Emulsion breakers including polyester functionalities

Patent metadata

Field	Value
Publication number	US-9587155-B2
Application number	US-201313894563-A
Country	US
Kind code	B2
Filing date	May 15, 2013
Priority date	May 16, 2012
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

An emulsion breaker composition, a method of making the emulsion breaker, and method of breaking an emulsion are disclosed. In one method, an emulsion is contacted with an effective amount of an emulsion breaker composition. The emulsion breaker is a linear or branched polymer having at least one branch, wherein each branch has a first polymer block having a backbone including a plurality of ester groups and a second polymer block including an alkoxylate, and wherein at least two of the ester groups are connected by a —CR1R2 group. The emulsion breakers are preferably formed by reacting a polyol with a cyclic ester monomer in the presence of a first catalyst to form an intermediate polymer having a plurality of branches, wherein each branch has a backbone including a plurality of ester groups, and then reacting the intermediate polymer with at least one alkylene oxide species in the presence of a second catalyst to form an alkoxylate block on each branch.

First claim

What is claimed is:

1. A method of breaking an emulsion, comprising:
introducing an effective amount of an emulsion breaker composition into contact with the emulsion, wherein the emulsion breaker is a branched polymer having two or more branches, wherein each branch has a first polymer block having a backbone including a plurality of ester groups and a second polymer block including two alkoxylate sub-blocks, wherein the two alkoxylate sub-blocks include a first sub-block of propylene oxide and a second sub-block that is a mixed oxide of propylene oxide and ethylene oxide, and wherein at least two of the ester groups are connected via a —CR 1 R 2 group, wherein R 1 and R 2 are independently selected from hydrogen or C 1 to C 16 alkyl;
wherein each branch is attached to a polyol and the polyol is selected from trimethylolpropane, glycerol, polyglycerol, pentaerythritol, sorbitol, sucrose, castor oil, hydroxylated soybean oil, and a combination thereof.

2. The method of claim 1 , wherein the polyol is trimethylolpropane, the first polymer block is derived from a monomer and the monomer is lactide, glycolide or a combination thereof, and wherein the trimethylolpropane and monomer are provided to the reaction at a trimethylolpropane:monomer weight ratio ranging from 4 to 0.01.

3. The method of claim 2 , wherein the monomer is lactide selected from D-lactide, L-lactide, meso stereoisomers of lactide, and a combination thereof.

4. The method of claim 2 , wherein the monomer is a racemic mixture of lactides.

5. The method of claim 1 , wherein the second sub-block is attached directly to the first polymer block.

6. The method of claim 1 , wherein the second sub-block further includes butylene oxide.

7. The method of claim 1 , wherein the polyol is castor oil.

8. The method of claim 1 , wherein the first block is attached to the polyol and the second block is attached to the first block.

9. The method of claim 1 , wherein the second block is attached to the polyol and the first block is attached to the second block.

10. A method of breaking an emulsion, comprising
introducing an effective amount of an emulsion breaker composition into contact with the emulsion, wherein the emulsion breaker is formed by (i) reacting a polyol with a monomer selected from lactide, glycolide, and combinations thereof in the presence of a first catalyst to polymerize the monomer and form an intermediate polymer having a plurality of branches, wherein each branch has a backbone including a plurality of ester groups; and then (ii) reacting the intermediate polymer with at least one alkylene oxide species in the presence of a second catalyst to form two alkoxylate sub-blocks on each branch, wherein the two alkoxylate sub-blocks include a first sub-block of propylene oxide and a second sub-block that is a mixed oxide of propylene oxide and ethylene oxide, and wherein the polyol is selected from trimethylolpropane, glycerol, polyglycerol, pentaerythritol, sorbitol, sucrose, castor oil, hydroxylated soybean oil, and a combination thereof.

11. The method of claim 10 , wherein the monomer is lactide selected from D-lactide, L-lactide, meso stereoisomers of lactide, and a combination thereof.

12. The method of claim 10 , wherein the first catalyst is stannous octoate and the second catalyst is a double metal cyanide catalyst.

13. The method of claim 12 , wherein the polyol is selected from trimethylolpropane, glycerol, polyglycerol, pentaerythritol, sorbitol, sucrose, castor oil, hydroxylated soybean oil, and a combination thereof.

14. The method of claim 10 , wherein the polyol is trimethylolpropane, and wherein the trimethylolpropane and monomer are provided to the reaction at a trimethylolpropane:monomer weight ratio ranging from 4 to 0.01.

15. The method of claim 14 , wherein the monomer is lactide selected from D-lactide, L-lactide, meso stereoisomers of lactide, and a combination thereof.

16. The method of claim 14 , wherein the monomer is a racemic mixture of lactides.

17. The method of claim 14 , wherein the first catalyst is stannous octoate and the second catalyst is a double metal cyanide catalyst.

18. The method of claim 10 , wherein the second sub-block is attached directly to the first polymer block.

19. The method of claim 10 , wherein the polyol is castor oil.

Assignees

• Ecolab Usa Inc

Inventors

• Qu Liangwei
• Vijn Jan Pieter
• Bodnar Scot
• Lizarazo Carlos

Classifications

• C09K8/00 Primary

  Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations · CPC title

• C10G33/04 Primary

  with chemical means · CPC title