement indicator and said elastomeric spring member to a common, predetermined level of said one or more environmental agents. 14. A replacement indicator according to claim 1 , wherein said layer of material is a first layer of material having a first visually-observable characteristic, and said replacement indicator further comprises a second layer of material disposed laterally adjacent said first layer of material, said second layer of material including a first side securable along the associated exterior surface of the associated elastomeric spring member and a second side facing opposite said first side such that said second side is exposable to one or more environmental agents to which the associated elastomeric spring member would be simultaneously exposed in an installed condition of said replacement indicator, said second layer of material having a second visually-observable characteristic that changes from said first color to said second color upon exposure to a second predetermined level of said one or more environmental agents. 15. A replacement indicator according to claim 14 further comprising a backing member including a first side securable along the associated exterior surface of the associated elastomeric spring member and a second side facing opposite said first side with said first and second layers of material secured to said backing member along said second side thereof. 16. An assembly comprising: a gas spring assembly including: a first end member; a second end member spaced from said first end member such that a longitudinal axis extends therebetween; and, a flexible wall extending circumferentially about said longitudinal axis and longitudinally between opposing first and second ends, said flexible wall including an interior surface and an exterior surface with said first end member secured across said first end of said flexible wall and said second end member secured across said second end of said flexible wall such that a spring chamber is at least partially formed by said interior surface of said flexible wall between said first and second end members; and, a replacement indicator operatively associated with said as spring assembly, said replacement indicator including: a first layer of material including a first side oriented toward said gas spring assembly and a second side facing opposite said first side with said second side being exposed to one or more environmental agents, said first layer of material having a first visually-observable characteristic that changes from one color to another color upon exposure to a first predetermined level of said one or more environmental agents such that said change in said visually-observable characteristic can be correlated to a first level of exposure of said material characteristic of said flexible wall to said one or more environmental agents; and, a second layer of material disposed laterally adjacent said first layer of material, said second layer of material including a first side oriented toward said gas spring assembly and a second side facing opposite said first side with said second side being exposed to said one or more environmental agents, said second layer of material having a second visually-observable characteristic that changes from one color to another color upon exposure to a second predetermined level of said one or more environmental agents
characterised by the assembling method or by the mounting arrangement, e.g. mounting of the membrane (F16F9/0409, F16F9/0445 take precedence) · CPC title
wherein the fluid is a gas · CPC title
Maintenance · CPC title
on pneumatic springs · CPC title
Pneumatic spring · CPC title
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