Method for removing ink from paper

Patent metadata

Field	Value
Publication number	US-9587350-B2
Application number	US-201113578680-A
Country	US
Kind code	B2
Filing date	Feb 11, 2011
Priority date	Feb 12, 2010
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

A method for removing ink from printed paper comprising: (a) pulping printed paper at least 25 wt % of which is old newsprint at a consistency of at least about 3% to obtain a pulp slurry; (b) treating the pulp slurry with an ink removing system, which system comprises: (i) a combination of lipase and at least one second enzyme chosen from amylase, xylanase or cellulase, and (ii) a non-ionic surfactant, in amounts effective to release ink from said pulp slurry, wherein the lipase is present in an amount of at least about 0.001 wt % based on the dry content of the pulp slurry and the ratio of the at least one second enzyme:lipase is at least about 1.2:1; and (c) separating the released ink from the pulp slurry, wherein the treating step is carried out prior to a deinking flotation stage.

First claim

What is claimed is:

1. A method for removing ink from printed paper comprising the steps of:
(a) pulping printed paper at least 25 wt % of which is old newsprint at a consistency of at least about 3% to obtain a pulp slurry;
(b) treating the pulp slurry with an ink removing system, which system comprises:
(i) an enzyme combination consisting of lipase and xylanase, and
(ii) a non-ionic surfactant, in amounts effective to release ink from said pulp slurry,
wherein the lipase is present in an amount of at least about 0.001 wt % based on the dry content of the pulp slurry and the ratio of xylanase: lipase is at least about 1.2:1, wherein the total amount of enzyme is in the range from 0.0022 to less than 0.025 wt % based on the dry content of the pulp slurry; and

(c) separating the released ink from the pulp slurry in a deinking flotation stage to provide a deinked pulp slurry, wherein the treating step is carried out prior to the deinking flotation stage, and wherein the ink removal efficiency is at least about 50%.

2. A method according to claim 1 , wherein the ratio of xylanase: lipase is at least about 1.5:1.

3. A method according to claim 2 , wherein the ratio of xylanase: lipase is in the range of about 1.5:1 to about 2.5:1.

4. A method according to claim 2 , wherein the non-ionic surfactant is chosen from fatty alcohol ethyoxylates (FAEO), propoxylates (FAPO) and combination thereof (FAEPO).

5. A method according to claim 4 , wherein the ratio of (i): ii) is in the range of about 1:2 to about 1:4.

6. A method according to claim 1 , wherein the ink removing system further comprises (iii) a soap.

7. A method according to claim 6 , wherein the ink removing system further comprises (iv) an alkaline reagent.

8. A method according to claim 7 , wherein the printed paper comprises ONP in an amount in the range of from about 40 wt % to about 95 wt %.

9. A method according to claim 7 , wherein the soap is a fatty acid soap.

10. A method according to claim 7 , wherein the alkaline reagent is sodium silicate.

11. A method according to claim 7 , wherein the combination of enzymes (i) is a combination of lipase and xylanase; the non-ionic surfactant (ii) is chosen from fatty alcohol ethoxylates (FAEO), propoxylates (FAPO) and combinations thereof (FAEPO): the soap (iii) is a tallow fatty acid soap; and the alkaline reagent (iv) is sodium silicate.

12. A method according to claim 11 , wherein the ratio of (i): (ii) is in the range of about 1:2 to 1:4.

13. A method according to claim 12 , wherein (i) and (ii) are premixed to form an enzyme composition (v) and then adding (v) to the pulp slurry as a component of the ink removing system.

14. A method according to claim 13 , wherein the enzyme composition (v) is added to the pulp slurry in an amount in the range of about 0.04 to about 0.5 wt %, the soap (iii) is added to the pulp slurry in an amount in the range of about 0.1 to about 1 wt %, and the alkaline reagent (iv) is added to the pulp slurry in an amount in the range of about 0.5 to about 2 wt %, all based on the solid content of the slurry.

15. A method according to claim 13 , wherein the pH of the slurry is maintained in the range of about 6 to about 11.

16. A method according to claim 13 , wherein the slurry is substantially free of sodium sulfite.

17. A method according to claim 13 , wherein the slurry is substantially free of sodium hydroxide or, if added to the slurry, the sodium hydroxide is added in an amount less than 0.15 wt %, based on the weight of the slurry.

18. A method according to claim 13 , wherein the slurry is substantially free of hydrogen peroxide.

19. A method according to claim 13 , wherein the ink removal efficiency is at least 70%.

20. A method for removing ink from printed paper comprising the steps of:
(a) pulping printed paper at least 25 wt % of which is old newsprint at a consistency of at least about 3% to obtain a pulp slurry;
(b) treating the pulp slurry with an ink removing system, which system comprises:
(i) an enzyme combination consisting of lipase and xylanase, wherein the lipase is present in an amount of at least about 0.001 wt % based on the dry content of the pulp slurry, the ratio of xylanase to lipase is at least about 1.2:1, and the total amount of enzyme is in the range from 0.0022 to less than 0.025wt % based on the dry content of the pulp slurry; and
(ii) a nonionic surfactant, in amounts effective to release ink from said pulp slurry, and

(c) separating the released ink from the pulp slurry in a deinking flotation stage to provide a deinked pulp slurry, wherein the treating step is carried out prior to the deinking flotation stage, and wherein the ink removal efficiency is at least about 50%; and
wherein the pH of the deinking flotation stage is between 7.3 and 7.6.

Assignees

• Haynes Robert Daniel
• Auger Scott Barton
• Kemira Oyj

Inventors

• Haynes Robert Daniel
• Auger Scott Barton

Classifications

• D21C5/027 Primary

  Chemicals therefor · CPC title

• D21C5/005

  Treatment of cellulose-containing material with microorganisms or enzymes · CPC title

• D21C5/025

  De-inking · CPC title

• Y02W30/648

  Cross-Sectional Technologies · mapped topic

• Y02W30/64

  Paper recycling · CPC title