Acrylic copolymer for use in highly filled composites

Patent metadata

Field	Value
Publication number	US-9587100-B2
Application number	US-201314138219-A
Country	US
Kind code	B2
Filing date	Dec 23, 2013
Priority date	Oct 30, 2007
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

The invention relates to an acrylic copolymer additive useful as a process aid in highly filled polyvinyl chloride (PVC) and chlorinated polyvinyl chloride (CPVC) composites. The acrylic additive is especially useful in highly filled PVC flooring tiles, rolled flooring, pipe and siding. The acrylic copolymer additive contains from 50 to 79 weight percent of methyl methacrylate monomer units, and has a Tg of less than 90° C.

First claim

What is claimed is:

1. Highly filled flooring comprising composite material comprising a blend of:
a) from 70 to 95 weight percent of one or more fillers; at least one filler selected from the group consisting of cellulosic fibers, calcium carbonate, rosin, limestone, aluminum trihydrate, silica and quartz;
b) from 1 to 15 weight percent of polyvinyl chloride or chlorinated polyvinyl chloride;
c) from 0.5 to 4 weight percent of an acrylic copolymer powder, wherein said acrylic copolymer comprises from 50 to 79 weight percent of methyl methacrylate units, and from 20 to 50 weight percent of at least one other acrylic monomer unit different from methyl methacrylate, wherein said copolymer has a Tg of less than 90° C., and wherein said acrylic copolymer has a weight average molecular weight of from 2 million to 10 million;
d) optionally other adjuvants;
the total adding to 100 weight percent.

2. The composite material of claim 1 , wherein said acrylic copolymer comprises from 50 to 75 weight percent of methyl methacrylate units and from 25 to 50 weight percent of the at least one other acrylic monomer unit.

3. The composite material of claim 1 , wherein said acrylic copolymer comprises from 50 to 70 weight percent of methyl methacrylate units and from 30 to 50 weight percent of the at least one other acrylic monomer unit.

4. The composite material of claim 1 , wherein said acrylic copolymer comprises methyl methacrylate and butyl acrylate.

5. The composite material of claim 1 , comprising 3.5 to 7 weight percent of polyvinyl chloride or chlorinated polyvinyl chloride.

6. The composite material of claim 1 , comprising 0.7 to 2.5 weight percent of said acrylic copolymer.

7. The composite material of claim 1 , wherein said acrylic copolymer has a Tg of less than 80° C.

8. The composite material of claim 1 , wherein said acrylic copolymer has a Tg of less than 70° C.

9. The composite material of claim 1 , wherein said acrylic copolymer has a weight average molecular weight of from 4.5 million to 5.5 million.

10. The composite material of claim 1 , wherein the highly filled flooring is in the form of tile or rolled flooring.

11. The composite material of claim 1 , wherein the adjuvant is selected from the group consisting of dyes, colorants, UV stabilizers, anti-oxidants, pigments, heat stabilizers, accent chips, PVC homopolymer, plasticizers, lubricants, calcium stearate, polyethylene, paraffin wax, impact modifiers and combinations thereof.

Assignees

• Arkema Inc

Inventors

• Lavallee Paul R
• Lavach Mark L
• Hu Rong Maria

Classifications

• C08L27/24

  halogenated · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title

• E04F15/10

  of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite {tiles}, hardboard {, or with a top layer of other materials} · CPC title

• C08F2500/01

  High molecular weight, e.g. >800,000 Da. · CPC title

• C08L27/06 Primary

  Homopolymers or copolymers of vinyl chloride · CPC title