Self-lubricating polymer composition and method of lubricating an article

Patent metadata

Field	Value
Publication number	US-9587201-B2
Application number	US-201314646140-A
Country	US
Kind code	B2
Filing date	Nov 15, 2013
Priority date	Nov 21, 2012
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

A self-lubricating polymer composition is provided. The self-lubricating composition comprises a polymer matrix formed from a homopolymer or copolymer selected from the group consisting of a polyamide, a polyester, a polycarbonate, and combinations thereof, and a particulate siloxane slip agent substantially homogeneously distributed in the polymer. Also provided are self-lubricating articles, such as electrical wire and optical cable, coated with the self-lubricating polymer composition.

First claim

What is claimed is:

1. A self-lubricating polymer composition, the composition comprising:
a polymer matrix formed from a nylon; and
a particulate siloxane slip agent substantially homogeneously distributed in the polymer,
wherein the siloxane concentration is between about 0.05 percent by weight and 1 percent by weight based on the total weight of the polymer and siloxane, the average particle size of the particulate siloxane is from about 0.5 μm to about 25 μm.

2. The composition of claim 1 , wherein the nylon is selected from nylon 6 and nylon 66.

3. The composition of claim 1 , wherein the siloxane is a silsesquioxane of the formula RSiO 3/2 , wherein R is C 1-10 hydrocarbyl.

4. The composition of claim 1 , wherein the siloxane is methylsilsesquioxane.

5. The composition of claim 1 wherein a plurality of siloxane particles are characterized as having an average sphericity of from about 0.9 to 1.0.

6. The composition of claim 1 wherein the three dimensional conformation of the siloxane particles is generally spherical, substantially spherical, or uniformly spherical.

7. The composition of claim 1 , wherein the siloxane concentration is from about 0.1 percent by weight to about 0.5 percent by weight based on the combined weight of the polymer and the siloxane.

8. The composition of claim 1 , wherein the average particle size of the particulate siloxane is from about 1 μm to about 15 μm.

9. The composition of claim 1 , wherein the nylon concentration is at least 90 percent by weight.

10. The composition of claim 1 , wherein the particulate material does not migrate within the formed polymer matrix.

11. The composition of claim 1 , wherein the particulate material does not react with the polymer.

12. The composition of claim 1 wherein a cable formed by disposing the composition of claim 1 about an electrical conductor or optical cable has the characteristic that an amount of force required to pull said cable through a conduit arrangement made from 1 inch galvanized steel electrical metallic tubing including about 28.5 feet of straight conduit and four 90 degree bends and having a 5.5 foot long final straight section is no more than 25% greater than the force required to pull a similar comparative cable of the same size and type differing only with respect to the particulate slip agent, wherein the comparative cable comprises from 1 wt. % to 3 wt. % of a particulate polytetrafluorethylene slip agent substantially homogeneously distributed in the polymer and no particulate siloxane slip agent.

13. The composition of claim 1 wherein a cable formed by disposing the composition of claim 1 about an electrical conductor or optical cable has the characteristic that an amount of force required to pull said cable through a conduit arrangement made from 1 inch galvanized steel electrical metallic tubing including about 28.5 feet of straight conduit and four 90 degree bends and having a 5.5 foot long final straight section is at least 25% less than the force required to pull a non-lubricated cable of the same cable type and size through the conduit arrangement.

14. A self-lubricating cable comprising:
(i) an electrical conductor or an optical cable; and
(ii) a coating comprising the self-lubricating polymer composition of claim 1 disposed peripherally about the electrical conductor or optical cable.

15. A method of lubricating an article, the method comprising:
(a) forming a lubrication mixture comprising the self-lubricating polymer composition of claim 1 ; and
(b) coating the article with the lubrication mixture.

16. The method of claim 15 further comprising at least one insulator layer disposed between the article and the coating.

17. The method of claim 15 , wherein the article is an electrical conductor or an optical cable.

18. The method of claim 15 wherein the lubrication mixture is extruded onto an exterior surface of the article.

Assignees

• Polyone Corp

Inventors

• Tomsheck Chad R
• Paisner Martin J
• Dawsey Timothy R

Classifications

• C08L77/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• G02B6/4438

  for facilitating insertion by fluid drag in ducts or capillaries · CPC title

• C08L67/00 Primary

  Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain (of polyester-amides C08L77/12; of polyester-imides C08L79/08); Compositions of derivatives of such polymers · CPC title

• C08L83/04

  Polysiloxanes · CPC title