Drilling fluid containing a surfactant having a high boiling point and a long chain tail group

Patent metadata

Field	Value
Publication number	US-9587162-B2
Application number	US-201314034539-A
Country	US
Kind code	B2
Filing date	Sep 23, 2013
Priority date	Feb 21, 2012
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

According to an embodiment, an invert emulsion drilling fluid comprises: an external phase, wherein the external phase of the drilling fluid comprises a hydrocarbon liquid; an internal phase, wherein the internal phase of the drilling fluid comprises water; and a surfactant, wherein the surfactant: (A) comprises a hydrophobic tail group having a carbon chain length greater than or equal to 16; (B) has a boiling point greater than or equal to 400° F. (204.4° C.); and (C) is in at least a sufficient concentration such that the surfactant spontaneously forms reverse-micelles. According to another embodiment, a method of using the invert emulsion drilling fluid comprises: introducing the drilling fluid into a well.

First claim

What is claimed is:

1. An invert emulsion drilling fluid comprising:
an external phase, wherein the external phase of the drilling fluid comprises a hydrocarbon liquid;
an internal phase, wherein the internal phase of the drilling fluid comprises water, and wherein the internal phase is in a concentration of about 2% to about 20% by volume of the external phase;
a surfactant, wherein the surfactant:
(A) comprises a hydrophobic tail group having a carbon chain length greater than or equal to 16, wherein the tail group is branched;
(B) has a boiling point in the range of about 450° F. to about 700° F.; and
(C) is in a concentration in the range of about 12 to about 25 pounds per barrel (about 39 to about 97 kilograms per cubic meter) of the drilling fluid,
wherein the amount of branching of the tail group is selected such that the surfactant has a boiling point in the range of about 450° F. to about 700° F.;

an emulsifier selected from the group consisting of calcium oleate, a linear octadecenamide, phosphatide, and combinations thereof; and
a viscosifier selected from a group consisting of an aluminum-silicate organophilic clay, a magnesium-silicate organophilic clay, dimer and trimmer fatty acids, stearic acid, and combinations thereof.

2. The drilling fluid according to claim 1 , wherein the hydrocarbon liquid is selected from the group consisting of: a fractional distillate of crude oil; a fatty derivative of an acid, an ester, an ether, an alcohol, an amine, an amide, or an imide; a saturated hydrocarbon; an unsaturated hydrocarbon; a branched hydrocarbon; a cyclic hydrocarbon; and any combination thereof.

3. The drilling fluid according to claim 1 , wherein the water is selected from the group consisting of freshwater, seawater, brine, and any combination thereof in any proportion.

4. The drilling fluid according to claim 1 , wherein the hydrophobic tail group has a carbon chain length in the range of C18 to C24.

5. The drilling fluid according to claim 1 , wherein the surfactant further comprises a hydrophilic head group, and wherein the hydrophilic head group comprises an amide, an imide, an ether, a polyethylene oxide, a quaternary amine, a phenol, or an allyl carboxylic acid functional group.

6. The drilling fluid according to claim 1 , wherein the drilling fluid has an electrical stability of greater than 300 volts.

7. The drilling fluid according to claim 1 , wherein the drilling fluid has a plastic viscosity in the range from about 12 to about 50 cP.

8. The drilling fluid according to claim 1 , wherein the surfactant is in a sufficient concentration such that the drilling fluid has an API fluid loss of less than 10 mL/30 min at a temperature of 302° F. (150° C.) and a pressure differential of 500 psi (3.4 MPa).

9. The drilling fluid according to claim 1 , wherein the drilling fluid is stable after static aging for 16 hours at a temperature of at least 475° F. (246° C.).

10. The drilling fluid according to claim 1 , wherein the drilling fluid has a sag factor less than or equal to 0.53 after static aging for 16 hours at a temperature of at least 475° F. (246° C.) and a pressure of 500 psi (3.4 MPa).

11. The drilling fluid according to claim 1 , wherein the surfactant is in a sufficient concentration such that the drilling fluid is stable and has a sag factor less than or equal to 0.53 after static aging for 16 hours at a temperature of at least 475° F. (246° C.) and a pressure of 500 psi (3.4 MPa).

12. The drilling fluid according to claim 1 , wherein the drilling fluid is used in a well.

13. The drilling fluid according to claim 12 , wherein the well is an oil, gas, or water production well, a geothermal well, or an injection well.

14. The drilling fluid according to claim 12 , wherein the well has a bottomhole temperature in the range of about 400 to about 600° F. (about 204.4 to about 315.6° C).

15. An invert emulsion drilling fluid comprising:
an external phase, wherein the external phase of the drilling fluid comprises a hydrocarbon liquid;
an internal phase, wherein the internal phase of the drilling fluid comprises water, and wherein the internal phase is in a concentration of about 2% to about 20% by volume of the external phase;
a surfactant, wherein the surfactant:
(A) comprises a hydrophobic tail group having a carbon chain length greater than or equal to 16;
(B) has a boiling point in the range of about 450° F. to about 700° F.;
(C) is in a concentration in the range of about 15 to about 30 pounds per barrel (about 58 to about 116 kilograms per cubic meter) of the drilling fluid; and
(D) comprises a hydrophilic head group, wherein the hydrophilic head group comprises an amide, an imide, an ether, a polyethylene oxide, a quaternary amine, a phenol, or an allyl carboxylic acid functional group,
wherein the hydrophilic head group, the hydrophobic tail group, or both the hydrophilic head and hydrophobic tail of the surfactant is branched, and wherein the amount of branching, the chain length, or both the amount of branching and the chain length are selected such that the surfactant has a boiling point in the range of about 450° F. to about 700° F.;
an emulsifier selected from the group consisting of calcium oleate, a linear octadecenamide, phosphatide, and combinations thereof; a thinner selected from a group consisting of sulfo fatty acid-sodium salt, sulfonic acid salt, fatty alcohols, and combination thereof; and
a viscosifier selected from a group consisting of an aluminum-silicate organophilic clay, a magnesium-silicate organophilic clay, dimer and trimmer fatty acids, stearic acid, and combinations thereof.

16. The drilling fluid according to claim 15 , wherein the hydrophobic tail group has a carbon chain length in the range of C18 to C24.

17. The drilling fluid according to claim 1 , wherein the drilling fluid further comprises:
a thinner selected from a group consisting of sulfo fatty acid-sodium salt, sulfonic acid salt, fatty alcohols, and combination thereof;
a weighting agent selected from a group consisting of barite, hematite, manganese tetroxide, calcium carbonate, and combinations thereof; and
a fluid loss additive selected from the group consisting of a modified lignitic compound, methylestryrene-co-acrylate; a substituted styrene copolymer, and combinations thereof.

18. The method according to claim 1 , wherein the surfactant comprises 9-octadecenamide, N-(2-hydroxypropyl)-.

Assignees

• Halliburton Energy Services Inc

Inventors

• Fisk Jr James V

Classifications

• C09K8/36 Primary

  Water-in-oil emulsions · CPC title

• B01F17/0021

  Operations & Transport · mapped topic

• B01F17/0042

  Operations & Transport · mapped topic

• C09K23/22

  Amides or hydrazides · CPC title