Composition having an active metal or precursor, an amine component and a non-amine containing polar additive useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst

Patent metadata

Field	Value
Publication number	US-9586199-B2
Application number	US-201514817272-A
Country	US
Kind code	B2
Filing date	Aug 4, 2015
Priority date	Jun 28, 2011
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

A composition that comprises a support material that is loaded with an active metal or metal precursor, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating therein an amine component and a non-amine containing polar additive.

First claim

That which is claimed is:

1. A method of making a composition, wherein said method comprises:
incorporating a metal-containing solution into a support material to provide a metal-incorporated support material; and incorporating both an amine component and a non-amine containing polar additive into said metal-incorporated support material to thereby provide an impregnated composition comprising said support material, said amine component, and said non-amine containing polar additive wherein the weight ratio of said non-amine containing polar additive to said amine component is in the range of upwardly to 10:1; wherein said amine component is selected from the group of compounds consisting of ether amine compounds, alkyl amine compounds, and amine oxide compounds; and wherein said amine compound has a molecular weight greater than 160 and a flash point of at least 80° C.

2. A method as recited in claim 1 , further comprising: contacting said impregnated composition under suitable hydrogen treatment conditions with hydrogen to thereby provide a hydrogen-treated composition.

3. A method as recited in claim 2 , wherein prior to said incorporating of said amine component and said non-amine containing polar additive into said metal-incorporated support material, said metal-incorporated support material is dried so as to contain a volatiles content in the range of from 3 to 20 wt. % LOI.

4. A method as recited in claim 1 , wherein said amine component is an ether amine compound.

5. A method as recited in claim 4 , wherein said ether amine compounds include those selected from the family of compounds having the following formula: R—O—(CH 2 ) n NH 2 , wherein R is an alkyl functional group comprising from 4 to 14 carbon atoms and n is an integer of ranging from 1 to 6.

6. A method as recited in claim 1 , wherein said amine oxide compounds include those selected from the family of compounds having the following formula: [R1, R2 and R3] N + O − , wherein R1 is either a hydrogen atom or an alkyl functional group, R2 is either a hydrogen atom or an alkyl functional group, and R3 is either a hydrogen atom or an alky functional group, wherein the total number of carbon atoms included in R1 and R2 and R3 is in the range of from 8 carbon atoms to 40 carbon atoms.

7. A method as recited in claim 1 , wherein said alkyl amine compounds include those selected from the group of amine compounds consisting of primary amines having from 8 to 20 carbon atoms, secondary amines having from 8 to 20 carbon atoms, and tertiary amines having from 8 to 20 carbon atoms.

8. A method as recited in claim 1 , wherein said non-amine containing polar additive is selected from those compounds having a dipole moment of at least 0.45 and which are an heterocompound but excluding heterocompounds that include an amino functional group or a sulfur atom.

9. A method as recited in claim 1 , wherein said active metal precursor is a metal compound that includes a Group 9 and Group 10 metal component selected from the group consisting of cobalt and nickel, and wherein said Group 9 and Group 10 metal component is present in said composition in an amount in the range of from 5 wt. % to 50 wt. %.

10. A method as recited in claim 9 , wherein said support material that is loaded with said active metal precursor, said amine component, and said non-amine containing polar additive is treated with hydrogen.

11. A method as recited in claim 10 , wherein said support material that is loaded with said active metal precursor, said amine component, and said non-amine containing polar additive treated with hydrogen is treated with a sulfur compound.

12. A method as recited in claim 1 , wherein said support material is loaded with an active metal precursor, an amine component, and a non-amine containing polar additive in the substantial absence of a hydrocarbon oil.

13. A method as recited in claim 1 , wherein said amine component is a mixture of two ether amines of 3-(octyloxy)propylamine and 3-(decyloxy)propylamine.

14. A method as recited in claim 7 , wherein said alkyl amine is oleylamine.

15. A method as recited in claim 4 , wherein said non-amine containing polar additive is n-formylmorpholine (NFM).

16. A method as recited in claim 13 , wherein said non-amine containing polar additive is n-formylmorpholine (NFM).

Assignees

• Shell Oil Co

Inventors

• Gabrielov Alexei Grigorievich
• Gillespie William Douglas

Classifications

• B01J23/85 Primary

  Chromium, molybdenum or tungsten · CPC title

• C10G45/06

  containing nickel or cobalt metal, or compounds thereof · CPC title

• B01J27/24

  Nitrogen compounds · CPC title

• B01J23/883

  and nickel · CPC title

• B01J37/024 Primary

  Multiple impregnation or coating · CPC title