Copper complex titanium oxide dispersion liquid, coating agent composition, and antibacterial/antiviral member

Patent metadata

Field	Value
Publication number	US-9585385-B2
Application number	US-201414764705-A
Country	US
Kind code	B2
Filing date	Feb 26, 2014
Priority date	Mar 13, 2013
Publication date	Mar 7, 2017
Grant date	Mar 7, 2017

Abstract

A copper complex titanium oxide dispersion liquid includes: titanium oxide particles; and 0.1 to 20 parts by mass of cuprous oxide particles per 100 parts by mass of the titanium oxide particles. The dispersion liquid further includes: 5 to 100 parts by mass of phosphate ester-based anionic surfactant per 100 parts by mass of the titanium oxide particles and the cuprous oxide particles combined; and 300 to 2000 parts by mass of an organic solvent per 100 parts by mass of the titanium oxide particles and the cuprous oxide particles combined. The titanium oxide particles and the cuprous oxide particles have an average primary particle diameter of 2 nm to 80 nm and have an average secondary particle diameter of 50 nm to 150 nm as measured by dynamic light scattering using cumulant analysis. Moreover, 10 or more parts by mass of the titanium oxide particles are contained in 100 parts by mass of non-volatile matter content of the copper complex titanium oxide dispersion liquid.

First claim

The invention claimed is:

1. A copper complex titanium oxide dispersion liquid, comprising:
titanium oxide particles;
0.1 to 20 parts by mass of cuprous oxide particles per 100 parts by mass of the titanium oxide particles;
5 to 100 parts by mass of a phosphate ester-based anionic surfactant per 100 parts by mass of the titanium oxide particles and the cuprous oxide particles combined; and
300 to 2000 parts by mass of an organic solvent per 100 parts by mass of the titanium oxide particles and the cuprous oxide particles combined,
wherein the titanium oxide particles and the cuprous oxide particles have an average primary particle diameter of 2 nm to 80 nm and have an average secondary particle diameter of 50 nm to 150 nm, the average secondary particle diameter being measured by dynamic light scattering using cumulant analysis.

2. A coating agent composition, comprising:
the copper complex titanium oxide dispersion liquid according to claim 1 ; and
a binder resin,
wherein 10 to 80 parts by mass of the titanium oxide particles are contained in 100 parts by mass of non-volatile matter content of the coating agent composition.

3. The coating agent composition according to claim 2 , wherein the binder resin contains chlorinated polyolefin.

4. An antibacterial/antiviral member, comprising:
a substrate; and
a coating film which is provided on the substrate and includes the coating agent composition according to claim 2 .

5. The antibacterial/antiviral member according to claim 4 , wherein the coating film has a static contact angle of 30 degrees or less for oleic acid.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Ueda Takeshi
• Yamashina Daigo
• Kinugawa Kensaku

Classifications

• C01G23/003

  Titanates (C01G23/001 takes precedence) · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C09D5/14

  Paints containing biocides, e.g. fungicides, insecticides or pesticides (C09D5/16 takes precedence) · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• C08J2433/06

  of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title