Formaldehyde-free protein-containing binder compositions

Patent metadata

Field	Value
Publication number	US-9587103-B2
Application number	US-201414168458-A
Country	US
Kind code	B2
Filing date	Jan 30, 2014
Priority date	Feb 1, 2010
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

One-part binder compositions are described that may include a protein and a crosslinking combination. The crosslinking combination may include at least a first crosslinking compound and a second crosslinking compound. The first and second crosslinking compounds are individually crosslinkable with each other and with the protein. Examples of the protein include soy protein. Fiber products and methods of making the fiber products are also described. The fiber products may include organic fibers, inorganic fibers, or both, in a cured thermoset binder based on solutions of the one-part binder compositions.

First claim

What is claimed is:

1. A one-part binder composition comprising:
a protein dispersed in a crosslinking solution, wherein the crosslinking solution is a solution that at least includes:
a first crosslinking compound and a second crosslinking compound, wherein:
the first and second crosslinking compounds are individually crosslinkable with each other and with the protein, and
the one-part binder composition does not include an emulsion polymer.

2. The one-part binder composition of claim 1 , wherein the first crosslinking compound comprises a polymer compound, and the second crosslinking compound comprises a crosslinking agent.

3. The one-part binder composition of claim 2 , wherein the polymer compound comprises a carboxyl-containing polycarboxy polymer and the crosslinking agent comprises at least one hydroxyl group.

4. The one-part binder composition of claim 2 , wherein the polymer compound comprises a hydroxyl-containing polyhydroxy polymer and the crosslinking agent comprises at least one carboxyl group.

5. The one-part binder composition of claim 2 , wherein the polymer compound comprises a solution polymer.

6. A fiber product comprising:
inorganic or organic fibers and a cured thermoset binder prepared from a one-part binder solution comprising an aqueous mixture of:
a protein; and
an aqueous solution comprising at least a first crosslinking compound comprising a solution polymer compound of styrene and maleic anhydride and a second crosslinking compound comprising a crosslinking agent of a polyol, wherein the first and second crosslinking compounds are individually crosslinkable with each other and with the protein, and wherein the aqueous solution does not include an emulsion of the first crosslinking compound or the second crosslinking compound.

7. The fiber product of claim 6 , wherein the inorganic or organic fibers comprise glass fibers.

8. The fiber product of claim 6 , wherein the protein comprises soy flour.

9. The fiber product of claim 6 , wherein the fiber product is selected from the group consisting of an insulation batt, a woven fiberglass mat, a non-woven fiberglass mat, and a spunbond product.

10. The fiber product of claim 6 , wherein the cured binder has a white or off-white color.

11. The fiber product of claim 6 , wherein cured binder further comprises a dye or pigment that gives the fiber product a predetermined color.

12. A method of making a fiber product, the method comprising:
providing fibers comprising organic fibers or inorganic fibers;
applying a one-part binder solution to the fibers, wherein the one-part binder solution comprises an aqueous mixture of:
a protein; and
an aqueous solution comprising at least a first crosslinking compound comprising a solution polymer compound of styrene and maleic anhydride and a second crosslinking compound comprising a crosslinking agent of a polyol, wherein the first and second crosslinking compounds are individually crosslinkable with each other and with the protein, and wherein the aqueous solution does not include an emulsion of the first crosslinking compound or the second crosslinking compound; and
reusing an unused portion of the one-part binder solution in a subsequent application of the one-part binder solution to the same fibers or a different group of fibers.

13. The method of claim 12 , wherein the one-part binder solution has a shelf life of at least one month.

14. The method of claim 12 , wherein the one-part binder solution has a viscosity of about 1 cps to about 1000 cps.

15. The method of claim 12 , wherein the protein comprises soy flour.

16. The method of claim 12 , wherein the step of applying the one-part binder solution to the fiber comprises curtain coating or spray coating the binder solution on the fibers.

17. The method of claim 12 , wherein the one-part binder solution further comprises a dye or pigment to give the fiber product a predetermined color.

18. The one-part binder composition of claim 2 , wherein the crosslinking agent comprises a polyol, an alkanol amine, or a polyamine.

19. The one-part binder composition of claim 2 , wherein the protein comprises soy protein.

20. The one-part binder composition of claim 19 , wherein the soy protein comprises soy flour, soy protein concentrate, soy protein isolate, or soy polymer.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Shooshtari Kiarash Alavi
• Asrar Jawed

Classifications

• C08L89/00

  Compositions of proteins; Compositions of derivatives thereof (foodstuff preparations A23J3/00) · CPC title

• Y10T442/20

  Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer · CPC title

• C08J5/24

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title

• C08L2666/02

  Organic macromolecular compounds, natural resins, waxes or and bituminous materials · CPC title

• C09J133/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title