Exhaust gas after-treatment system and method for the exhaust gas after-treatment

Patent metadata

Field	Value
Publication number	US-9587539-B2
Application number	US-201514678640-A
Country	US
Kind code	B2
Filing date	Apr 3, 2015
Priority date	Apr 8, 2014
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

An exhaust gas after-treatment system for an internal combustion engine, with a particle filter arranged downstream of an internal combustion engine for filtering soot out of the exhaust gas, and with an oxidation catalytic converter arranged upstream of the particle filter and downstream of the internal combustion engine for the oxidation of SO 2 into SO 3 . The SO 3 and/or precipitated H2SO 4 serves for the oxidation of soot in the particle filter and thus for the regeneration of the particle filter.

First claim

What is claimed is:

1. An exhaust gas after-treatment system arranged in an exhaust gas flow of an internal combustion engine, comprising:
a particle filter arranged downstream of the internal combustion engine configured to filter soot out of the exhaust gas; and
an oxidation catalytic converter arranged upstream of the particle filter and downstream of the internal combustion engine configured to oxidize SO 2 into SO 3 ,
wherein at least one of the SO 3 and precipitated H 2 SO 4 serves for oxidation of soot in the particle filter for regeneration of the particle filter based at least in part on a temperature of the exhaust gas.

2. The exhaust gas after-treatment system according to claim 1 ,
wherein the oxidation catalytic converter comprises at least one of vanadium, sodium, iron, cerium, cesium, and oxides of these elements as active component for oxidation of SO 2 into SO 3 ,
wherein the oxidation catalytic converter utilizes at least one of titanium oxide and silicon oxide as a base material.

3. The exhaust gas after-treatment system according to claim 1 , wherein the oxidation catalytic converter active component comprises at least 5% vanadium.

4. The exhaust gas after-treatment system according to claim 1 , wherein a mass ratio between SO 3 and soot is at least 7:1 downstream of the oxidation catalytic converter, proximate to the particle filter.

5. The exhaust gas after-treatment system according to claim 1 , further comprising:
a turbine for an exhaust gas turbocharger,
wherein the oxidation catalytic converter is arranged upstream of the turbine of the exhaust gas turbocharger and the particle filter is positioned downstream of the turbine.

6. The exhaust gas after-treatment system according to claim 1 , further comprising:
an oxidation catalytic converter for oxidation of NO into NO 2 arranged upstream of the particle filter and downstream of the internal combustion engine,
wherein the NO 2 serves for the oxidation of soot in the particle filter and the regeneration of the particle filter.

7. The exhaust gas after-treatment system according to claim 6 , wherein the oxidation catalytic converter for oxidation of NO into NO 2 is connected parallel to the oxidation catalytic converter for oxidation of SO 2 into SO 3 .

8. The exhaust gas after-treatment system according to claim 7 , further comprising:
shut-off valves configured to shut off at least one of the oxidation catalytic converter for the oxidation of NO into NO 2 and the oxidation catalytic converter for oxidation of SO 2 into SO 3 from the exhaust gas flow based at least in part on the Sulphur content of a fuel provided to the internal combustion engine.

9. The exhaust gas after-treatment system according to claim 2 ,
wherein the base material is stabilized by tungsten oxide.

10. The exhaust gas after-treatment system according to claim 3 , wherein the oxidation catalytic converter active component comprises at least 9% vanadium.

11. The exhaust gas after-treatment system according to any one of the claim 4 , wherein the mass ratio between SO 3 and soot is at least 16:1.

12. A method for exhaust gas after-treatment of exhaust gas leaving an internal combustion engine, comprising:
providing the exhaust gas to an oxidation catalytic converter for oxidation of SO 2 into SO 3 ;
providing the exhaust gas, after oxidation by the oxidation catalytic converter, to a particle filter configured to filter soot out of the exhaust gas; and
regenerating the particle filter by oxidation of soot in the particle filter with at least one of the SO 3 formed in the oxidation catalytic converter and precipitated H 2 SO 4 based at least in part on a temperature of the exhaust gas.

13. The method for exhaust gas after-treatment according to claim 12 ,
wherein during operation of the internal combustion engine with a fuel having a high Sulphur content, shutting off the exhaust gas flow by shut-off valves to an oxidation catalytic converter for oxidation of NO into NO 2 so the exhaust gas flow is provided to the oxidation catalytic converter for the oxidation of SO 2 into SO 3 , and
wherein during operation of the internal combustion engine with a fuel that has a relatively low Sulphur content, shutting off the exhaust gas flow by shut-off valves to the oxidation catalytic converter for the oxidation of SO 2 into SO 3 so the exhaust gas flow is provided to the oxidation catalytic converter for the oxidation of NO into NO 2 .

14. The method for exhaust gas after-treatment according to claim 13 , wherein the high Sulphur content is a Sulphur content of the fuel above 1,000 ppm.

Assignees

• Döring Andreas
• Man Diesel & Turbo Se

Inventors

• Döring Andreas

Classifications

• F01N13/011

  having two or more purifying devices arranged in parallel · CPC title

• B01D2255/2065

  Cerium · CPC title

• B01D53/94

  by catalytic processes · CPC title

• B01D2255/2022

  Potassium · CPC title

• B01D53/96

  Regeneration, reactivation or recycling of reactants · CPC title