Transparent thermoplastic resin composition

Patent metadata

Field	Value
Publication number	US-9587058-B2
Application number	US-201313740335-A
Country	US
Kind code	B2
Filing date	Jan 14, 2013
Priority date	Jul 28, 2010
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

A resin composition includes a phosphorus-based acrylic copolymer (A) including (a1) an acrylic monomer represented by Formula 1 and (a2) a phosphorus-based acrylic monomer represented by Formula 2 as defined in the specification. The resin composition can have flame retardancy, heat resistance, mechanical properties, and/or flowability, while maintaining properties of high transparency and scratch resistance.

First claim

That which is claimed is:

1. A transparent thermoplastic resin composition comprising a phosphorus-based acrylic copolymer resin (A) and about 0.1 parts by weight to about 40 parts by weight based on about 100 parts by weight of the phosphorus-based acrylic copolymer resin (A) of an acrylic impact modifier (C),
wherein the phosphorus-based acrylic copolymer resin (A) comprises (a1) at least one acrylic monomer represented by Formula 1 and (a2) at least one phosphorus-based acrylic monomer represented by Formula 2:

wherein R 1 is —H or —CH 3 , and
R 2 is —(CH 2 ) n —CH 3 , where n is an integer from 0 to 18; and

wherein R 1 is —H or —CH 3 ,
R 3 is

t is an integer from 0 to 10, and
R 4 and R 5 are the same or different and are each independently —O—(CH 2 ) m —CH 3 , where m is an integer from 0 to 5, provided that at least one of R 4 and R 5 is —O—CH 3 ,
wherein the phosphorus-based acrylic copolymer resin (A) has a glass transition temperature (Tg) of about 80° C. or more, and wherein the phosphorus-based acrylic copolymer resin (A) has a weight average molecular weight of about 50,000 g/mol to about 500,000 g/mol.

2. The transparent thermoplastic resin composition according to claim 1 , wherein the phosphorus-based acrylic copolymer resin (A) further comprises a phosphorus-based acrylic monomer (a3) represented by Formula 3:

wherein R 1 is —H or —CH 3 ,
R 3 is

t is an integer from 0 to 10, and

R 4 and R 5 are the same or different and are each independently —O—(CH 2 ) m —CH 3 , where m is an integer from 1 to 5.

3. The transparent thermoplastic resin composition according to claim 1 , wherein the composition further comprises an acrylic resin (B).

4. The transparent thermoplastic resin composition according to claim 3 , comprising the acrylic resin (B) in an amount of about 0.1 parts by weight to about 99 parts by weight based on about 100 parts by weight of the phosphorus-based acrylic copolymer resin (A).

5. The transparent thermoplastic resin composition according to claim 3 , comprising the acrylic resin (B) and the acrylic impact modifier (C) in an amount of about 0.1 parts by weight to about 99 parts by weight and about 0.1 to about 40 parts by weight, respectively, based on about 100 parts by weight of the phosphorus-based acrylic copolymer resin (A).

6. The transparent thermoplastic resin composition according to claim 1 , wherein the phosphorus content of the phosphorus-based acrylic copolymer resin (A) ranges from about 1.5 wt % to about 10 wt %.

7. The transparent thermoplastic resin composition according to claim 1 , wherein the phosphorus-based acrylic copolymer resin (A) has a refractive index from about 1.48 to about 1.495.

8. The transparent thermoplastic resin composition according to claim 1 , wherein the phosphorus-based acrylic monomer (a2) comprises dimethyl (methacryloyloxymethyl) phosphonate, dimethyl (acryloyloxymethyl) phosphonate, methylethyl (methacryloyloxymethyl) phosphonate, methylethyl (acryloyloxymethyl) phosphonate, dimethyl (methacryloyloxyethyl) phosphonate, or a combination thereof.

9. The transparent thermoplastic resin composition according to claim 2 , wherein the phosphorus-based acrylic monomer (a3) comprises diethyl (methacryloyloxymethyl) phosphonate, diethyl (acryloyloxymethyl) phosphonate, diethyl (methacryloyloxyethyl) phosphonate, dipropyl (methacryloyloxymethyl) phosphonate, dipropyl (methacryloyloxyethyl) phosphonate, or a combination thereof.

10. The transparent thermoplastic resin composition according to claim 3 , wherein the acrylic resin (B) comprises a polymer or a copolymer of methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, hexyl methacrylate, cyclohexyl methacrylate, phenyl methacrylate, benzyl methacrylate, phenoxy methacrylate, phenoxyethyl methacrylate, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, or a combination thereof, and wherein the acrylic resin (B) has a weight average molecular weight from about 5,000 g/mol to about 300,000 g/mol and a refractive index from about 1.480 to about 1.495.

11. The transparent thermoplastic resin composition according to claim 1 , wherein the acrylic impact modifier (C) comprises a multilayered graft copolymer obtained by polymerizing an acrylic rubber monomer including butyl (meth)acrylate, hexyl (meth)acrylate, ethylhexyl (meth)acrylate, stearyl (meth)acrylate, lauryl (meth)acrylate, or a combination thereof to provide a rubber polymer, and grafting at least one graft copolymerizable monomer including methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, butyl (meth)acrylate, styrene, alpha-styrene, C1-C10 alkyl substituted styrene, acrylonitrile, methacrylonitrile, maleic anhydride, C1-C10 N-substituted maleimide, phenyl N-substituted maleimide, or a combination thereof onto the rubber polymer, wherein the acrylic impact modifier (C) has a refractive index from about 1.480 to about 1.495.

12. The transparent thermoplastic resin composition according to claim 1 , wherein the transparent thermoplastic resin composition has a total light transmittance of about 80% or more measured on a 2.5 mm thick specimen in accordance with ASTM D1003.

13. The transparent thermoplastic resin composition according to claim 1 , wherein the transparent thermoplastic resin composition has a pencil hardness level from F to 3H measured on a 2.5 mm thick specimen in accordance with JIS K5401, or BSP width from about 180 μm to about 300 μm.

14. The transparent thermoplastic resin composition according to claim 1 , wherein the transparent thermoplastic resin composition has a Vicat Softening Temperature of about 70° C. or more measured on a 3.2 mm thick specimen in accordance with ISO R306.

15. The transparent thermoplastic resin composition according to claim 1 , wherein the transparent thermoplastic resin composition has flame retardancy of any one of V2, V1 and V0 measured on a 3.2 mm thick specimen in accordance with UL94.

16. The transparent thermoplastic resin composition according to claim 1 , further comprising flame retardant, antimicrobial agent, releasing agent, heat stabilizer, antioxidant, light stabilizer, compatibilizer, dye, inorganic additives, surfactant, nucleating agent, coupling agent, filler, plasticizer, impact modifier, blending agent, coloring agent, stabilizer, lubricant, antistatic agent, pigment, fire-proofing agent, or a combination thereof.

17. A molded article produced from the transparent thermoplastic resin composition according to claim 1 .

18. The transparent thermoplastic resin composition according to claim 1 , wherein the phosphorus-based acrylic copolymer resin (A) has a glass transition temperature (Tg) of 96° C. or more.

19. The transparent thermoplastic resin composition according to claim 18 , wherein the phosphorus-based acrylic copolymer resin (A) has a glass transition temperature (Tg) of 101° C.

Assignees

• Cheil Ind Inc
• Samsung Sdi Co Ltd

Inventors

• Kwon Kee Hae
• Chung Jin Hwa
• Lee Jin Seong
• Kim Man Suk
• Park Kwang Soo
• Koo Ja Kwan

Classifications

• C08F230/02 Primary

  containing phosphorus · CPC title

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08L51/00

  Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds (for ABS polymers C08L55/02); Compositions of derivatives of such polymers · CPC title

• C08L33/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title