Resin composition for solar cell encapsulant, and solar cell encapsulant and solar cell module using the same

Patent metadata

Field	Value
Publication number	US-9587094-B2
Application number	US-201414768123-A
Country	US
Kind code	B2
Filing date	Feb 13, 2014
Priority date	Feb 15, 2013
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

Provided are a resin composition for solar cell encapsulant which contains an ethylene/α-olefin and is satisfactory in terms of crosslinkability, heat resistance, transparency, and impact resistance, a solar cell encapsulant formed from the resin composition, and a solar cell module obtained using the resin composition. Provided are a resin composition for solar cell encapsulant and the likes, which comprises an ethylene/α-olefin copolymer (A) having the following properties (a1) to (a3) and organic peroxide (B):
(a1) a branch number derived from comonomer (N) and a total number of vinyl and vinylidene (V) in the ethylene/α-olefin copolymer satisfy the following relationship of expression (1): N×V≧10, wherein N and V are the number, as determined by NMR, per total of 1,000 carbon atoms contained in the main chain and side chain, (a2) an MFR (190° C., 21.18-N load) is 0.1-100 g/10 min, and (a3) a density is 0.860-0.920 g/cm 3 .

First claim

The invention claimed is:

1. A resin composition for solar cell encapsulant which comprises the following component (A) and component (B):
component (A): an ethylene/α-olefin copolymer having the following properties (a1) to (a3):
(a1) a branch number derived from comonomer (N) and a total number of vinyl and vinylidene (V) in the ethylene/α-olefin copolymer satisfy the following relationship of expression (1):
N×V≧ 10  expression (1)

wherein N and V are the number, as determined by NMR, per total of 1,000 carbon atoms contained in the main chain and side chain,

(a2) an MFR (190° C., 21.18-N load) is 0.1-100 g/10 min, and
(a3) a density is 0.860-0,920 g/cm 3 ,
component (B): organic peroxide.

2. The resin composition for solar cell encapsulant according to claim 1 , wherein the component (A) is an ethylene/α-olefin copolymer which further has the following property (a4):
(a4) a branch number derived from comonomer (N) in the ethylene/α-olefin copolymer satisfies the following relationship of expression (2):
0 <N< 54.0  expression (2)

wherein N is the number, as determined by NMR, per total of 1,000 carbon atoms contained in the main chain and side chains.

3. The resin composition for solar cell encapsulant according to claim 1 , wherein the content of component (B) is 0.2-5 parts by weight per 100 parts by weight of component (A).

4. The resin composition for solar cell encapsulant according to claim 1 , which further comprises the following component (C):
component (C): a hindered amine-type light stabilizer.

5. The resin composition for solar cell encapsulant according to claim 4 , wherein the content of component (C) is 0.01-2.5 parts by weight per 100 parts by weight of component (A).

6. The resin composition for solar cell encapsulant according to claim 1 , wherein the number of carbon atoms in the α-olefin of component (A) is 8-20.

7. The resin composition for solar cell encapsulant according to claim 1 , wherein the α-olefin of component (A) is 1-octene.

8. A solar cell encapsulant formed from the resin composition for solar cell encapsulant according to claim 1 .

9. A solar cell module using the solar cell encapsulant according to claim 8 .

10. The resin composition for solar cell encapsulant according to claim 1 , wherein the total number of vinyl and vinylidene (V) in the ethylene/α-olefin copolymer is 0.17 or larger.

11. The resin composition for solar cell encapsulant according to claim 1 , wherein the total number of vinyl and vinylidene (V) in the ethylene/α-olefin copolymer is 0.20 or larger.

12. The resin composition for solar cell encapsulant according to claim 1 , wherein the resin contained in the resin composition consists essentially of the ethylene/α-olefin copolymer of component (A).

Assignees

• Japan Polyethylene Corp

Inventors

• Maeyama Tomoaki
• Ueno Masahiro

Classifications

• C08K5/14 Primary

  Peroxides · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• H01L31/0481

  Electricity · mapped topic

• C08L23/08 Primary

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title