Liquid deposition composition and process for forming metal therefrom
US-2015191825-A1 · Jul 9, 2015 · US
US9586909B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9586909-B2 |
| Application number | US-201514984262-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 30, 2015 |
| Priority date | Nov 28, 2013 |
| Publication date | Mar 7, 2017 |
| Grant date | Mar 7, 2017 |
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Provided is a 5,6-diaryl-2-pyrazyl triflate, its synthetic method, and a method for synthesizing an organometallic complex having a triarylpyrazine ligand from the 5,6-diaryl-2-pyrazyl triflate. The triflate is readily obtained from the corresponding 5,6-diarylpyrazin-2-ol, and the palladium-catalyzed coupling of the 5,6-diaryl-2-pyrazyl triflate with an arylboronic acid derivative leads to a high yield of a triarylpyrazine derivative having high purity. The use of the triarylpyrazine derivative in the reaction with a metal compound such as a metal chloride results in an ortho-metallated organometallic complex with high purity. The high purity of the organometallic complex contributes to the extremely high durability of a light-emitting element.
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What is claimed is: 1. A compound represented by the following formula: wherein R 1 to R 8 each independently represent any one of hydrogen, an alkyl group having 1 to 6 carbon atoms, a phenyl group, and a phenyl group having, as a substituent, an alkyl group having 1 to 6 carbon atoms. 2. The compound according to claim 1 is a compound represented by the following formula (100) 3. The compound according to claim 1 is a compound represented by the following formula (101) 4. The compound according to claim 1 is a compound represented by the following formula (102) 5. The compound according to claim 1 is a compound represented by the following formula (103) 6. The compound according to claim 1 is a compound represented by the following formula (104) 7. The compound according to claim 1 is a compound represented by the following formula (105) 8. The compound according to claim 1 is a compound represented by the following formula (106) 9. The compound according to claim 1 is a compound represented by the following formula (107) 10. The compound according to claim 1 is a compound represented by the following formula (108) 11. The compound according to claim 1 is a compound represented by the following formula (109) 12. The compound according to claim 1 is a compound represented by the following formula (110) 13. The compound according to claim 1 is a compound represented by the following formula (111)
with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms · CPC title
Oxygen or sulfur atoms · CPC title
of the platinum group, i.e. Os, Ir, Pt, Ru, Rh or Pd · CPC title
Electricity · mapped topic
Electricity · mapped topic
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