Barrier film for food packaging

Patent metadata

Field	Value
Publication number	US-9587093-B2
Application number	US-201313856627-A
Country	US
Kind code	B2
Filing date	Apr 4, 2013
Priority date	Nov 17, 2006
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

Barrier films are prepared from a blend of two high density polyethylene blend components and a high performance organic nucleating agent. The two high density polyethylene blend components have substantially different melt indices. Large reductions in the moisture vapor transmission rate of the film are observed in the presence of the nucleating agent when the melt indices of the two blend components have a ratio of greater than 10/1. The resulting barrier films are suitable for the preparation of packaging for dry foods such as crackers and breakfast cereals.

First claim

What is claimed is:

1. A method for improving the barrier properties of a polyethylene film, said method comprising the steps of:
converting into a film a mixture comprising;
a) a first high density polyethylene having a density of from 0.950 to 0.975 g/cc and a high melt index I 2 ;
b) a second high density polyethylene having a density of from 0.955 to 0.965 g/cc and a low melt index I 2 ′, and;
c) from 100 to 3,000 ppm of a calcium salt of 1,2-cyclohexanedicarboxylic acid;
wherein the I 2 ratio, obtained by dividing said high melt index I 2 value by said low melt index I 2 ′ value, is greater than 10/1;
wherein said film has from about 20% to about 53% improved water vapor transmission rate compared with a control film which is made using the same amounts of said first and said second high density polyethylenes but does not contain said calcium salt of 1,2-cyclohexanedicarboxylic acid, and;
wherein density is measured according to ASTM D 1505 and melt index is measured according to ASTM D 1238 when conducted at 190° C. using a 2.16 kg weight.

2. The method of claim 1 , wherein said mixture comprises; from 5 to 60 weight % of said first high density polyethylene and from 95 to 40 weight % of said second high density polyethylene, based on the total weight of said mixture.

3. The method of claim 1 , wherein said first high density polyethylene is further characterized by having a molecular weight distribution, Mw/Mn, of from 2 to 4.

4. The method of claim 1 , wherein said mixture has a density from 0.955 to 0.967 g/cc.

5. The method of claim 1 , wherein said mixture has a melt index, I 2 , of from 0.8 to 8 grams/10 minutes.

Assignees

• Nova Chemicals International Sa

Inventors

• Aubee Norman Dorien Joseph
• Chuang Tingting Yu
• Checknita Douglas
• Chisholm P Scott
• Lam Patrick
• Marshall Sarah
• Sauvageau Denny Paul
• Tikuisis Tony

Classifications

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• C08K5/0083

  Nucleating agents promoting the crystallisation of the polymer matrix · CPC title

• B29C55/28

  of blown tubular films, e.g. by inflation {(extrusion moulding of tubular films B29C48/03)} · CPC title

• C08L2201/14

  Gas barrier composition · CPC title

• B29K2023/086

  EVOH, i.e. ethylene vinyl alcohol copolymer · CPC title